Persistence of coherent quantum dynamics at strong dissipation

The quantum dynamics of a two state system coupled to a bosonic reservoir with sub-Ohmic spectral density is investigated for strong friction. Numerically exact path integral Monte Carlo methods reveal that in contrast to conventional expectations, coherent dynamics never turns into incoherent decay for a broad class of spectral distributions. Coherences associated with substantial system-reservoir entanglement exist in non-equilibrium even when strong dissipation makes the thermodynamic state of the system to behave essentially classical. This may be of relevance for current experiments with nanoscale devices and bio-molecular aggregates.Comment: 5 pages, 5 figure

A test of "fluctuation theorem" in non-Markovian open quantum systems

We study fluctuation theorems for open quantum systems with a non-Markovian heat bath using the approach of quantum master equations and examine the physical quantities that appear in those fluctuation theorems. The approach of Markovian quantum master equations to the fluctuation theorems was developed by Esposito and Mukamel [Phys. Rev. E {\bf73}, 046129 (2006)]. We show that their discussion can be formally generalized to the case of a non-Markovian heat bath when the local system is linearly connected to a Gaussian heat bath with the spectrum distribution of the Drude form. We found by numerically simulating the spin-boson model in non-Markovian regime that the "detailed balance" condition is well satisfied except in a strongly non-equilibrium transient situation, and hence our generalization of the definition of the "entropy production" is almost always legitimate. Therefore, our generalization of the fluctuation theorem seems meaningful in wide regions.Comment: 21 pages, 5 figure

High-order noise filtering in nontrivial quantum logic gates

Treating the effects of a time-dependent classical dephasing environment during quantum logic operations poses a theoretical challenge, as the application of non-commuting control operations gives rise to both dephasing and depolarization errors that must be accounted for in order to understand total average error rates. We develop a treatment based on effective Hamiltonian theory that allows us to efficiently model the effect of classical noise on nontrivial single-bit quantum logic operations composed of arbitrary control sequences. We present a general method to calculate the ensemble-averaged entanglement fidelity to arbitrary order in terms of noise filter functions, and provide explicit expressions to fourth order in the noise strength. In the weak noise limit we derive explicit filter functions for a broad class of piecewise-constant control sequences, and use them to study the performance of dynamically corrected gates, yielding good agreement with brute-force numerics.Comment: Revised and expanded to include filter function terms beyond first order in the Magnus expansion. Related manuscripts available from http://www.physics.usyd.edu.au/~mbiercu

Dissipative Dynamics with Trapping in Dimers

The trapping of excitations in systems coupled to an environment allows to study the quantum to classical crossover by different means. We show how to combine the phenomenological description by a non-hermitian Liouville-von Neumann Equation (LvNE) approach with the numerically exact path integral Monte-Carlo (PIMC) method, and exemplify our results for a system of two coupled two-level systems. By varying the strength of the coupling to the environment we are able to estimate the parameter range in which the LvNE approach yields satisfactory results. Moreover, by matching the PIMC results with the LvNE calculations we have a powerful tool to extrapolate the numerically exact PIMC method to long times.Comment: 5 pages, 2 figure

Coherent and incoherent dynamics in excitonic energy transfer: correlated fluctuations and off-resonance effects

We study the nature of the energy transfer process within a pair of coupled two-level systems (donor and acceptor) subject to interactions with the surrounding environment. Going beyond a standard weak-coupling approach, we derive a master equation within the polaron representation that allows for investigation of both weak and strong system-bath couplings, as well as reliable interpolation between these two limits. With this theory, we are then able to explore both coherent and incoherent regimes of energy transfer within the donor-acceptor pair. We elucidate how the degree of correlation in the donor and acceptor fluctuations, the donor-acceptor energy mismatch, and the range of the environment frequency distribution impact upon the energy transfer dynamics. In the resonant case (no energy mismatch) we describe in detail how a crossover from coherent to incoherent transfer dynamics occurs with increasing temperature [A. Nazir, Phys. Rev. Lett. 103, 146404 (2009)], and we also explore how fluctuation correlations are able to protect coherence in the energy transfer process. We show that a strict crossover criterion is harder to define when off-resonance, though we find qualitatively similar population dynamics to the resonant case with increasing temperature, while the amplitude of coherent population oscillations also becomes suppressed with growing site energy mismatch.Comment: 14 pages, 7 figures, builds upon PRL 103, 146404 (2009) (arXiv:0906.0592). Comments welcome. V2 - Section IV shortened to improve presentation, references updated, new Imperial College affiliation added for A. Nazir. Published versio

