96 research outputs found
Improving HTc Josephson Junctions (HTc JJ) by annealing: the role of vacancy-interstitial annihilation
We have studied the annealing effect in transport properties of High
temperature Josephson Junctions (HTc JJ) made by ion irradiation. Low
temperature annealing (80 degrees Celsius) increases the JJ transition
temperature (TJ) and the Ic.Rn product, where Ic is the critical current and Rn
the normal resistance. We found that the spread in JJ characteristics can be
lowered by sufficient long annealing times. Using random walk numerical
simulations, we showed that the characteristic annealing time and the evolution
of the spread in JJ characteristics can be explained by a vacancy-interstitial
annihilation process rather than by an oxygen diffusion one.Comment: 7 pages and 3 figures submitted to Applied Physics Letter
Study and optimization of ion-irradiated High-Tc Josephson nanoJunctions by Monte Carlo simulations
High Tc Josephson nanoJunctions (HTc JnJ) made by ion irradiation have
remarkable properties for technological applications. However, the spread in
their electrical characteristics increases with the ion dose. We present a
simple model to explain the JnJ inhomogeneities, which accounts quantitatively
for experimental data. The spread in the slit's width of the irradiation mask
is the limiting factor.Monte Carlo simulations have been performed using
different irradiation conditions to study their influence on the spread of the
JnJ charcateristics. A "universal" behavior has been evidenced, which allows to
propose new strategies to optimize JnJ reproducibility.Comment: 14 pages, 6 Figures. accepted in Journal of Applied Physic
Unusual magneto-transport of YBa2Cu3O7-d films due to the interplay of anisotropy, random disorder and nanoscale periodic pinning
We study the general problem of a manifold of interacting elastic lines whose
spatial correlations are strongly affected by the competition between random
and ordered pinning. This is done through magneto-transport experiments with
YBa2Cu3O7-d thin films that contain a periodic vortex pinning array created via
masked ion irradiation, in addition to the native random pinning. The strong
field-matching effects we observe suggest the prevalence of periodic pinning,
and indicate that at the matching field each vortex line is bound to an
artificial pinning site. However, the vortex-glass transition dimensionality,
quasi-2D instead of the usual 3D, evidences reduced vortex-glass correlations
along the vortex line. This is also supported by an unusual angular dependence
of the magneto-resistance, which greatly differs from that of Bose-glass
systems. A quantitative analysis of the angular magnetoresistance allows us to
link this behaviour to the enhancement of the system anisotropy, a collateral
effect of the ion irradiation
Electron-Doped Manganese Perovskites: The Polaronic State
Using the Lanczos method in linear chains we study the ground state of the
double exchange model including an antiferromagnetic super-exchange in the low
concentration limit. We find that this ground state is always inhomogeneous,
containig ferromagnetic polarons. The extention of the polaron spin distortion,
the dispersion relation and their trapping by impurities, are studied for
diferent values of the super exchange interaction and magnetic field. We also
find repulsive polaron polaron interaction.Comment: 4 pages, 6 embedded figure
A surge in obsidian exploitation more than 1.2 million years ago at Simbiro III (Melka Kunture, Upper Awash, Ethiopia)
Pleistocene archaeology records the changing behaviour and capacities of early hominins. These behavioural changes, for example, to stone tools, are commonly linked to environmental constraints. It has been argued that, in earlier times, multiple activities of everyday life were all uniformly conducted at the same spot. The separation of focused activities across different localities, which indicates a degree of planning, according to this mindset characterizes later hominins since only 500,000 years ago. Simbiro III level C, in the upper Awash valley of Ethiopia, allows us to test this assumption in its assemblage of stone tools made only with obsidian, dated to more than 1.2 million years (Myr) old. Here we first reconstruct the palaeoenvironment, showing that the landscape was seasonally flooded. Following the deposition of an accumulation of obsidian cobbles by a meandering river, hominins began to exploit these in new ways, producing large tools with sharp cutting edges. We show through statistical analysis that this was a focused activity, that very standardized handaxes were produced and that this was a stone-tool workshop. We argue that at Simbiro III, hominins were doing much more than simply reacting to environmental changes; they were taking advantage of new opportunities, and developing new techniques and new skills according to them
Heterogeneity Governs 3D-Cultures of Clinically Relevant Microbial Communities
The intrinsic heterogeneity of bacterial niches should be retained in in vitrocultures to represent the complex microbial ecology. As a case study,mucin-containing hydrogels -CF-Mu3Gel - are generated by diffusion-inducedgelation, bioinspired on cystic fibrosis (CF) mucus, and a microbial nichechallenging current therapeutic strategies. At breathing frequency, CF-Mu3Gelexhibits aG′andG′′equal to 24 and 3.2 Pa, respectively. Notably, CF-Mu3Gelexhibits structural gradients with a gradual reduction of oxygen tensionacross its thickness (280–194μmol L−1). Over the culture period, a steepdecline in oxygen concentration occurs just a few millimeters below theair–mucus interface in CF-Mu3Gel, similar to those of CF airway mucus.Importantly, the distinctive features of CF-Mu3Gel significantly influencebacterial organization and antimicrobial tolerance in mono- and co-cultures ofStaphylococcus aureusandPseudomonas aeruginosathat standard culturesare unable to emulate. The antimicrobial susceptibility determined inCF-Mu3Gel corroborates the mismatch on the efficacy of antimicrobialtreatment between planktonically cultured bacteria and those in patients.With this example-based research, new light is shed on the understanding ofhow the substrate influences microbial behavior, paving the way for improvedfundamental microbiology studies and more effective drug testing anddevelopment
Non-adiabatic small polaron hopping in the n=3 Ruddlesden-Popper compound Ca4Mn3O10
Magnetotransport properties of the compound Ca4Mn3O10 are interpreted in
terms of activated hopping of small magnetic polarons in the non-adiabatic
regime. Polarons are most likely formed around Mn3+ sites created by oxygen
substoichiometry. The application of an external field reduces the size of the
magnetic contribution to the hopping barrier and thus produces an increase in
the conductivity .We argue that the change in the effective activation energy
around TN is due to the crossover to VRH conduction as antiferromagnetic order
sets in.Comment: 29 pages, 7 figure
Methyl methacrylate and respiratory sensitization: A Critical review
Methyl methacrylate (MMA) is a respiratory irritant and dermal sensitizer that has been associated with occupational asthma in a small number of case reports. Those reports have raised concern that it might be a respiratory sensitizer. To better understand that possibility, we reviewed the in silico, in chemico, in vitro, and in vivo toxicology literature, and also epidemiologic and occupational medicine reports related to the respiratory effects of MMA. Numerous in silico and in chemico studies indicate that MMA is unlikely to be a respiratory sensitizer. The few in vitro studies suggest that MMA has generally weak effects. In vivo studies have documented contact skin sensitization, nonspecific cytotoxicity, and weakly positive responses on local lymph node assay; guinea pig and mouse inhalation sensitization tests have not been performed. Cohort and cross-sectional worker studies reported irritation of eyes, nose, and upper respiratory tract associated with short-term peaks exposures, but little evidence for respiratory sensitization or asthma. Nineteen case reports described asthma, laryngitis, or hypersensitivity pneumonitis in MMA-exposed workers; however, exposures were either not well described or involved mixtures containing more reactive respiratory sensitizers and irritants.The weight of evidence, both experimental and observational, argues that MMA is not a respiratory sensitizer
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