14,325 research outputs found

    Re-entry vehicle shape for enhanced performance

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    A convex shell structure for enhanced aerodynamic performance and/or reduced heat transfer requirements for a space vehicle that re-enters an atmosphere. The structure has a fore-body, an aft-body, a longitudinal axis and a transverse cross sectional shape, projected on a plane containing the longitudinal axis, that includes: first and second linear segments, smoothly joined at a first end of each the first and second linear segments to an end of a third linear segment by respective first and second curvilinear segments; and a fourth linear segment, joined to a second end of each of the first and second segments by curvilinear segments, including first and second ellipses having unequal ellipse parameters. The cross sectional shape is non-symmetric about the longitudinal axis. The fourth linear segment can be replaced by a sum of one or more polynomials, trigonometric functions or other functions satisfying certain constraints

    Penrose Diagram for a Transient Black Hole

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    A Penrose diagram is constructed for a spatially coherent black hole that smoothly begins an accretion, then excretes symmetrically as measured by a distant observer, with the initial and final states described by a metric of Minkowski form. Coordinate curves on the diagram are computationally derived. Causal relationships between space-time regions are briefly discussed. The life cycle of the black hole demonstrably leaves asymptotic observers in an unaltered Minkowski space-time of uniform conformal scale.Comment: 14 pages, 9 figures, spelling correction

    Structural Classification of Metal Complexes with Three-Coordinate Centres

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    Attempts to describe the geometry about three-coordinate silver(I) complexes have proven difficult because interatomic angles generally vary wildly and there is no adequate or readily available classification system found in the literature. A search of the Cambridge Structural Database shows that complexes formed between any metal centre and three non-metal donors (18001 examples) usually adopt geometries that are quite different than ideal ā€˜textbookā€™ extremes of either trigonal planar (āˆ¼4% with Ī± = Ī² = Ī³ = 120 Ā± 2Ā°), T-shaped (āˆ¼0.05% with Ī± = 180 Ā± 2Ā°, Ī² = Ī³ = 90 Ā± 2Ā°), or trigonal pyramidal (āˆ¼0.3% with Ī± = Ī² = Ī³ = 110 Ā± 2Ā°). Moreover, there are multiple variations of ā€œY-typeā€ and ā€œotherā€ shapes that require elaboration. Thus, to assist in future structural descriptions, we developed a classification system that spans all known and yet-to-be-discovered three-coordinate geometries. A spreadsheet has also been constructed that utilizes the ā€œshape-spaceā€ approach to extract the structural description from a user input of three angles about a tri-coordinate centre and the number of atoms in a plane. The structures of two silver(I) complexes of new N-donor ligands p-NH2C6H4C6H4CH(pz = pyrazol-1-yl)2, L1, and 2-ferrocenyl-4,5-di(2-pyridyl)imidazole, L2, illustrate the utility of this classification system

    Experimental Database with Baseline CFD Solutions: 2-D and Axisymmetric Hypersonic Shock-Wave/Turbulent-Boundary-Layer Interactions

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    A database compilation of hypersonic shock-wave/turbulent boundary layer experiments is provided. The experiments selected for the database are either 2D or axisymmetric, and include both compression corner and impinging type SWTBL interactions. The strength of the interactions range from attached to incipient separation to fully separated flows. The experiments were chosen based on criterion to ensure quality of the datasets, to be relevant to NASA's missions and to be useful for validation and uncertainty assessment of CFD Navier-Stokes predictive methods, both now and in the future. An emphasis on datasets selected was on surface pressures and surface heating throughout the interaction, but include some wall shear stress distributions and flowfield profiles. Included, for selected cases, are example CFD grids and setup information, along with surface pressure and wall heating results from simulations using current NASA real-gas Navier-Stokes codes by which future CFD investigators can compare and evaluate physics modeling improvements and validation and uncertainty assessments of future CFD code developments. The experimental database is presented tabulated in the Appendices describing each experiment. The database is also provided in computer-readable ASCII files located on a companion DVD

    A TPD and RAIRS comparison of the low temperature behavior of benzene, toluene, and xylene on graphite

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    The first comparative study of the surface behavior of four small aromatic molecules, benzene, toluene, p-xylene, and o-xylene, adsorbed on graphite at temperatures ā‰¤30 K, is presented. Intermolecular interactions are shown to be important in determining the growth of the molecules on the graphite surface at low (monolayer) exposures. Repulsive intermolecular interactions dominate the behavior of benzene and toluene. By contrast, stronger interactions with the graphite surface are observed for the xylene isomers, with islanding observed for o-xylene. Multilayer desorption temperatures and energies increase with the size of the molecule, ranging from 45.5 to 59.5 kJ molāˆ’1 for benzene and p-xylene, respectively. Reflection absorption infrared spectroscopy gives insight into the effects of thermal processing on the ordering of the molecules. Multilayer benzene, p-xylene, and o-xylene form crystalline structures following annealing of the ice. However, we do not observe an ordered structure for toluene in this study. The ordering of p-xylene shows a complex relationship dependent on both the annealing temperature and exposure

    Effectiveness of a short video-based educational intervention on factors related to clinical trial participation in adolescents and young adults: a pre-test/post-test design

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    Abstract Background Poor clinical trial enrollment continues to be pervasive and is especially problematic among young adults and youth, and among minorities. Efforts to address barriers to enrollment have been predominantly focused on adult diseased populations. Because older adults may already have established attitudes, it is imperative to identify strategies that target adolescents and young adults. The purpose of this study was to test the effectiveness of an educational video on factors related to clinical trial participation among a healthy adolescent and young adult population. Methods Participants completed a 49-item pre-test, viewed a 10-min video, and completed a 45-item post-test to assess changes in attitudes, knowledge, self-efficacy, receptivity to, and intention to participate (primary outcome) in clinical trials. Descriptive statistics, paired samples t-tests, and Wilcoxon signed-rank tests were conducted. Results The final analyses included 935 participants. The mean age was 20.7 years, with almost 70% aged 18 to 20ā€‰years. The majority were female (73%), non-Hispanic (92.2%), white (70%), or African American (20%). Participants indicated a higher intention to participate in a clinical trial (pā€‰<ā€‰0.0001) and receptivity to hearing more about a clinical trial (pā€‰<ā€‰0.0001) after seeing the video. Intention to participate (definitely yes and probably yes) increased by an absolute 18% (95% confidence interval 15ā€“22%). There were significant improvements in attitudes, knowledge, and self-efficacy scores for all participants (pā€‰<ā€‰0.0001). Conclusions The results of this study showed strong evidence for the effectiveness of a brief intervention on factors related to participation in clinical trials. This supports the use of a brief intervention, in a traditional educational setting, to impact the immediate attitudes, knowledge, self-efficacy, and intention to participate in clinical trial research among diverse, healthy adolescents and young adults.https://deepblue.lib.umich.edu/bitstream/2027.42/146769/1/13063_2018_Article_3097.pd
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