Superficial Scald versus Ethanol Vapours: A Dose Response

Early picked "Granny Smith" apples (Malus domestica Borkh.) were stored under air or CA (controlled atmosphere at 2 kPa O2 and <1 kPa CO2) at 1°C. During the first week of storage, fruit was subjected to ethanol vapours in doses from 0 to 8 g/kg of fruit. Ethanol at 4 g/kg protected fruit against superficial scald in CA storage for at least 5.5 months, plus two weeks in cold air storage, plus a week at ambient temperature. Ethanol at 6 g/kg protected fruit in cold air storage for 3 months, plus a week at ambient temperature. Effects of ethanol vapours and CA on headspace ethylene levels are discussed. Ethanol vapours did not cause significant off-flavours in "Granny Smith" apples (consumer panel, hedonic scale), or purpling of the skin of Red Delicious apples (visual assessment)

Stochastic dynamics of an electron in a Penning trap: phase flips correlated with amplitude collapses and revivals

We study the effect of noise on the axial mode of an electron in a Penning trap under parametric-resonance conditions. Our approach, based on the application of averaging techniques to the description of the dynamics, provides an understanding of the random phase flips detected in recent experiments. The observed correlation between the phase jumps and the amplitude collapses is explained. Moreover, we discuss the actual relevance of noise color to the identified phase-switching mechanism. Our approach is then generalized to analyze the persistence of the stochastic phase flips in the dynamics of a cloud of N electrons. In particular, we characterize the detected scaling of the phase-jump rate with the number of electrons.Comment: 15 pages, 6 figure

Reduced dimensionality spin-orbit dynamics of CH3 + HCl reversible arrow CH4 Cl on ab initio surfaces

A reduced dimensionality quantum scattering method is extended to the study of spin-orbit nonadiabatic transitions in the CH3 + HCl reversible arrow CH4 + Cl(P-2(J)) reaction. Three two-dimensional potential energy surfaces are developed by fitting a 29 parameter double-Morse function to CCSD(T)/IB//MP2/cc-pV(T+d)Z-dk ab initio data; interaction between surfaces is described by geometry-dependent spin-orbit coupling functions fit to MCSCF/cc-pV(T+d)Z-dk ab initio data. Spectator modes are treated adiabatically via inclusion of curvilinear projected frequencies. The total scattering wave function is expanded in a vibronic basis set and close-coupled equations are solved via R-matrix propagation. Ground state thermal rate constants for forward and reverse reactions agree well with experiment. Multi-surface reaction probabilities, integral cross sections, and initial-state selected branching ratios all highlight the importance of vibrational energy in mediating nonadiabatic transition. Electronically excited state dynamics are seen to play a small but significant role as consistent with experimental conclusions. (C) 2011 American Institute of Physics. [doi:10.1063/1.3592732

Time scale of forerunners in quantum tunneling

The forerunners preceding the main tunneling signal of the wave created by a source with a sharp onset or by a quantum shutter, have been generally associated with over-the-barrier (non-tunneling) components. We demonstrate that, while this association is true for distances which are larger than the penetration lenght, for smaller distances the forerunner is dominated by under-the-barrier components. We find that its characteristic arrival time is inversely proportional to the difference between the barrier energy and the incidence energy, a tunneling time scale different from both the phase time and the B\"uttiker-Landauer (BL) time.Comment: Revtex4, 14 eps figure

Time dependence of evanescent quantum waves

The time dependence of quantum evanescent waves generated by a point source with an infinite or a limited frequency band is analyzed. The evanescent wave is characterized by a forerunner (transient) related to the precise way the source is switched on. It is followed by an asymptotic, monochromatic wave which at long times reveals the oscillation frequency of the source. For a source with a sharp onset the forerunner is exponentially larger than the monochromatic solution and a transition from the transient regime to the asymtotic regime occurs only at asymptotically large times. In this case, the traversal time for tunneling plays already a role only in the transient regime. To enhance the monochromatic solution compared to the forerunner we investigate (a) frequency band limited sources and (b) the short time Fourier analysis (the spectrogram) corresponding to a detector which is frequency band limited. Neither of these two methods leads to a precise determination of the traversal time. However, if they are limited to determine the traversal time only with a precision of the traversal time itself both methods are successful: In this case the transient behavior of the evanescent waves is at a time of the order of the traversal time followed by a monochromatic wave which reveals the frequency of the source.Comment: 16 text pages and 9 postscript figure

