Exergy analysis of a diesel engine with waste cooking biodiesel and triacetin

This study uses the first and second laws of thermodynamics to investigate the effect of 18 oxygenated fuels on the quality and quantity of energy in a turbo-charged, common-rail six19 cylinder diesel engine. This work was performed using a range of fuel oxygen content based 20 on diesel, waste cooking biodiesel, and a triacetin. The experimental engine performance and 21 emission data was collected at 12 engine operating modes. Energy and exergy parameters were 22 calculated, and results showed that the use of oxygenated fuels can improve the thermal 23 efficiency leading to lower exhaust energy loss. Waste cooking biodiesel (B100) exhibited the 24 lowest exhaust loss fraction and highest thermal efficiency (up to 6% higher than diesel). 25 Considering the exergy analysis, lower exhaust temperatures obtained with oxygenated fuels 26 resulted in lower exhaust exergy loss (down to 80%) and higher exergetic efficiency (up to 27 10%). Since the investigated fuels were oxygenated, this study used the oxygen ratio (OR) 28 instead of the equivalence ratio to provide a better understanding of the concept. The OR has 29 increased with decreasing engine load and increasing engine speed. Increasing the OR 30 decreased the fuel exergy, exhaust exergy and destruction efficiency. With the use of B100, 31 there was a very high exergy destruction (up to 55%), which was seen to decrease with the 32 addition of triacetin (down to 29%)

Effect of cold start on engine performance and emissions from diesel engines using IMO-Compliant distillate fuels

© 2019 Elsevier Ltd Emissions from ships at berth are small compared to the total ship emissions; however, they are one of the main contributors to pollutants in the air of densely-populated areas, consequently heavily affecting public health. This is due to auxiliary marine engines being used to generate electric power and steam for heating and providing services. The present study has been conducted on an engine representative of a marine auxiliary, which was a heavy duty, six-cylinder, turbocharged and after-cooled engine with a high pressure common rail injection system. Engine performance and emission characterisations during cold start are the focus of this paper, since cold start is significantly influential. Three tested fuels were used, including the reference diesel and two IMO (International Maritime Organization) compliant spiked fuels. The research engine was operated at a constant speed and 25% load condition after 12 h cooled soak. Results show that during cold start, significant heat generated from combustion is used to heat the engine block, coolant and lubricant. During the first minute, compared to the second minute, emissions of particle number (PN), carbon monoxide (CO), particulate matter (PM), and nitrogen oxides (NOx) were approximately 10, 4, 2 and 1.5 times higher, respectively. The engine control unit (ECU) plays a vital role in reducing engine emissions by changing the engine injection strategy based on the engine coolant temperature. IMO-compliant fuels, which were higher viscosity fuels associated with high sulphur content, resulted in an engine emission increase during cold start. It should be taken into account that auxiliary marine diesel engines, working at partial load conditions during cold start, contribute considerably to emissions in coastal areas. It demonstrates a need to implement practical measures, such as engine pre-heating, to obtain both environmental and public health advantages in coastal areas

Cold-start NOx emissions : diesel and waste lubricating oil as a fuel additive

NOx emissions from diesel engines are a concern from both environmental and health perspectives. Recently this attention has targeted cold-start emissions highlighting that emission after-treatment systems are not effective in this period. Using a 6-cylinder, turbocharged, common-rail diesel engine, the current research investigates NOx emissions during cold-start using different engine performance parameters. In addition, it studies the influence of waste lubricating oil on NOx emissions introducing it as a fuel additive (1 and 5% by volume). To interpret the NOx formation, this study evaluates different parameters: exhaust gas temperature, engine oil temperature, engine coolant temperature, start of injection/combustion, in-cylinder pressure, heat release rate, maximum in-cylinder pressure and maximum rate of pressure rise. This study clarified how cold-start NOx increases as the engine is warming up while in general cold-start NOx is higher than hot-start. Results showed that in comparison with warmed up condition, during cold-start NOx, maximum in-cylinder pressure and maximum rate of pressure rise were higher; while start of injection, start of combustion and ignition delay were lower. During cold-start increased engine temperature was associated with decreasing maximum rate of pressure rise and peak apparent heat release rate. During cold-start NOx increased with temperature and it dropped sharply due to the delayed start of injection. This study also showed that using waste lubricating oil decreased NOx and maximum rate of pressure rise; and increased maximum in-cylinder pressure. NOx had a direct correlation with the maximum rate of pressure rise; and an inverse correlation with the maximum in-cylinder pressure

