2,712 research outputs found
Modeling one-dimensional island growth with mass-dependent detachment rates
We study one-dimensional models of particle diffusion and
attachment/detachment from islands where the detachment rates gamma(m) of
particles at the cluster edges increase with cluster mass m. They are expected
to mimic the effects of lattice mismatch with the substrate and/or long-range
repulsive interactions that work against the formation of long islands.
Short-range attraction is represented by an overall factor epsilon<<1 in the
detachment rates relatively to isolated particle hopping rates [epsilon ~
exp(-E/T), with binding energy E and temperature T]. We consider various
gamma(m), from rapidly increasing forms such as gamma(m) ~ m to slowly
increasing ones, such as gamma(m) ~ [m/(m+1)]^b. A mapping onto a column
problem shows that these systems are zero-range processes, whose steady states
properties are exactly calculated under the assumption of independent column
heights in the Master equation. Simulation provides island size distributions
which confirm analytic reductions and are useful whenever the analytical tools
cannot provide results in closed form. The shape of island size distributions
can be changed from monomodal to monotonically decreasing by tuning the
temperature or changing the particle density rho. Small values of the scaling
variable X=epsilon^{-1}rho/(1-rho) favour the monotonically decreasing ones.
However, for large X, rapidly increasing gamma(m) lead to distributions with
peaks very close to and rapidly decreasing tails, while slowly increasing
gamma(m) provide peaks close to /2$ and fat right tails.Comment: 16 pages, 6 figure
Island size distributions in submonolayer growth: successful prediction by mean field theory with coverage dependent capture numbers
We show that mean-field rate equations for submonolayer growth can
successfully predict island size distributions in the pre-coalescence regime if
the full dependence of capture numbers on both the island size and the coverage
is taken into account. This is demonstrated by extensive Kinetic Monte Carlo
simulations for a growth kinetics with hit and stick aggregation. A detailed
analysis of the capture numbers reveals a nonlinear dependence on the island
size for small islands. This nonlinearity turns out to be crucial for the
successful prediction of the island size distribution and renders an analytical
treatment based on a continuum limit of the mean-field rate equations
difficult.Comment: 4 pages, 4 figue
Kinetic theory of cluster impingement in the framework of statistical mechanics of rigid disks
The paper centres on the evaluation of the function n(theta)=N(theta)/N0,
that is the normalized number of islands as a function of coverage 0<theta<1,
given N0 initial nucleation centres (dots) having any degree of spatial
correlation. A mean field approach has been employed: the islands have the same
size at any coverage. In particular, as far as the random distribution of dots
is concerned, the problem has been solved by considering the contribution of
binary collisions between islands only. With regard to correlated dots, we
generalize a method previously applied to the random case only. In passing, we
have made use of the exclusion probability reported in [S. Torquato, B. Lu, J.
Rubinstein, Phys.Rev.A 41, 2059 (1990)], for determining the kinetics of
surface coverage in the case of correlated dots, improving our previous
calculation [M. Tomellini, M. Fanfoni, M. Volpe Phys. Rev.B 62, 11300, (2000)].Comment: 10 pages, 3 figure
The Three-Nucleon System Near the N-d Threshold
The three-nucleon system is studied at energies a few hundred keV above the
N-d threshold. Measurements of the tensor analyzing powers and
for p-d elastic scattering at keV are presented
together with the corresponding theoretical predictions. The calculations are
extended to very low energies since they are useful for extracting the p-d
scattering lengths from the experimental data. The interaction considered here
is the Argonne V18 potential plus the Urbana three-nucleon potential. The
calculation of the asymptotic D- to S-state ratio for H and He, for
which recent experimental results are available, is also presented.Comment: Latex, 11 pages, 2 figures, to be published in Phy.Lett.
