Matching fields of a long superconducting film

We obtain the vortex configurations, the matching fields and the magnetization of a superconducting film with a finite cross section. The applied magnetic field is normal to this cross section, and we use London theory to calculate many of its properties, such as the local magnetic field, the free energy and the induction for the mixed state. Thus previous similar theoretical works, done for an infinitely long superconducting film, are recovered here, in the special limit of a very long cross section.Comment: Contains a REVTeX file and 4 figure

Interactions between directly and parametrically driven vibration modes in a micromechanical resonator

The interactions between parametrically and directly driven vibration modes of a clamped-clamped beam resonator are studied. An integrated piezoelectric transducer is used for direct and parametric excitation. First, the parametric amplification and oscillation of a single mode are analyzed by the power and phase dependence below and above the threshold for parametric oscillation. Then, the motion of a parametrically driven mode is detected by the induced change in resonance frequency in another mode of the same resonator. The resonance frequency shift is the result of the nonlinear coupling between the modes by the displacement-induced tension in the beam. These nonlinear modal interactions result in the quadratic relation between the resonance frequency of one mode and the amplitude of another mode. The amplitude of a parametrically oscillating mode depends on the square root of the pump frequency. Combining these dependencies yields a linear relation between the resonance frequency of the directly driven mode and the frequency of the parametrically oscillating mode.Comment: 5 pages, 4 figure

High sensitive quasi freestanding epitaxial graphene gassensor on 6H-SiC

We have measured the electrical response to NO$_2$, N$_2$, NH$_3$ and CO for epitaxial graphene and quasi freestanding epitaxial graphene on 6H-SiC substrates. Quasi freestanding epitaxial graphene shows a 6 fold increase in NO2 sensitivity compared to epitaxial graphene. Both samples show a sensitivity better than the experimentally limited 1 ppb. The strong increase in sensitivity of quasi freestanding epitaxial graphene can be explained by a Fermi-energy close to the Dirac Point leading to a strongly surface doping dependent sample resistance. Both sensors show a negligible sensitivity to N$_2$, NH$_3$ and CO

Interface formation in K doped poly(dialkoxy-p-phenylene vinylene) light-emitting diodes

Manufacturing of Al/K/OC1C10 poly(p-phenylene vinylene)/indium–tin–oxide light emitting diode structures by physical vapor deposition of K onto the emissive polymer layer has been characterized by electroluminescence and ion spectroscopy. Varying the deposited K areal density from 3.9×1012 to 1.2×1014 atoms cm−2 the external efficiency rises from 0.01 to 1.2 Cd A−1. Spectra obtained by ion scattering analysis demonstrate the overall absence of K at the polymer outermost surface layer, and diffusion up to a depth of 200 Å. Depth profiles have been derived, and were modeled using an irreversible first order “trapping” reaction. Trapping may stem from confinement of the electron at a conjugated segment, that was donated through charge transfer typical for alkali/π-conjugated systems. This study demonstrates that evaporation of low work function metals onto organic systems should not be depicted as simple layered stacking structures. The enhanced electroluminescence with submonolayer K deposition is attributed to the shift of the recombination zone away from the Al cathode, which is demonstrated to prevail over the known exciton quenching mechanism due to the formation of gap states

Tuning the emission wavelength of Si nanocrystals in SiO2 by oxidation

Si nanocrystals (diameter 2–5 nm) were formed by 35 keV Si + implantation at a fluence of 6 × 1016 Si/cm2 into a 100 nm thick thermally grown SiO2 film on Si (100), followed by thermal annealing at 1100 °C for 10 min. The nanocrystals show a broad photoluminescence spectrum, peaking at 880 nm, attributed to the recombination of quantum confined excitons. Rutherford backscattering spectrometry and transmission electron microscopy show that annealing these samples in flowing O2 at 1000 °C for times up to 30 min results in oxidation of the Si nanocrystals, first close to the SiO2 film surface and later at greater depths. Upon oxidation for 30 min the photoluminescence peak wavelength blueshifts by more than 200 nm. This blueshift is attributed to a quantum size effect in which a reduction of the average nanocrystal size leads to emission at shorter wavelengths. The room temperature luminescence lifetime measured at 700 nm increases from 12 µs for the unoxidized film to 43 µs for the film that was oxidized for 29 min

Propagation of optical excitations by dipolar interactions in metal nanoparticle chains

