Interactive Chemical Reactivity Exploration

Elucidating chemical reactivity in complex molecular assemblies of a few hundred atoms is, despite the remarkable progress in quantum chemistry, still a major challenge. Black-box search methods to find intermediates and transition-state structures might fail in such situations because of the high-dimensionality of the potential energy surface. Here, we propose the concept of interactive chemical reactivity exploration to effectively introduce the chemist's intuition into the search process. We employ a haptic pointer device with force-feedback to allow the operator the direct manipulation of structures in three dimensions along with simultaneous perception of the quantum mechanical response upon structure modification as forces. We elaborate on the details of how such an interactive exploration should proceed and which technical difficulties need to be overcome. All reactivity-exploration concepts developed for this purpose have been implemented in the Samson programming environment.Comment: 36 pages, 14 figure

Dark matter directional detection with MIMAC

MiMac is a project of micro-TPC matrix of gaseous (He3, CF4) chambers for direct detection of non-baryonic dark matter. Measurement of both track and ionization energy will allow the electron-recoil discrimination, while access to the directionnality of the tracks will open a unique way to distinguish a geniune WIMP signal from any background. First reconstructed tracks of 5.9 keV electrons are presented as a proof of concept.Comment: 4 pages, proc. of the 44th Rencontres De Moriond: Electroweak Interactions And Unified Theories, 7-14 Mar 2009, La Thuile, Ital

In situ measurement of the electron drift velocity for upcoming directional Dark Matter detectors

Three-dimensional track reconstruction is a key issue for directional Dark Matter detection and it requires a precise knowledge of the electron drift velocity. Magboltz simulations are known to give a good evaluation of this parameter. However, large TPC operated underground on long time scale may be characterized by an effective electron drift velocity that may differ from the value evaluated by simulation. In situ measurement of this key parameter is hence needed as it is a way to avoid bias in the 3D track reconstruction. We present a dedicated method for the measurement of the electron drift velocity with the MIMAC detector. It is tested on two gas mixtures: CF4 and CF4 + CHF3. The latter has been chosen for the MIMAC detector as we expect that adding CHF3 to pure CF4 will lower the electron drift velocity. This is a key point for directional Dark Matter as the track sampling along the drift field will be improved while keeping almost the same Fluorine content of the gas mixture. We show that the drift velocity at 50 mbar is reduced by a factor of about 5 when adding 30% of CHF3.Comment: 19 pages, 14 figures. Minor corrections, matches published version in JINS

Measurement of the electron drift velocity for directional dark matter detectors

Three-dimensional track reconstruction is a key issue for directional Dark Matter detection. It requires a precise knowledge of the electron drift velocity. Magboltz simulations are known to give a good evaluation of this parameter. However, large TPC operated underground on long time scale may be characterized by an effective electron drift velocity that may differ from the value evaluated by simulation. In situ measurement of this key parameter is hence a way to avoid bias in the 3D track reconstruction. We present a dedicated method for the measurement of the electron drift velocity with the MIMAC detector. It is tested on two gas mixtures : $\rm CF_4$ and $\rm CF_4+CHF_3$. We also show that adding $\rm CHF_3$ allows us to lower the electron drift velocity while keeping almost the same Fluorine content of the gas mixture.Comment: Proceedings of the 4th international conference on Directional Detection of Dark Matter (CYGNUS 2013), 10-12 June 2013, Toyama, Japa

Development and validation of a 64 channel front end ASIC for 3D directional detection for MIMAC

A front end ASIC has been designed to equip the {\mu}TPC prototype developed for the MIMAC project, which requires 3D reconstruction of low energy particle tracks in order to perform directional detection of galactic Dark Matter. Each ASIC is able to monitor 64 strips of pixels and provides the "Time Over Threshold" information for each of those. These 64 digital informations, sampled at a rate of 50 MHz, can be transferred at 400MHz by eight LVDS serial links. Eight ASIC were validated on a 2x256 strips of pixels prototype.Comment: proceedings of TWEPP-11, Vienna, Austria, 26-30 September 201

Quenching factor measurement in low pressure gas detector for directional dark matter search

There is considerable experimental effort dedicated to the directional detection of particle dark matter. Gaseous mu-TPC detectors present the privileged features of being able to reconstruct the track and the energy of the recoil nucleus following the interaction. A precise measurement of the recoil energy is a key point for the directional search strategy. Quenching has to be taken into account, i.e. only a certain fraction of the recoil energy is deposited in the ionization channel. Measurements of the ionization quenching factor for different gas mixture at room temperature have been made with a dedicated ion beam facility at the LPSC of Grenoble.Comment: Proceedings of the 3rd International conference on Directional Detection of Dark Matter (CYGNUS 2011), Aussois, France, 8-10 June 201