51 research outputs found
Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst
A palladacyclic precatalyst is employed to cleanly generate a highly active XantPhos-ligated Pd-catalyst. Its use in low temperature aminocarbonylations of (hetero)aryl bromides provides access to a range of challenging products in good to excellent yields with low catalyst loading and only a slight excess of CO. Some products are unattainable by traditional carbonylative coupling.National Institutes of Health (U.S.) (Award GM46059)Danish National Research Foundation (Grant DNRF59)Villum FoundationDanish Council for Independent Researc
Palladium-Catalyzed Oxidative Domino Carbocyclization–Carbonylation–Alkynylation of Enallenes
Palladium‐Catalyzed Carbonylative Heck Reaction of Aryl Bromides with Vinyl Ethers to 3‐Alkoxy Alkenones and Pyrazoles
Hydroxy- and alkoxycarbonylation of aryl iodides catalyzed by polymer-supported palladium
Quinolin-8-yl Formate: A New Option for Small-Scale Carbonylation Reactions in Microwave Reactors
2-Pyridyl substituents enhance the activity of palladium–phospha-adamantane catalysts for the methoxycarbonylation of phenylacetylene
Synthesis of 1-((4-methoxyphenyl)-3-alkynes)-1 H -pyrrole-2,5-diones and functionalization to triazoles
- …