Exploring Oxidation in the Remote Free Troposphere: Insights from Atmospheric Tomography (ATom)
Earth's atmosphere oxidizes the greenhouse gas methane and other gases, thus determining their lifetimes and oxidation products. Much of this oxidation occurs in the remote, relatively clean free troposphere above the planetary boundary layer, where the oxidation chemistry is thought to be much simpler and better understood than it is in urban regions or forests. The NASA airborne Atmospheric Tomography study (ATom) was designed to produce cross sections of the detailed atmospheric composition in the remote atmosphere over the Pacific and Atlantic Oceans during four seasons. As part of the extensive ATom data set, measurements of the atmosphere's primary oxidant, hydroxyl (OH), and hydroperoxyl (HO₂) are compared to a photochemical box model to test the oxidation chemistry. Generally, observed and modeled median OH and HO₂ agree to with combined uncertainties at the 2σ confidence level, which is ~±40%. For some seasons, this agreement is within ~±20% below 6 km altitude. While this test finds no significant differences, OH observations increasingly exceeded modeled values at altitudes above 8 km, becoming ~35% greater, which is near the combined uncertainties. Measurement uncertainty and possible unknown measurement errors complicate tests for unknown chemistry or incorrect reaction rate coefficients that would substantially affect the OH and HO₂ abundances. Future analysis of detailed comparisons may yield additional discrepancies that are masked in the median values
Ag-coverage-dependent symmetry of the electronic states of the Pt(111)-Ag-Bi interface: The ARPES view of a structural transition
We studied by angle-resolved photoelectron spectroscopy the strain-related
structural transition from a pseudomorphic monolayer (ML) to a striped
incommensurate phase in an Ag thin film grown on Pt(111). We exploited the
surfactant properties of Bi to grow ordered Pt(111)-xMLAg-Bi trilayers with 0 <
x < 5 ML, and monitored the dispersion of the Bi-derived interface states to
probe the structure of the underlying Ag film. We find that their symmetry
changes from threefold to sixfold and back to threefold in the Ag coverage
range studied. Together with previous scanning tunneling microscopy and
photoelectron diffraction data, these results provide a consistent microscopic
description of the coverage-dependent structural transition.Comment: 10 pages, 9 figure
Low-energy p-d Scattering: High Precision Data, Comparisons with Theory, and Phase-Shift Analyses
Angular distributions of sigma(theta), A_y, iT_11, T_20, T_21, and T_22 have
been measured for d-p scattering at E_c.m.=667 keV. This set of high-precision
data is compared to variational calculations with the nucleon-nucleon potential
alone and also to calculations including a three-nucleon (3N) potential.
Agreement with cross-section and tensor analyzing power data is excellent when
a 3N potential is used. However, a comparison between the vector analyzing
powers reveals differences of approximately 40% in the maxima of the angular
distributions which is larger than reported at higher energies for both p-d and
n-d scattering. Single-energy phase-shift analyses were performed on this data
set and a similar data set at E_c.m.=431.3 keV. The role of the different
phase-shift parameters in fitting these data is discussed.Comment: 18 pages, 6 figure
Strain-Dependence of Surface Diffusion: Ag on Ag(111) and Pt(111)
Using density-functional theory with the local-density approximation and the
generalized gradient approximation we compute the energy barriers for surface
diffusion for Ag on Pt(111), Ag on one monolayer of Ag on Pt(111), and Ag on
Ag(111). The diffusion barrier for Ag on Ag(111) is found to increase linearly
with increasing lattice constant. We also discuss the reconstruction that has
been found experimentally when two Ag layers are deposited on Pt(111). Our
calculations explain why this strain driven reconstruction occurs only after
two Ag layers have been deposited.Comment: 4 pages, 3 figures, Phys. Rev. B 55 (1997), in pres
Decoherence and the rate of entropy production in chaotic quantum systems
We show that for an open quantum system which is classically chaotic (a
quartic double well with harmonic driving coupled to a sea of harmonic
oscillators) the rate of entropy production has, as a function of time, two
relevant regimes: For short times it is proportional to the diffusion
coefficient (fixed by the system--environment coupling strength). For longer
times (but before equilibration) there is a regime where the entropy production
rate is fixed by the Lyapunov exponent. The nature of the transition time
between both regimes is investigated.Comment: Revtex, 4 pages, 3 figures include
Decoherence of a Pointer by a Gas Reservoir
We study the effect of the environment on the process of the measurement of a
state of a microscopic spin half system. The measuring apparatus is a heavy
particle, whose center of mass coordinates can be considered at the end of the
measurement as approximately classical, and thus can be used as a pointer. The
state of the pointer, which is the result of its interaction with the spin, is
transformed into a mixed state by the coupling of the pointer to the
environment. The environment is considered to be a gas reservoir, whose
particles interact with the pointer. This results in a Fokker-Planck equation
for the reduced density matrix of the pointer. The solution of the equation
shows that the quantum coherences, which are characteristic to the entangled
state between the probabilities to find the pointer in one of two positions,
decays exponentially fast in time. We calculate the exponential decay function
of this decoherence effect, and express it in terms of the parameters of the
model.Comment: 41 pages, 1 figur
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