Dispersion relations for dipolar modes propagating along a chain of metal nanoparticles are calculated by solving the full Maxwell equations, including radiation damping. The nanoparticles are treated as point dipoles, which means the results are valid only for a/d <= 1/3, where a is the particle radius and d the spacing. The discrete modes for a finite chain are first calculated, then these are mapped onto the dispersion relations appropriate for the infinite chain. Computed results are given for a chain of 50-nm diameter Ag spheres spaced by 75 nm. We find large deviations from previous quasistatic results: Transverse modes interact strongly with the light line. Longitudinal modes develop a bandwidth more than twice as large, resulting in a group velocity that is more than doubled. All modes for which k_mode <= w/c show strongly enhanced decay due to radiation damping.Comment: 26 pages, 7 figures, 2 tables. to appear in Phys. Rev.

Charging of single Si nanocrystals by atomic force microscopy

Conducting-tip atomic force microscopy (AFM) has been used to electronically probe silicon nanocrystals on an insulating substrate. The nanocrystal samples were produced by aerosol techniques and size classified; nanocrystal size can be controlled in the size range of 2-50 nm with a size variation of less than 10%. Using a conducting tip, the charge was injected directly into the nanocrystals, and the subsequent dissipation of the charge was monitored. Estimates of the injected charge can be made by comparison of the data with an intermittent contact mode model of the AFM response to the electrostatic force produced by the stored charge

Surface analysis of the ab-plane of MoVTeNbOx catalysts for propane (amm) oxidation by low energy ion scattering (LEIS)

There is great global interest in utilization of light alkane feedstocks in the prodn. of petrochems. by selective (amm)oxidn. due to current abundance and lower costs of alkanes compared to the corresponding olefins. However, direct oxidn. of alkanes requires multifunctional catalysts that cope with simultaneous activation of C-H bonds, mol. oxygen and ammonia and that concurrently provide selectively oxidizing oxygen atoms. For selective oxidn. of propane to acrylic acid and ammoxidn. to acrylonitrile, this multi-functionality is implemented in MoVTeNbOx catalysts, which show high activities and selectivities to acrylic acid and acrylonitrile. It has been suggested that the ab-planes of the M1 phase contain the active and selective surface sites. The catalytic role of these planes was investigated by combining the microreactor study of propane (amm)oxidn. over these model catalysts with Low Energy Ion Scattering (LEIS) to selectively det. the at. compn. of the outer surface of the ab-planes

Liquid metals as electrodes in polymer light emitting diodes

We demonstrate that liquid metals can be used as cathodes in light emitting diodes (pLEDs). The main difference between the use of liquid cathodes and evaporated cathodes is the sharpness of the metal–polymer interface. Liquid metal cathodes result in significantly sharper metal–organic interfaces than vapor deposited cathodes, due to the high surface energy of the metals. The sharper interface in pLEDs with liquid metal cathodes is observed by neutral impact collision ion scattering spectroscopy and low energy ion scattering spectroscopy measurements. The influence of interface sharpness on device performance was studied by comparing current–voltage-light characteristics of devices with OC1C10 paraphenylenevinylene (PPV) as electroluminescent polymer and indium tin oxide (ITO) as hole injection electrode, and different cathodes. Comparison of devices using a liquid Ga cathode and an evaporated Al cathode showed that light emission for the liquid Ga cathode is two orders of magnitude larger than for the evaporated Al cathode, and that the external light efficiency is increased by an order of magnitude. Since the work function of Ga and Al is nearly the same, the poor performance for evaporated Al LEDs is attributed to the formation of an interfacial layer where Al has diffused into, and reacted with, the PPV. This interfacial layer has poor electrical conduction compared to pure PPV, and contains quenching sites which reduce light emission. Low work function liquid metal cathodes were studied by using liquid Ca and Ba amalgams. The improved performance of liquid amalgam pLEDs is attributed to the different structure of the metal–polymer interface. The enormous increase in light and current through the amalgam devices compared to those using pure Hg demonstrate that less than 1 ML of a metal with a low work function at the polymer-cathode interface can have a dramatic effect on the performance of the devices. Devices with a liquid Ca amalgam cathode showed an increase of the current (by 50%) and brightness (80%) compared to devices with an evaporated Ca cathode, which is ascribed to reduced diffusion of Ca into the emissive PPV laye