4,523 research outputs found
Aggregation of metallochlorophylls - Examination by spectroscopy
Nuclear magnetic resonance measurements determine which metallochlorophylls, besides magnesium-containing chlorophylls, possess coordination aggregation properties. Infrared spectroscopy reveals that only zinc pheophytin and zinc methyl pheophorbide showed significant coordination aggregation, whereas divalent nickel and copper did not
Thermodynamic Properties of the Spin-1/2 Antiferromagnetic ladder Cu2(C2H12N2)2Cl4 under Magnetic Field
Specific heat () measurements in the spin-1/2
Cu(CHN)Cl system under a magnetic field up to
are reported and compared to the results of numerical calculations
based on the 2-leg antiferromagnetic Heisenberg ladder. While the temperature
dependences of both the susceptibility and the low field specific heat are
accurately reproduced by this model, deviations are observed below the critical
field at which the spin gap closes. In this Quantum High Field phase,
the contribution of the low-energy quantum fluctuations are stronger than in
the Heisenberg ladder model. We argue that this enhancement can be attributed
to dynamical lattice fluctuations. Finally, we show that such a Heisenberg
ladder, for , is unstable, when coupled to the 3D lattice, against a
lattice distortion. These results provide an alternative explanation for the
observed low temperature ( -- ) phase (previously
interpreted as a 3D magnetic ordering) as a new type of incommensurate gapped
state.Comment: Minor changes, list of authors complete
Elementary Excitations in Quantum Antiferromagnetic Chains: Dyons, Spinons and Breathers
Considering experimental results obtained on three prototype compounds, TMMC,
CsCoCl3 (or CsCoBr3) and Cu Benzoate, we discuss the importance of non-linear
excitations in the physics of quantum (and classical) antiferromagnetic spin
chains.Comment: Invited at the International Symposium on Cooperative Phenomena of
Assembled Metal Complexes, November 15-17, 2001, Osaka, Japa
Daily and seasonal variations in the spatial distribution of zooplankton populations in relation to the physical structure in the Ligurian Sea Front
Results from five hydrographic and biological surveys at different seasons across the Ligurian Sea front, using horizontal continuous measurements and vertical profiles are presented. The vertical circulation across the front is described, and two divergences and one convergence are identified as permanent features from data. The key to find their location for each survey is given. The spatial patterns of 14 zooplankton taxa along the transect are established using variance analysis, principal component and correspondence analyses. The spatial distribution of each taxon is related to the physical structure, and the convection cells evidenced by the scheme appear as different biotopes. The daily variability of the spatial distributions is negligible compared to the annual variability. Distinctions are made between coastal species always inhabiting the peripheral (coastal zone) and others with distinct coastal, frontal and offshore distributions varying with the season. For the latter species the frontal zone is a preferential biotope during their seasonal growth period. Consequently the accumulation of organisms near the convergence cannot be created by only the dynamic causes. The role of biological processes in the observed distributions is discussed
Study on the neuronal circuits implicated in postural tremor and hypokinesia
The effect of various tegmentary lesions at the level of the pontomesenchphalon in monkeys on motor function was observed. The importance of the monoaminergic mechanisms of the brainstem is discussed. The results also show the importance of the descending tegmentary rubral system and the rubroolivocerebellar circuit in controlling peripheral motor activity. The destruction of the sensory motor cortex proves to be a more effective way of eliminating spontaneous or harmaline induced tremor than the complete interruption of the pyramidal system on the level of the cerebral peduncle
Legal Uncertainty and Land Disputes in the Peri-Urban Areas of Mozambique: Land Markets in Transition
The Government of Mozambique is considering legal changes in its land law and administration of state leasehold property-an enormous challenge given its past socialist history and the uncertainties created by its current transition to a private market economy. The present research sought to identify dispute causes and de facto processes of dispute resolution as one basis for gauging inadequacies in the current law and system of state land administration.Land Economics/Use,
Amp\`ere-Class Pulsed Field Emission from Carbon-Nanotube Cathodes in a Radiofrequency Resonator
Pulsed field emission from cold carbon-nanotube cathodes placed in a
radiofrequency resonant cavity was observed. The cathodes were located on the
backplate of a conventional -cell resonant cavity operating at
1.3-GHz and resulted in the production of bunch train with maximum average
current close to 0.7 Amp\`ere. The measured Fowler-Nordheim characteristic,
transverse emittance, and pulse duration are presented and, when possible,
compared to numerical simulations. The implications of our results to
high-average-current electron sources are briefly discussed.Comment: 5 pages, 6 figures; submitted to Applied Physics Letter
Charge Ordering and Spin Dynamics in NaV2O5
We report high-resolution neutron inelastic scattering experiments on the
spin excitations of NaV2O5. Below Tc, two branches associated with distinct
energy gaps are identified. From the dispersion and intensity of the spin
excitation modes, we deduce the precise zig-zag charge distribution on the
ladder rungs and the corresponding charge order (about 0.6). We argue that the
spin gaps observed in the low-T phase of this compound are primarily due to the
charge transfer.Comment: 4 pages, 5 figures, to appear in Phys. Rev. Let
From Skew-Cyclic Codes to Asymmetric Quantum Codes
We introduce an additive but not -linear map from
to and exhibit some of its interesting
structural properties. If is a linear -code, then is an
additive -code. If is an additive cyclic code then
is an additive quasi-cyclic code of index . Moreover, if is a module
-cyclic code, a recently introduced type of code which will be
explained below, then is equivalent to an additive cyclic code if is
odd and to an additive quasi-cyclic code of index if is even. Given any
-code , the code is self-orthogonal under the trace
Hermitian inner product. Since the mapping preserves nestedness, it can be
used as a tool in constructing additive asymmetric quantum codes.Comment: 16 pages, 3 tables, submitted to Advances in Mathematics of
Communication
Memory, learning and language in autism spectrum disorder
Background and aims: The ‘dual-systems’ model of language acquisition has been used by Ullman and colleagues to explain patterns of strength and weakness in the language of higher-functioning people with autism spectrum disorder (ASD). Specifically, intact declarative/explicit learning is argued to compensate for a deficit in non-declarative/implicit procedural learning, constituting an example of the so-called ‘see-saw’ effect. Ullman and Pullman (2015) extended their argument concerning a see-saw effect on language in ASD to cover other perceived anomalies of behaviour, including impaired acquisition of social skills. The aim of this paper is to present a critique of Ullman and colleagues’ claims, and to propose an alternative model of links between memory systems and language in ASD.
Main contribution: We argue that a 4-systems model of learning, in which intact semantic and procedural memory are used to compensate for weaknesses in episodic memory and perceptual learning, can better explain patterns of language ability across the autistic spectrum. We also argue that attempts to generalise the ‘impaired implicit learning/spared declarative learning’ theory to other behaviours in ASD are unsustainable.
Conclusions: Clinically significant language impairments in ASD are under-researched, despite their impact on everyday functioning and quality of life. The relative paucity of research findings in this area lays it open to speculative interpretation which may be misleading.
Implications: More research is need into links between memory/learning systems and language impairments across the spectrum. Improved understanding should inform therapeutic intervention, and contribute to investigation of the causes of language impairment in ASD with potential implications for prevention
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