66 research outputs found
The Impact of Molecular Polarization on the Electronic Properties of Molecular Semiconductors
In a molecular semiconductor, the carrier is dressed with a polarization
cloud that we treat as a quantum field of Frenkel excitons coupled to it. The
consequences of the existence of this electronic polaron on the dynamics of an
extra charge in a material like pentacene can thus be evaluated.Comment: 7 pages, 1 figure, LaTe
Polarization effects in the channel of an organic field-effect transistor
We present the results of our calculation of the effects of dynamical
coupling of a charge-carrier to the electronic polarization and the
field-induced lattice displacements at the gate-interface of an organic
field-effect transistor (OFET). We find that these interactions reduce the
effective bandwidth of the charge-carrier in the quasi-two dimensional channel
of a pentacene transistor by a factor of two from its bulk value when the gate
is a high-permittivity dielectric such as
while this reduction essentially vanishes using a polymer gate-insulator. These
results demonstrate that carrier mass renormalization triggers the dielectric
effects on the mobility reported recently in OFETs.Comment: 19 pages, 3 figure
Quantum coherence and carriers mobility in organic semiconductors
We present a model of charge transport in organic molecular semiconductors
based on the effects of lattice fluctuations on the quantum coherence of the
electronic state of the charge carrier. Thermal intermolecular phonons and
librations tend to localize pure coherent states and to assist the motion of
less coherent ones. Decoherence is thus the primary mechanism by which
conduction occurs. It is driven by the coupling of the carrier to the molecular
lattice through polarization and transfer integral fluctuations as described by
the hamiltonian of Gosar and Choi. Localization effects in the quantum coherent
regime are modeled via the Anderson hamiltonian with correlated diagonal and
non-diagonal disorder leading to the determination of the carrier localization
length. This length defines the coherent extension of the ground state and
determines, in turn, the diffusion range in the incoherent regime and thus the
mobility. The transfer integral disorder of Troisi and Orlandi can also be
incorporated. This model, based on the idea of decoherence, allowed us to
predict the value and temperature dependence of the carrier mobility in
prototypical organic semiconductors that are in qualitative accord with
experiments
Current saturation and Coulomb interactions in organic single-crystal transistors
Electronic transport through rubrene single-crystal field effect transistors
(FETs) is investigated experimentally in the high carrier density regime (n ~
0.1 carrier/molecule). In this regime, we find that the current does not
increase linearly with the density of charge carriers, and tends to saturate.
At the same time, the activation energy for transport unexpectedly increases
with increasing n. We perform a theoretical analysis in terms of a well-defined
microscopic model for interacting Frohlich polarons, that quantitatively
accounts for our experimental observations. This work is particularly
significant for our understanding of electronic transport through organic FETs.Comment: Extended version with 1 additional figure and an appendix explaining
the consistency of the theoretical calculatio
Interplay of disorder and nonlinearity in Klein-Gordon models: Immobile kinks
We consider Klein-Gordon models with a -correlated spatial disorder.
We show that the properties of immobile kinks exhibit strong dependence on the
assumptions as to their statistical distribution over the minima of the
effective random potential. Namely, there exists a crossover from monotonically
increasing (when a kink occupies the deepest potential well) to the
non-monotonic (at equiprobable distribution of kinks over the potential minima)
dependence of the average kink width as a function of the disorder intensity.
We show also that the same crossover may take place with changing size of the
system.Comment: 7 pages, 4 figure
Nitrous oxide does not produce a clinically important sparing effect during closed-loop delivered propofol-remifentanil anaesthesia guided by the bispectral index: a randomized multicentre studyâ âĄ
Background Nitrous oxide (N2O) offers both hypnotic and analgesic characteristics. We therefore tested the hypothesis that N2O administration decreases the amount of propofol and remifentanil given by a closed-loop automated controller to maintain a similar bispectral index (BIS). Methods In a randomized multicentre double-blind study, patients undergoing elective surgery were randomly assigned to breathe 60% inspired N2O (N2O group) or 40% oxygen (AIR group). Anaesthesia depth was evaluated by the proportion of time where BIS was within the range of 40-60 (BIS40-60). The primary outcomes were propofol and remifentanil consumption, with reductions of 20% in either being considered clinically important. Results A total of 302 patients were randomized to the N2O group and 299 to the AIR group. At similar BIS40-60 [79 (67-86)% vs 76 (65-85)%], N2O slightly decreased propofol consumption [4.5 (3.7-5.5) vs 4.8 (4.0-5.9) mg kgâ1 hâ1, P=0.032], but not remifentanil consumption [0.17 (0.12-0.23) vs 0.18 (0.14-0.24) ”g kgâ1 minâ1]. For the subgroups of men, at similar BIS40-60 [80 (72-88)% vs 80 (70-87)%], propofol [4.2 (3.4-5.3) vs 4.4 (3.6-5.4) mg kgâ1 hâ1] and remifentanil [0.19 (0.13-0.25) vs 0.18 (0.15-0.23) ”g kgâ1 minâ1] consumptions were similar in the N2O vs AIR group, respectively. For the subgroups of women, at similar BIS40-60 [76 (64-84)% vs 72 (62-82)%], propofol [4.7 (4.0-5.8) vs 5.3 (4.5-6.6) mg kgâ1 hâ1, P=0.004] and remifentanil [0.18 (0.13-0.25) vs 0.20 (0.15-0.27) ”g kgâ1 minâ1, P=0.029] consumptions decreased with the co-administration of N2O. Conclusions With automated drug administration titrated to comparable BIS, N2O only slightly reduced propofol consumption and did not reduce remifentanil consumption. There was a minor gender dependence, but not by a clinically important amount. Clinical trial registration This study was registered at ClinicalTrials.gov, number NCT0054720
Theory of energetic/alpha particle effects on magnetohydrodynamic modes in tokamaks
The presence of energetic particles is shown to qualitatively modify the stability properties of ideal as well as resistive magnetohydrodynamic (MHD) modes in tokamaks. Specifically, we demonstrate that, consistent with highpower ICRF heating experiments in JET, high energy trapped particles can effectively stabilize the sawtooth mode, providing a possible route to stable high current tokamak operation. An alternative stabilization scheme employing barely circulating energetic particles is also proposed. Finally, we present analytical and numerical studies on the excitations of high-n MHD modes via transit resonances with circulating alpha particles. 14 refs., 3 figs
Magnetic Reconnection Triggering Magnetohydrodynamic Instabilities during a Sawtooth Crash in a Tokamak Plasma
Tunable Frohlich Polarons in Organic Single-Crystal Transistors
In organic field effect transistors (FETs), charges move near the surface of
an organic semiconductor, at the interface with a dielectric. In the past, the
nature of the microscopic motion of charge carriers -that determines the device
performance- has been related to the quality of the organic semiconductor.
Recently, it has been appreciated that also the nearby dielectric has an
unexpectedly strong influence. The mechanisms responsible for this influence
are not understood. To investigate these mechanisms we have studied transport
through organic single crystal FETs with different gate insulators. We find
that the temperature dependence of the mobility evolves from metallic-like to
insulating-like with increasing the dielectric constant of the insulator. The
phenomenon is accounted for by a two-dimensional Frohlich polaron model that
quantitatively describes our observations and shows that increasing the
dielectric polarizability results in a crossover from the weak to the strong
polaronic coupling regime
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