A multi-objective genetic algorithm for the design of pressure swing adsorption

Pressure Swing Adsorption (PSA) is a cyclic separation process, more advantageous over other separation options for middle scale processes. Automated tools for the design of PSA processes would be beneficial for the development of the technology, but their development is a difficult task due to the complexity of the simulation of PSA cycles and the computational effort needed to detect the performance at cyclic steady state. We present a preliminary investigation of the performance of a custom multi-objective genetic algorithm (MOGA) for the optimisation of a fast cycle PSA operation, the separation of air for N2 production. The simulation requires a detailed diffusion model, which involves coupled nonlinear partial differential and algebraic equations (PDAEs). The efficiency of MOGA to handle this complex problem has been assessed by comparison with direct search methods. An analysis of the effect of MOGA parameters on the performance is also presented

UTCI field measurements in an urban park in Florence (Italy)

The aim of this study is to evaluate human thermal comfort in different green area settings in the city of Florence by using the Universal Thermal Climate Index (UTCI). Field measurements of air temperature, solar radiation, relative humidity, wind speed and black globe thermometer were collected during hot summer days in various parts of Cascine Park, the biggest urban park in Florence (Italy). UTCI was evaluated over different surfaces (asphalt, gravel and grass) completely exposed to the sun or shaded by a large lime tree (Tilia × europaea). The results showed strong differences in UTCI values depending on the exposure to tree shade, while no significant difference was found among ground-cover materials when all surfaces were equally exposed to solar radiation. Future studies are needed to investigate the microclimatic effects of different tree species on UTCI

Air gasification of digestate and its co-gasification with residual biomass in a pilot scale rotary kiln

In this study energy recovery of digestate from a biogas plant was investigated via air gasification. Gasification tests were executed in a pilot scale rotary kiln plant having a nominal biomass feeding rate of about 20 kg/h. The equivalence ratio was varied from 0.22 to 0.39 with the goal to approach the autothermal condition. Tests were carried out for 5 h in steady state condition. Syngas composition, char and gas yields were measured. To improve the cold gas efficiency of the process, a mixture of digestate and almond shells (60:40 wt%) was gasified. Autothermal condition was reached with the mixture using equivalence ratio of 0.30 where the corresponding cold gas efficiency achieved the maximum value of 55%. The raw gas had a lower heating value of 4–5 MJ/Nm3. To evaluate possible improvements in the produced gas properties, in this work the effect of steam injection was also investigated

Translational nucleosome positioning: A computational study

Biological and Soft Matter Physic

CO2 adsorption on different organo-­‐modified SBA-­‐15 silicas: a multidisciplinary study on the effects of basic surface groups

Hybrid organic–inorganic SBA-15 silicas functionalized with increasing amounts of amino groups were studied in this work aiming to evaluate the effects of their physico-chemical properties on CO2 capture ability. Three different amino-silane species were used: 3-aminopropyltriethoxysilane (APTS), 3-(2-aminoethyl)- aminopropyltrimethoxysilane (EAPTS) and 3-[2-(2-aminoethyl)aminoethyl] aminopropyltrimethoxysilane (PAPTS). More specifically, samples were prepared by using two methods, following a post-synthesis grafting procedure and a one-pot preparation method. Experimental and computational techniques were used to study the structural and textural properties of the obtained samples and their surface species in relation to the adopted preparation method. For the most reactive samples, additional hints on the interactions of organosilane species with the silica surface were obtained by a combination of IR and SS-NMR spectroscopy, with particular emphasis on the effects of the silane chain length on the mobility of the organic species. Advanced complementary solid-state NMR techniques provided deeper information on the interactions of organosilane species with the silica surface. Finally, the amount of CO2 adsorbed was estimated by comparing the classical microcalorimetric analysis method with a new type of screening test, the Zero Length Column analysis, which is able to evaluate small amounts of samples in a very short time and the adsorption properties of the adsorbents. The reactivity of the amino-modified silica samples is deeply influenced by both the preparation route and by the type of organosilane used for the functionalization of the materials. In particular, samples prepared by the post-synthesis grafting procedure and containing higher amount of amino groups in the chain are more reactive, following the order PAPTS 4 EAPTS 4 APTS