A new approach in the use of SIT in determining the dependence on ionic strength of activity coefficients. Application to some chloride salts of interest in the speciation of natural fluids

AbstractThis paper describes a modified version of the SIT (Specific ion Interaction Theory) method and its use in determining the dependence on ionic strength of activity coefficients. In the new approach the interaction coefficients (e) are not constant but depend on ionic strength (I /mol kg-1) according to the simple relationship:e = e∞+ (e0 - e∞) / (l + 1)where e0 and are true constants for I→ 0 and l→ ∞, respectively. To check the two parameter SIT equation, we calculated e0 and for the activity coefficients of HCl, LiCl, NaCl, KCl, MgCl2, CaCl2 and SrCl2, in a wide ionic strength range (0.1 ≤ l/mol kg-1 ≤ 4.5, for KCl; 0.1 ≤ l/mol kg-1 ≤ 6, for HCl, LiCl, NaCl; 0.3 ≤ l/mol kg-1 ≤ 12, for SrCl2; 0.3 ≤ l/mol kg-1 ≤ 15, for MgCl2; 0.3 ≤ l/mol kg-1 ≤ 18, for CaCl2). Results show that the γ values calculated using this approach fit quite well over the whole I-range for all the electrolytes considered. Comparison is made with the analogous one parameter SIT equation. The temperature coefficients of inter..

Bernoulli type polynomials on Umbral Algebra

The aim of this paper is to investigate generating functions for modification of the Milne-Thomson's polynomials, which are related to the Bernoulli polynomials and the Hermite polynomials. By applying the Umbral algebra to these generating functions, we provide to deriving identities for these polynomials

The Gould-Hopper Polynomials in the Novikov-Veselov equation

We use the Gould-Hopper (GH) polynomials to investigate the Novikov-Veselov (NV) equation. The root dynamics of the $\sigma$-flow in the NV equation is studied using the GH polynomials and then the Lax pair is found. In particulr, when $N=3,4,5$, one can get the Gold-fish model. The smooth rational solutions of the NV equation are also constructed via the extended Moutard transformation and the GH polynomials. The asymptotic behavior is discussed and then the smooth rational solution of the Liouville equation is obtained.Comment: 22 pages, no figur

"Green oncology": a new paradigm for medical oncology

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Breast cancer "tailored follow-up" in Italian oncology units: a web-based survey

urpose: Breast cancer follow-up procedures after primary treatment are still a controversial issue. Aim of this study was to investigate, through a web-based survey, surveillance methodologies selected by Italian oncologists in everyday clinical practice. Methods: Referents of Italian medical oncology units were invited to participate to the study via e-mail through the SurveyMonkey website. Participants were asked how, in their institution, exams of disease staging and follow-up are planned in asymptomatic women and if surveillance continues beyond the 5th year. Results: Between February and May 2013, 125 out of 233 (53.6%) invited referents of Italian medical oncology units agreed to participate in the survey. Ninety-seven (77.6%) referents state that modalities of breast cancer follow-up are planned according to the risk of disease progression at diagnosis and only 12 (9.6%) oncology units apply the minimal follow-up procedures according to international guidelines. Minimal follow-up is never applied in high risk asymptomatic women. Ninety-eight (78.4%) oncology units continue follow-up in all patients beyond 5 years. Conclusions: Our survey shows that 90.4% of participating Italian oncology units declare they do not apply the minimal breast cancer follow-up procedures after primary treatment in asymptomatic women, as suggested by national and international guidelines. Interestingly, about 80.0% of interviewed referents performs the so called "tailored follow-up", high intensity for high risk, low intensity for low risk patients. There is an urgent need of randomized clinical trials able to determine the effectiveness of risk-based follow-up modalities, their ideal frequency and persistence in time