Quantum-wave evolution in a step potential barrier

By using an exact solution to the time-dependent Schr\"{o}dinger equation with a point source initial condition, we investigate both the time and spatial dependence of quantum waves in a step potential barrier. We find that for a source with energy below the barrier height, and for distances larger than the penetration length, the probability density exhibits a {\it forerunner} associated with a non-tunneling process, which propagates in space at exactly the semiclassical group velocity. We show that the time of arrival of the maximum of the {\it forerunner} at a given fixed position inside the potential is exactly the traversal time, $\tau$. We also show that the spatial evolution of this transient pulse exhibits an invariant behavior under a rescaling process. This analytic property is used to characterize the evolution of the {\it forerunner}, and to analyze the role played by the time of arrival, $3^{-1/2}\tau$, found recently by Muga and B\"{u}ttiker [Phys. Rev. A {\bf 62}, 023808 (2000)].Comment: To be published in Phys. Rev. A (2002

Tunneling dynamics in relativistic and nonrelativistic wave equations

We obtain the solution of a relativistic wave equation and compare it with the solution of the Schroedinger equation for a source with a sharp onset and excitation frequencies below cut-off. A scaling of position and time reduces to a single case all the (below cut-off) nonrelativistic solutions, but no such simplification holds for the relativistic equation, so that qualitatively different ``shallow'' and ``deep'' tunneling regimes may be identified relativistically. The nonrelativistic forerunner at a position beyond the penetration length of the asymptotic stationary wave does not tunnel; nevertheless, it arrives at the traversal (semiclassical or B\"uttiker-Landauer) time "tau". The corresponding relativistic forerunner is more complex: it oscillates due to the interference between two saddle point contributions, and may be characterized by two times for the arrival of the maxima of lower and upper envelops. There is in addition an earlier relativistic forerunner, right after the causal front, which does tunnel. Within the penetration length, tunneling is more robust for the precursors of the relativistic equation

Collisional depolarization of NO(A) by He and Ar studied by quantum beat spectroscopy

Zeeman and hyperfine quantum beat spectroscopies have been used to measure the total elastic plus inelastic angular momentum depolarization rate constants at 300 K for NO (A 2 σ+) in the presence of He and Ar. In the case of Zeeman quantum beats it is shown how the applied magnetic field can be used to allow measurement of depolarization rates for both angular momentum orientation and alignment. For the systems studied here, collisional loss of alignment is more efficient than loss of orientation. In the case of NO (A) with He, and to a lesser extent NO (A) with Ar, collisional depolarization is found to be a relatively minor process compared to rotational energy transfer, reflecting the very weak long-range forces in these systems. Detailed comparisons are made with quantum mechanical and quasiclassical trajectory calculations performed on recently developed potential energy surfaces. For both systems, the agreement between the calculated depolarization cross sections and the present measurements is found to be very good, suggesting that it is reasonable to consider the NO (A) bond as frozen during these angular momentum transferring collisions. A combination of kinematic effects and differences in the potential energy surfaces are shown to be responsible for the differences observed in depolarization cross section with He and Ar as a collider. © 2009 American Institute of Physics

Composite absorbing potentials

The multiple scattering interferences due to the addition of several contiguous potential units are used to construct composite absorbing potentials that absorb at an arbitrary set of incident momenta or for a broad momentum interval.Comment: 9 pages, Revtex, 2 postscript figures. Accepted in Phys. Rev. Let

Time-of-arrival distribution for arbitrary potentials and Wigner's time-energy uncertainty relation

A realization of the concept of "crossing state" invoked, but not implemented, by Wigner, allows to advance in two important aspects of the time of arrival in quantum mechanics: (i) For free motion, we find that the limitations described by Aharonov et al. in Phys. Rev. A 57, 4130 (1998) for the time-of-arrival uncertainty at low energies for certain mesurement models are in fact already present in the intrinsic time-of-arrival distribution of Kijowski; (ii) We have also found a covariant generalization of this distribution for arbitrary potentials and positions.Comment: 4 pages, revtex, 2 eps figures include