442 research outputs found
Validation of the Wiedemann-Franz Law in solid and molten tungsten above 2000 K through thermal conductivity measurements via steady state temperature differential radiometry
We measure the thermal conductivity of solid and molten tungsten using Steady
State Temperature Differential Radiometry. We demonstrate that the thermal
conductivity can be well described by application of Wiedemann-Franz Law to
electrical resistivity data, thus suggesting the validity of Wiedemann-Franz
Law to capture the electronic thermal conductivity of metals in their molten
phase. We further support this conclusion using ab initio molecular dynamics
simulations with a machine-learned potential. Our results show that at these
high temperatures, the vibrational contribution to thermal conductivity is
negligible compared to the electronic component
Significance of perylene for source allocation of terrigenous organic matter in aquatic sediments.
Author Posting. © American Chemical Society, 2019. This is an open access article published under an ACS AuthorChoice License. The definitive version was published in Environmental Science and Technology 53(14), (2019):8244-8251, doi:10.1021/acs.est.9b02344.Perylene is a frequently abundant, and sometimes the only polycyclic aromatic hydrocarbon (PAH) in aquatic sediments, but its origin has been subject of a longstanding debate in geochemical research and pollutant forensics because its historical record differs markedly from typical anthropogenic PAHs. Here we investigate whether perylene serves as a source-specific molecular marker of fungal activity in forest soils. We use a well-characterized sedimentary record (1735 to 1999) from the anoxic-bottom waters of the Pettaquamscutt River basin, RI, USA to examine mass accumulation rates and isotope records of perylene, and compare them with total organic carbon and the anthropogenic PAH fluoranthene. We support our arguments with radiocarbon (14C) data of higher plant leaf-wax n-alkanoic acids. Isotope-mass balance calculations of perylene and n-alkanoic acids indicate that ~40 % of sedimentary organic matter is of terrestrial origin. Further, both terrestrial markers are pre-aged on millennial time-scales prior to burial in sediments and insensitive to elevated 14C concentrations following nuclear weapons testing in the mid-20th Century. Instead, changes coincide with enhanced erosional flux during urban sprawl. These findings suggest that perylene is definitely a product of soil derived fungi, and a powerful chemical tracer to study spatial and temporal connectivity between terrestrial and aquatic environments.We thank John King, Sean Sylva, Brad Hubeny, Peter Sauer, and Jim Broda for their help in sampling; Carl Johnson and Daniel Montluçon for their incessant help with analyses; as well as Mark Yunker for critical discussion on the perils of perylene. Professor Phil Meyers and two anonymous reviewers provided comments that improved the quality of the manuscript. U.M.H. acknowledges the Swiss National Science Foundation for his postdoctoral fellowship and T.I.E. and K.A.H. acknowledges the NSF for research grants CHE-0089172 and OCE-9708478.2020-06-1
Crossover Scaling in Dendritic Evolution at Low Undercooling
We examine scaling in two-dimensional simulations of dendritic growth at low
undercooling, as well as in three-dimensional pivalic acid dendrites grown on
NASA's USMP-4 Isothermal Dendritic Growth Experiment. We report new results on
self-similar evolution in both the experiments and simulations. We find that
the time dependent scaling of our low undercooling simulations displays a
cross-over scaling from a regime different than that characterizing Laplacian
growth to steady-state growth
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Report from the First Snake Genomics and Integrative Biology Meeting
This report summarizes the proceedings of the 1st Snake Genomics and Integrative Biology Meeting held in Vail, CO USA, 5-8 October 2011. The meeting had over twenty registered participants, and was conducted as a single session of presentations. Goals of the meeting included coordination of genomic data collection and fostering collaborative interactions among researchers using snakes as model systems.Organismic and Evolutionary Biolog
Report from the First Snake Genomics and Integrative Biology Meeting
This report summarizes the proceedings of the 1st Snake Genomics and Integrative Biology Meeting held in Vail, CO USA, 5-8 October 2011. The meeting had over twenty registered participants, and was conducted as a single session of presentations. Goals of the meeting included coordination of genomic data collection and fostering collaborative interactions among researchers using snakes as model systems
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