Theory of adhesion: role of surface roughness

We discuss how surface roughness influence the adhesion between elastic solids. We introduce a Tabor number which depends on the length scale or magnification, and which gives information about the nature of the adhesion at different length scales. We consider two limiting cases relevant for (a) elastically hard solids with weak adhesive interaction (DMT-limit) and (b) elastically soft solids or strong adhesive interaction (JKR-limit). For the former cases we study the nature of the adhesion using different adhesive force laws ($F\sim u^{-n}$, $n=1.5-4$, where $u$ is the wall-wall separation). In general, adhesion may switch from DMT-like at short length scales to JKR-like at large (macroscopic) length scale. We compare the theory predictions to the results of exact numerical simulations and find good agreement between theory and the simulation results

Molecular dynamics study of contact mechanics: contact area and interfacial separation from small to full contact

We report a molecular dynamics study of the contact between a rigid solid with a randomly rough surface and an elastic block with a flat surface. We study the contact area and the interfacial separation from small contact (low load) to full contact (high load). For small load the contact area varies linearly with the load and the interfacial separation depends logarithmically on the load. For high load the contact area approaches to the nominal contact area (i.e., complete contact), and the interfacial separation approaches to zero. The present results may be very important for soft solids, e.g., rubber, or for very smooth surfaces, where complete contact can be reached at moderate high loads without plastic deformation of the solids.Comment: 4 pages,5 figure

Contact mechanics with adhesion: Interfacial separation and contact area

We study the adhesive contact between elastic solids with randomly rough, self affine fractal surfaces. We present molecular dynamics (MD) simulation results for the interfacial stress distribution and the wall-wall separation. We compare the MD results for the relative contact area and the average interfacial separation, with the prediction of the contact mechanics theory of Persson. We find good agreement between theory and the simulation results. We apply the theory to the system studied by Benz et al. involving polymer in contact with polymer, but in this case the adhesion gives only a small modification of the interfacial separation as a function of the squeezing pressure.Comment: 5 pages, 4 figure

A national multiple baseline cohort study of mental health conditions in early adolescence and subsequent educational outcomes in New Zealand

Young people experiencing mental health conditions are vulnerable to poorer educational outcomes for many reasons, including: social exclusion, stigma, and limited in-school support. Using a near-complete New Zealand population administrative database, this prospective cohort study aimed to quantify differences in educational attainment (at ages 15-16 years) and school suspensions (over ages 13-16 years), between those with and without a prior mental health condition. The data included five student cohorts, each starting secondary school from 2013 to 2017 respectively (N=272,901). Both internalising and externalising mental health conditions were examined. Overall, 6.8% had a mental health condition. Using adjusted modified Poisson regression analyses, those with prior mental health conditions exhibited lower rates of attainment (IRR=0.87, 95% CI 0.86-0.88) and higher rates of school suspensions (IRR=1.63, 95% CI 1.57-1.70) by age 15-16 years. Associations were stronger among those exhibiting behavioural conditions, compared to emotional conditions, in line with previous literature. These findings highlight the importance of support for young people experiencing mental health conditions at this crucial juncture in their educational pathway. While mental health conditions increase the likelihood of poorer educational outcomes, deleterious outcomes were not a necessary sequalae. In this study, most participants with mental health conditions had successful educational outcomes

Magnetic friction in Ising spin systems

A new contribution to friction is predicted to occur in systems with magnetic correlations: Tangential relative motion of two Ising spin systems pumps energy into the magnetic degrees of freedom. This leads to a friction force proportional to the area of contact. The velocity and temperature dependence of this force are investigated. Magnetic friction is strongest near the critical temperature, below which the spin systems order spontaneously. Antiferromagnetic coupling leads to stronger friction than ferromagnetic coupling with the same exchange constant. The basic dissipation mechanism is explained. If the coupling of the spin system to the heat bath is weak, a surprising effect is observed in the ordered phase: The relative motion acts like a heat pump cooling the spins in the vicinity of the friction surface.Comment: 4 pages, 4 figure

Interfacial separation between elastic solids with randomly rough surfaces: comparison of experiment with theory

We study the average separation between an elastic solid and a hard solid with a nominal flat but randomly rough surface, as a function of the squeezing pressure. We present experimental results for a silicon rubber (PDMS) block with a flat surface squeezed against an asphalt road surface. The theory shows that an effective repulse pressure act between the surfaces of the form p proportional to exp(-u/u0), where u is the average separation between the surfaces and u0 a constant of order the root-mean-square roughness, in good agreement with the experimental results.Comment: 6 pages, 10 figure

Stochastic theory of large-scale enzyme-reaction networks: Finite copy number corrections to rate equation models

Chemical reactions inside cells occur in compartment volumes in the range of atto- to femtolitres. Physiological concentrations realized in such small volumes imply low copy numbers of interacting molecules with the consequence of considerable fluctuations in the concentrations. In contrast, rate equation models are based on the implicit assumption of infinitely large numbers of interacting molecules, or equivalently, that reactions occur in infinite volumes at constant macroscopic concentrations. In this article we compute the finite-volume corrections (or equivalently the finite copy number corrections) to the solutions of the rate equations for chemical reaction networks composed of arbitrarily large numbers of enzyme-catalyzed reactions which are confined inside a small sub-cellular compartment. This is achieved by applying a mesoscopic version of the quasi-steady state assumption to the exact Fokker-Planck equation associated with the Poisson Representation of the chemical master equation. The procedure yields impressively simple and compact expressions for the finite-volume corrections. We prove that the predictions of the rate equations will always underestimate the actual steady-state substrate concentrations for an enzyme-reaction network confined in a small volume. In particular we show that the finite-volume corrections increase with decreasing sub-cellular volume, decreasing Michaelis-Menten constants and increasing enzyme saturation. The magnitude of the corrections depends sensitively on the topology of the network. The predictions of the theory are shown to be in excellent agreement with stochastic simulations for two types of networks typically associated with protein methylation and metabolism.Comment: 13 pages, 4 figures; published in The Journal of Chemical Physic

Towards a modeling of the time dependence of contact area between solid bodies

I present a simple model of the time dependence of the contact area between solid bodies, assuming either a totally uncorrelated surface topography, or a self affine surface roughness. The existence of relaxation effects (that I incorporate using a recently proposed model) produces the time increase of the contact area $A(t)$ towards an asymptotic value that can be much smaller than the nominal contact area. For an uncorrelated surface topography, the time evolution of $A(t)$ is numerically found to be well fitted by expressions of the form [$A(\infty)-A(t)]\sim (t+t_0)^{-q}$, where the exponent $q$ depends on the normal load $F_N$ as $q\sim F_N^{\beta}$, with $\beta$ close to 0.5. In particular, when the contact area is much lower than the nominal area I obtain $A(t)/A(0) \sim 1+C\ln(t/t_0+1)$, i.e., a logarithmic time increase of the contact area, in accordance with experimental observations. The logarithmic increase for low loads is also obtained analytically in this case. For the more realistic case of self affine surfaces, the results are qualitatively similar.Comment: 18 pages, 9 figure