Effect of Hydrogen on the Structural and Phase State and Defect Structure of Titanium Alloy

Effect of hydrogen on the structural and phase state of the fine- and ultrafine-grained structure of two-phase (alpha + beta) titanium Ti-6Al-4V alloy was investigated by the methods of electron microscopy and X-ray diffraction analysis. The defect structure of the fine- and ultrafine-grained samples before and after hydrogen treatment was studied by the implemented Positron lifetime technique. Hydrogenation is found to result in minor structural and phase changes both in fine- and ultrafine-grained samples. It is shown that defect structure of samples depends on the structural state and hydrogen presence

The investigation of hydrogenation influence on structure changes of zirconium with nickel layer

The results of experimental investigation of hydrogenation influence on structure changes of zirconium alloy (Zr-1%Nb) with thin nickel layer have presented in this work. Nickel layer was formed by magnetron sputter deposition. Hydrogenation was carried out at gas atmosphere at constant temperature. Different hydrogen concentrations were obtained by varying time of hydrogenation. Defect and phase structure was studied by means of X-ray diffraction, glow discharge optical emission spectroscopy, positron lifetime and Doppler broadening spectroscopies. New experimental data about the evolution of the positron annihilation parameters depending on hydrogen concentration in Zr-1Nb alloy with nickel layer was obtained

Positron annihilation spectroscopy of vacancy-type defects hierarchy in submicrocrystalline nickel during annealing

Positron annihilation and X-ray diffraction analysis have been used to study submicrocrystalline nickel samples prepared by equal channel angular pressing. In the as-prepared samples the positrons are trapped at dislocation-type defects and in vacancy clusters that can include up to 5 vacancies. The study has revealed that the main positron trap centers at the annealing temperature of deltaT= 20°C-180°C are low-angle boundaries enriched by impurities. At deltaT = 180°C-360°C, the trap centers are low-angle boundaries providing the grain growth due to recrystallization in-situ

ERA5 reanalysis for the data interpretation on polarization laser sensing of high-level clouds

Interpreting the results of a high-level clouds (HLCs) lidar study requires a comparison with the vertical profiles of meteorological quantities. There are no regular radiosonde measurements of vertical profiles of meteorological quantities in Tomsk. The nearest aerological stations are several hundred kilometers away from the lidar and perform radiosonde measurements only a few times a day, whereas lidar experiments are performed continuously throughout the day. To estimate meteorological conditions at the HLC altitudes, we propose to use the ERA5 reanalysis. Its reliability was tested by comparing with the data from five aerological stations within a radius of 500 km around Tomsk. A labeled database of the lidar, radiosonde, and ERA5 data (2016–2020) for isobaric levels 1000–50 hPa was created. The temperature reconstruction error over the entire altitude range was characterized by an RMSE of 0.8–2.8 ◦C, bias of 0–0.9, and Corr ~1. The accuracy of the relative vertical profiles (RMSE 25–40%, Bias 10–22%, and Corr <0.7) and specific humidity (RMSE 0.2–1.2 g/kg, Bias ~0 g/kg, and Corr ~0) at the HLC altitudes were unsatisfying. The ERA5 data on wind direction and speed for the HLC altitudes were promising

Source for In Situ Positron Annihilation Spectroscopy of Thermal-And Hydrogen-Induced Defects Based on the Cu-64 Isotope

This work aims to investigate the 64Cu isotope applicability for positron annihilation experiments in in situ mode. We determined appropriate characteristics of this isotope for defect studies and implemented them under aggressive conditions (i.e., elevated temperature, hydrogen environment) in situ to determine the sensitivity of this approach to thermal vacancies and hydrogen-induced defects investigation. Titanium samples were used as test materials. The source was obtained by the activation of copper foil in the thermal neutron flux of a research nuclear reactor. Main spectrometric characteristics (e.g., the total number of counts, fraction of good signals, peak-to-noise ratio) of this source, as well as line-shaped parameters of the Doppler broadening spectrum (DBS), were studied experimentally. These characteristics for 64Cu (in contrast to positron sources with longer half-life) were shown to vary strongly with time, owing to the rapidly changing activity. These changes are predictable and should be considered in the analysis of experimental data to reveal information about the defect structure. The investigation of samples with a controlled density of defects revealed the suitability of 64Cu positron source with an activity of 2-40 MBq for defects studies by DBS. However, greater isotope activity could also be applied. The results of testing this source at high temperatures and in hydrogen atmosphere showed its suitability to thermal vacancies and hydrogen-induced defects studies in situ. The greatest changes in the defect structure of titanium alloy during high-temperature hydrogen saturation occurred at the cooling stage, when the formation of hydrides began, and were associated with an increase in the dislocation density

Positron Annihilation Spectroscopy Study of Metallic Materials after High-Speed Cutting

During high-speed cutting, a white layer is often produced on the machined surfaces after mechanical machining, seriously affecting the mechanical properties. These properties are related to the material structure and the defects induced by cutting. However, there is a lack of research on the atomic-scale defects of the white layer. This paper studied the influence of cutting parameters, namely the feed rate, cutting speed and cutting depth, on atomic-scale defects induced by high-speed cutting in GCr15 steel. Positron annihilation studies showed typical plastically deformed or tempered carbon steel defects with additional vacancy cluster components. The quantity of these clusters changed with cutting parameters. Furthermore, significant changes were observed in the subsurface region up to 1 µm, occurring as a result of simultaneous phase transformations, deformation and thermal impacts. The predominant accumulation of only one type of atomic-scale defect was not observed

Effect of Proton Irradiation on the Defect Evolution of Zr/Nb Nanoscale Multilayers

Nanoscale multilayer coatings (NMCs) with different crystal structures are considered as capable of self-healing after radiation damage due to the recombination of vacancies and interstitials. This work is focused on a defect distribution study of NMCs based on Zr/Nb layers (25/25 nm and 100/100 nm) after proton irradiation. Coatings with a total thickness of 1.05 ± 0.05 µm were irradiated by 900-keV protons using a pelletron-type electrostatic accelerator with an ion current of 2 µA for durations of 60 min to 120 min. The influence of the irradiation effect was studied by X-ray diffraction analysis (XRD), glow discharge optical emission spectrometry (GD–OES), and Doppler broadening spectroscopy using a variable energy positron beam. The results obtained by these methods are compatible and indicate that defect concentration of Zr/Nb NMCs remains unchanged or slightly decreases with increasing irradiation time

Effect of Proton Irradiation on the Defect Evolution of Zr/Nb Nanoscale Multilayers

Nanoscale multilayer coatings (NMCs) with different crystal structures are considered as capable of self-healing after radiation damage due to the recombination of vacancies and interstitials. This work is focused on a defect distribution study of NMCs based on Zr/Nb layers (25/25 nm and 100/100 nm) after proton irradiation. Coatings with a total thickness of 1.05 ± 0.05 µm were irradiated by 900-keV protons using a pelletron-type electrostatic accelerator with an ion current of 2 µA for durations of 60 min to 120 min. The influence of the irradiation effect was studied by X-ray diffraction analysis (XRD), glow discharge optical emission spectrometry (GD–OES), and Doppler broadening spectroscopy using a variable energy positron beam. The results obtained by these methods are compatible and indicate that defect concentration of Zr/Nb NMCs remains unchanged or slightly decreases with increasing irradiation time