Signal regeneration techniques for advanced modulation formats

We review recent results on all-optical regeneration of phase encoded signals based on phase sensitive amplification achieved by avoiding phase-to-amplitude conversion in order to facilitate the regeneration of amplitude/phase encoded (QAM) signals

SOA-based, idler-free phase quantiser

Energy consumption, system complexity and potential for integration are important factors when considering the suitability of all-optical processing, and depend upon both the scheme used and the medium in which it is performed. We have recently proposed a simple, wavelength-converting phase quantising scheme based on an idler-free phase-sensitive amplifier, notable for its flexibility of operating power and relative compactness [1]. We have demonstrated its performance for QPSK regeneration using an operating power of 24 dBm in 300 m of highly nonlinear fibre (HNLF). Despite offering low loss and high net nonlinearity, the size and geometry of the HNLF do not make it suitable for integration in a photonic device. Semiconductor optical amplifiers (SOAs) on the other hand, offer a particularly compact medium for nonlinear signal processing, combining an amplifier and nonlinear medium in one device. BPSK phase regeneration has been demonstrated in SOAs [2]; in this paper we experimentally demonstrate, to our knowledge, the first realisation of QPSK phase regeneration in SOAs, making use of the above idler-free scheme to realise a compact and more easily integrated QPSK regenerator

PSA-based all-optical multi-channel phase regenerator

We demonstrate simultaneous phase regeneration of six NRZ BPSK signals in a single nonlinear medium using FWM-based phase sensitive amplification. BER measurements confirm OSNR improvement and negligible cross-talk across all the regenerated channels, impaired with broadband phase noise

Phase regeneration of QPSK signal in SOA using single-stage, wavelength converting PSA

We demonstrate, for the first time, all-optical phase regeneration of a quaternary phase shift keying (QPSK) signal through phase sensitive amplification (PSA) in nonlinear semiconductor optical amplifiers (SOAs), using a scheme only previously demonstrated in highly nonlinear fibre (HNLF). We make use of a highly tunable phase quantising scheme to circumvent some of the limitations imposed by the use of SOAs and show that it may function in either a conjugating or non-conjugating manner

Investigation into the role of pump to signal power ratio in FWM-based phase preserving amplitude regeneration

We carry out a detailed experimental characterization of a four-wave mixing based amplitude limiter in highly nonlinear fiber based on the Bessel-like power transfer characteristics and highlight trade-offs for phase preserving capabilities

Phase Regeneration of QPSK Signal in SOA Using Single-Stage, Wavelength Converting PSA

We demonstrate, for the first time, all-optical phase regeneration of a quaternary phase shift keying (QPSK) signal through phase sensitive amplification (PSA) in nonlinear semiconductor optical amplifiers (SOAs), using a scheme only previously demonstrated in highly nonlinear fibre (HNLF). We make use of a highly tunable phase quantising scheme to circumvent some of the limitations imposed by the use of SOAs and show that it may function in either a conjugating or non-conjugating manner

Reactivity of a dititanium bis(pentalene) complex toward heteroallenes and main-group element–element bonds

The reactivity of the Ti═Ti double bond in (μ,η5:η5-Pn†)2Ti2 (1; Pn† = 1,4-{SiiPr3}2C8H4) toward isocyanide and heteroallene substrates, and molecules featuring homonuclear bonds between main-group elements (E–E) has been explored. Reaction of 1 with methyl isocyanide or 1,3-N,N′-di-p-tolylcarbodiimide resulted in the formation of the 1:1 adducts (μ,η5:η5-Pn†)2Ti2(μ,η2-CNMe) (2) and (μ,η5:η5-Pn†)2Ti2(μ-C{N(4-C6H4CH3)}2) (3), respectively, which are thermally stable up to 100 °C in contrast to the analogous adducts formed with CO and CO2. Reaction of 1 with phenyl isocyanate afforded a paramagnetic complex, [(η8-Pn†)Ti]2(μ,κ2:κ2-O2CNPh) (4), in which the “double-sandwich” architecture of 1 has been broken and an unusual phenyl-carbonimidate ligand bridges two formally Ti(III) centers. Reaction of 1 with diphenyl dichalcogenides, Ph2E2 (E = S, Se, Te), led to the series of Ti–Ti single-bonded complexes (μ,η5:η5-Pn†)2[Ti(EPh)]2 (E = S (5), Se (6), Te (7)), which can be considered the result of a 2e– redox reaction or a 1,2-addition across the Ti═Ti bond. Treatment of 1 with azobenzene or phenyl azide afforded [(η8-Pn†)Ti]2(μ-NPh)2 (8), a bridging imido complex in which the pentalene ligands bind in an η8 fashion to each formally Ti(IV) center, as the result of a 4e– redox reaction driven by the oxidative cleavage of the Ti═Ti double bond. The new complexes 2–8 were extensively characterized by various techniques including multinuclear NMR spectroscopy and single-crystal X-ray diffraction, and the experimental work was complemented by density functional theory (DFT) studies

FWM-based, Idler-free Phase Quantiser with Flexible Operating Power

Coherently adding a signal's conjugate and third harmonic at the latter's wavelength enables phase quantisation across a large operating power range. With broadband phase noise, a 5.6dB QPSK receiver sensitivity improvement is achieved with BER=10-4

Coordination chemistry of amide-functionalised tetraazamacrocycles: structural, relaxometric and cytotoxicity studies

Three different tetraazamacrocyclic ligands containing four amide substituents that feature groups (namely allyl, styryl and propargyl groups) suitable for polymerisation have been synthesised. Gadolinium(III) complexes of these three ligands have been prepared as potential monomers for the synthesis of polymeric MRI contrast agents. To assess the potential of these monomers as MRI contrast agents, their relaxation enhancement properties and cytotoxicity have been determined. A europium(III) complex of one of these ligands (with propargyl substituents) is also presented together with its PARACEST properties. In addition, to gain further insight into the coordination chemistry of the tetra-propargyl substituted ligand, the corresponding zinc(II) and cadmium(II) complexes have been prepared. The X-ray crystal structures of the tetra-propargyl ligand and its corresponding gadolinium(III), zinc(II) and cadmium(II) complexes are also presented