The development and structure of the tail in woodpeckers

Thesis (M.A.)--University of Kansas, Zoology, 1927

SAMSS: An in-progress review of the Spacecraft Assembly, Maintenance, and Servicing Study

The Spacecraft Assembly, Maintenance, and Servicing Study (SAMSS) is an effort to define and verify the most cost effective approach to spacecraft servicing, as a alternative to replacement, in the 1990's and beyond. The intent of the study is to assess the servicing of satellites in all orbit regimes. Elements of a space servicing infrastructure are developed and cost estimates are generated. Readiness is assessed and proof of concept demonstrations are identified. Cryogenic fuel resupply is discussed

Hexafluorosilicate and tetrafluoroborate coordination to lead(II) di- and tri-imine complexes – Unusual fluoroanion coordination modes

AbstractLead(II) tetrafluoroborate and hexafluorosilicate complexes with 2,2′-bipyridyl, 1,10-phenathroline and 2,2′:6′,2″-terpyridyl have been prepared from the ligand and lead salt in aqueous/MeCN. Crystal structures are reported for [Pb(bipy)2(SiF6)], [Pb(phen)2(SiF6)] and [Pb(bipy)2(BF4)2] which are dinuclear with each lead coordinated “cis” to the two diimines and with the bridging fluoroanions completing eight or nine-coordination. [Pb(phen)2(BF4)2] is eight-coordinate and mononuclear with “cis” diimines and two κ2-BF4− groups. [Pb(phen)2(H2O)2(SiF6)] is also mononuclear with a κ2-SiF62− group and two coordinated water molecules. Reaction of Pb(BF4)2 with 2,2′:6′,2″-terpyridyl gave only [Pb(terpy)3][BF4]2, but Pb(SiF6) produced [Pb(terpy)(H2O)(SiF6)], which is a chain polymer with bridging SiF62− groups and significant π-stacking of the imine rings. The work has identified a number of coordination modes of the SiF62− anion, which has been little used in coordination chemistry but proves to be versatile and also stable (to decomposition/hydrolysis)