Fighting Decoherence by Feedback-controlled Dissipation

Repeated closed-loop control operations acting as piecewise-constant Liouville superoperators conditioned on the outcomes of regularly performed measurements may effectively be described by a fixed-point iteration for the density matrix. Even when all Liouville superoperators point to the completely mixed state, feedback of the measurement result may lead to a pure state, which can be interpreted as selective dampening of undesired states. Using a microscopic model, we exemplify this for a single qubit, which can be purified in an arbitrary single-qubit state by tuning the measurement direction and two qubits that may be purified towards a Bell state by applying a special continuous two-local measurement. The method does not require precise knowledge of decoherence channels and works for large reservoir temperatures provided measurement, processing, and control can be implemented in a continuous fashion.Comment: to appear in PR

Hafnium carbide formation in oxygen deficient hafnium oxide thin films

On highly oxygen deficient thin films of hafnium oxide (hafnia, HfO$_{2-x}$) contaminated with adsorbates of carbon oxides, the formation of hafnium carbide (HfC$_x$) at the surface during vacuum annealing at temperatures as low as 600 {\deg}C is reported. Using X-ray photoelectron spectroscopy the evolution of the HfC$_x$ surface layer related to a transformation from insulating into metallic state is monitored in situ. In contrast, for fully stoichiometric HfO$_2$ thin films prepared and measured under identical conditions, the formation of HfC$_x$ was not detectable suggesting that the enhanced adsorption of carbon oxides on oxygen deficient films provides a carbon source for the carbide formation. This shows that a high concentration of oxygen vacancies in carbon contaminated hafnia lowers considerably the formation energy of hafnium carbide. Thus, the presence of a sufficient amount of residual carbon in resistive random access memory devices might lead to a similar carbide formation within the conducting filaments due to Joule heating

Nakajima-Zwanzig versus time-convolutionless master equation for the non-Markovian dynamics of a two-level system

We consider the exact reduced dynamics of a two-level system coupled to a bosonic reservoir, further obtaining the exact time-convolutionless and Nakajima-Zwanzig non-Markovian equations of motion. The considered system includes the damped and undamped Jaynes-Cummings model. The result is obtained by exploiting an expression of quantum maps in terms of matrices and a simple relation between the time evolution map and time-convolutionless generator as well as Nakajima-Zwanzig memory kernel. This non-perturbative treatment shows that each operator contribution in Lindblad form appearing in the exact time-convolutionless master equation is multiplied by a different time dependent function. Similarly, in the Nakajima-Zwanzig master equation each such contribution is convoluted with a different memory kernel. It appears that depending on the state of the environment the operator structures of the two set of equations of motion can exhibit important differences.Comment: 12 pages, no figure

Dynamical typicality of quantum expectation values

We show that the vast majority of all pure states featuring a common expectation value of some generic observable at a given time will yield very similar expectation values of the same observable at any later time. This is meant to apply to Schroedinger type dynamics in high dimensional Hilbert spaces. As a consequence individual dynamics of expectation values are then typically well described by the ensemble average. Our approach is based on the Hilbert space average method. We support the analytical investigations with numerics obtained by exact diagonalization of the full time-dependent Schroedinger equation for some pertinent, abstract Hamiltonian model. Furthermore, we discuss the implications on the applicability of projection operator methods with respect to initial states, as well as on irreversibility in general.Comment: 4 pages, 1 figure, accepted for publication in Phys. Rev. Let

The equilibrium states of open quantum systems in the strong coupling regime

In this work we investigate the late-time stationary states of open quantum systems coupled to a thermal reservoir in the strong coupling regime. In general such systems do not necessarily relax to a Boltzmann distribution if the coupling to the thermal reservoir is non-vanishing or equivalently if the relaxation timescales are finite. Using a variety of non-equilibrium formalisms valid for non-Markovian processes, we show that starting from a product state of the closed system = system + environment, with the environment in its thermal state, the open system which results from coarse graining the environment will evolve towards an equilibrium state at late-times. This state can be expressed as the reduced state of the closed system thermal state at the temperature of the environment. For a linear (harmonic) system and environment, which is exactly solvable, we are able to show in a rigorous way that all multi-time correlations of the open system evolve towards those of the closed system thermal state. Multi-time correlations are especially relevant in the non-Markovian regime, since they cannot be generated by the dynamics of the single-time correlations. For more general systems, which cannot be exactly solved, we are able to provide a general proof that all single-time correlations of the open system evolve to those of the closed system thermal state, to first order in the relaxation rates. For the special case of a zero-temperature reservoir, we are able to explicitly construct the reduced closed system thermal state in terms of the environmental correlations.Comment: 20 pages, 2 figure