475 research outputs found

    Simple method for predicting viscosity of gas mixtures

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    Method is derived from the Chapman-enskog theory which describes viscosities at low-to-moderate pressures. Mixtures of nonpolar gases require the viscosities and molecular weights of the constituents in addition to the mixture composition. Dipole moments, boiling points and liquid boiling point densities are also needed with polar gases

    Ignition kinetics of the carbon monoxide-oxygen reaction

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    Ignition kinetics of carbon monoxide-oxygen reactio

    Transport Properties of High Temperature Gases

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    Transport properties of high temperature gase

    Transport properties of dilute gas mixtures

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    Transport properties of dilute binary gas mixture

    Carbon monoxide oxidation rates computed for automobile thermal reactor conditions

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    Carbon monoxide oxidation rates in thermal reactors for exhaust manifolds are computed by integrating differential equations for system of twenty-nine reversible chemical reactions. Reactors are noncatalytic replacements for conventional exhaust manifolds and are a system for reducing carbon monoxide and hydrocarbons in automobile exhausts

    Shock tube measurements of growth constants in the branched chain formaldehyde-carbon monoxide-oxygen system

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    Exponential free radical growth constants were measured for formaldehyde carbon monoxide-oxygen systems by monitoring the growth of oxygen atom concentration as manifested by CO flame band emission. Data were obtained over the temperature range of 1200 to 2000 K. The data were analyzed using a formaldehyde oxidation mechanism involving 12 elementary reaction steps. The computed growth constants are roughly in accord with experimental values, but are much more temperature dependent. The data was also analyzed assuming formaldehyde is rapidly decomposed to carbon monoxide and hydrogen. Growth constants computed for the resulting carbon monoxide hydrogen oxygen mixtures have a temperature dependence similar to experiments; however, for most mixtures, the computed growth constants were larger than experimental values

    Carbon monoxide oxidation rates computed for automobile exhaust manifold reactor conditions

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    Carbon monoxide oxidation rates for automobile exhaust manifold reactor condition

    Shock tube measurements of growth constants in the branched-chain ethane-carbon monoxide-oxygen system

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    Exponential free radical growth constants have been measured for ethane carbon monoxide oxygen mixtures by monitoring the growth of oxygen atom concentration as manifested by CO flame band emission. Data were obtained over the temperature range of 1200 to 1700 K. The data were analyzed using an ethane oxidation mechanism involving seven elementary reaction steps. Calculated growth constants were close to experimental values at lower temperatures, up to about 1400 K, but at higher temperatures computed growth constants were considerably smaller than experiment. In attempts to explain these results additional branching reactions were added to the mechanism. However, these additional reactions did not appreciably change calculated growth constants
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