Packaging techniques for low-altitude Venus balloons beacon

The results of a specific design project for the Venus balloon beacon, in which a microwave beacon is required to operate for a limited time at high temperature (350 C) and at high pressure, (10 bars). In a chemically hostile environment after surviving large mechanical shock forces (up to 280 gs) are discussed. It was found that many existing, commerically-available component can be used in such a design with only minor modifications. A further result is that a crude (and consequently low-cost) test program can be designed to identify and select promising commercial components

Is Hyperconjugation Responsible For The Gauche Effect In 1-Fluoropropane And Other 2-Substituted-1-Fluoroethanes?

The energies and geometries of a series of 2-substituted-1-fluoroethanes were computed at the MP2/6-311++G**(6D)//MP2/6-31+G* level of theory for both the maxima and minima of the rotation about the C-C bond. The results did not support the predictions of a hyperconjugative model, that both 1,2-difluoroethane and 1-chloro-2-fluoroethane would strongly prefer a gauche conformation, and that 1-fluoro-2-silylethane would strongly prefer an anti conformation. The existence of competing electrostatic interactions between the fluorine and the substituents at C-2 was indicated by the detailed geometries of the gauche conformers and by the calculated sensitivity of the gauche-anti energy differences to the presence of a polar solvent. However, Fourier analyses of the torsional potential energies were wholly consistent with hyperconjugative electron donation into the C-F sigma* orbital contributing to the conformational preferences of these 1-fluoroethanes. Fourier analyses also showed that hyperconjugation contributes to the small variations in C-C and C-F bond lengths and in fluorine atomic charges that were computed. The torsional potential energies, variations in geometry and atomic charge, and sensitivity to solvent were all in accord with the expected ranking of hyperconjugative electron donating ability of bonds to carbon, C-Si \u3e C-H \u3e C-C \u3e C-Cl \u3e C-F

The Synergy Between Qualitative Theory, Quantitative Calculations, and Direct Experiments in Understanding, Calculating, and Measuring the Energy Differences Between the Lowest Singlet and Triplet States of Organic Diradicals

Article discussing the synergy between qualitative theory, quantitative calculations, and direct experiments in understanding, calculating, and measuring the energy differences between the lowest singlet and triplet states of organic diradicals

The radical character of the acenes: A density matrix renormalization group study

We present a detailed investigation of the acene series using high-level wavefunction theory. Our ab-initio Density Matrix Renormalization Group algorithm has enabled us to carry out Complete Active Space calculations on the acenes from napthalene to dodecacene correlating the full pi-valence space. While we find that the ground-state is a singlet for all chain-lengths, examination of several measures of radical character, including the natural orbitals, effective number of unpaired electrons, and various correlation functions, suggests that the longer acene ground-states are polyradical in nature.Comment: 10 pages, 8 figures, supplementary material, to be published in J. Chem. Phys. 127, 200

Conceptual design of the MHD Engineering Test Facility

The reference conceptual design of the MHD engineering test facility, a prototype 200 MWe coal-fired electric generating plant designed to demonstrate the commerical feasibility of open cycle MHD is summarized. Main elements of the design are identified and explained, and the rationale behind them is reviewed. Major systems and plant facilities are listed and discussed. Construction cost and schedule estimates are included and the engineering issues that should be reexamined are identified

The Higgs - photon - Z boson coupling revisited

We analyze the coupling of CP-even and CP-odd Higgs bosons to a photon and a Z boson in extensions of the Standard Model. In particular, we study in detail the effect of charged Higgs bosons in two-Higgs doublet models, and the contribution of SUSY particle loops in the minimal supersymmetric extension of the Standard Model. The Higgs-$\gamma Z$ coupling can be measured in the decay $Z \to \gamma$+Higgs at $e^+e^-$ colliders running on the Z resonance, or in the reverse process Higgs $\to Z \gamma$ with the Higgs boson produced at LHC. We show that a measurement of this coupling with a precision at the percent level, which could be the case at future $e^+e^-$ colliders, would allow to distinguish between the lightest SUSY and standard Higgs bosons in large areas of the parameter space.Comment: 18 pages LaTex + 7 figures (ps). Typo corrected in eq.(5

Probing MSSM Higgs Sector with Explicit CP Violation at a Photon Linear Collider

The CP properties of Higgs bosons can be probed through their s-channel resonance productions via photon-photon collisions by use of circularly and/or linearly polarized backscattered laser photons at a TeV-scale linear e^+ e^- collider. Exploiting this powerful tool, we investigate in detail the Higgs sector of the minimal supersymmetric Standard Model with explicit CP violation.Comment: 18 pages, 5 figures. Some comments added and typos corrected. To appear in Phys. Rev.

Detection of chromosome aberrations in metaphase and interphase tumor cells by in situ hybridization using chromosome-specific library probes

Chromosome aberrations in two glioma cell lines were analyzed using biotinylated DNA library probes that specifically decorate chromosomes 1, 4, 7, 18 and 22 from pter to qter. Numerical changes, deletions and rearrangements of these chromosomes were radily visualized in metaphase spreads, as well as in early prophase and interphase nuclei. Complete chromosomes, deleted chromosomes and segments of translocated chromosomes were rapidly delineated in very complex karyotypes. Simultaneous hybridizations with additional subregional probes were used to further define aberrant chromosomes. Digital image analysis was used to quantitate the total complement of specific chromosomal DNAs in individual metaphase and interphase cells of each cell line. In spite of the fact that both glioma lines have been passaged in vitro for many years, an under-representation of chromosome 22 and an over-representation of chromosome 7 (specifically 7p) were observed. These observations agree with previous studies on gliomas. In addition, sequences of chromosome 4 were also found to be under-represented, especially in TC 593. These analyses indicate the power of these methods for pinpointing chromosome segments that are altered in specific types of tumors