Application of multicriteria decision making methods to compression ignition engine efficiency and gaseous, particulate, and greenhouse gas emissions

Compression ignition (CI) engine design is subject to many constraints, which present a multicriteria optimization problem that the engine researcher must solve. In particular, the modern CI engine must not only be efficient but must also deliver low gaseous, particulate, and life cycle greenhouse gas emissions so that its impact on urban air quality, human health, and global warming is minimized. Consequently, this study undertakes a multicriteria analysis, which seeks to identify alternative fuels, injection technologies, and combustion strategies that could potentially satisfy these CI engine design constraints. Three data sets are analyzed with the Preference Ranking Organization Method for Enrichment Evaluations and Geometrical Analysis for Interactive Aid (PROMETHEE-GAIA) algorithm to explore the impact of (1) an ethanol fumigation system, (2) alternative fuels (20% biodiesel and synthetic diesel) and alternative injection technologies (mechanical direct injection and common rail injection), and (3) various biodiesel fuels made from 3 feedstocks (i.e., soy, tallow, and canola) tested at several blend percentages (20-100%) on the resulting emissions and efficiency profile of the various test engines. The results show that moderate ethanol substitutions (∼20% by energy) at moderate load, high percentage soy blends (60-100%), and alternative fuels (biodiesel and synthetic diesel) provide an efficiency and emissions profile that yields the most "preferred" solutions to this multicriteria engine design problem. Further research is, however, required to reduce reactive oxygen species (ROS) emissions with alternative fuels and to deliver technologies that do not significantly reduce the median diameter of particle emissions. © 2013 American Chemical Society

The effect of triacetin as a fuel additive to waste cooking biodiesel on engine performance and exhaust emissions

This study investigates the effect of oxygenated fuels on engine performance and exhaust emission under a custom cycle using a fully instrumented 6-cylinder turbocharged diesel engine with a common railinjection system. A range of oxygenated fuels based on waste cooking biodiesel with triacetin as an oxygenated additive were studied. The oxygen ratio was used instead of the equivalence ratio, or air to fuelratio, to better explain the phenomena observed during combustion. It was found that the increased oxygen ratio was associated with an increase in the friction mean effective pressure, brake specific fuel consumption, CO, HC and PN. On the other hand, mechanical efficiency, brake thermal efficiency, CO2, NOx and PM decreased with oxygen ratio. Increasing the oxygen content of the fuel was associated with a decrease in indicated power, brake power, indicated mean effective pressure, brake mean effective pressure, friction power, blow-by, CO2, CO (at higher loads), HC, PM and PN. On the other hand, the brakespecific fuel consumption, brake thermal efficiency and NOx increased by using the oxygenated fuels. Also, by increasing the oxygen content, the accumulation mode count median diameter moved toward the smaller particle sizes. In addition to the oxygen content of fuel, the other physical and chemical properties of the fuels were used to interpret the behavior of the engine

Engine performance characteristics for biodiesels of different degrees of saturation and carbon chain lengths

This experimental study examines the effect on performance and emission outputs of a compression ignition engine operating on biodiesels of varying carbon chain length and the degree of unsaturation. A well-instrumented, heavy-duty, multi-cylinder, common-rail, turbo-charged diesel engine was used to ensure that the results contribute in a realistic way to the ongoing debate about the impact of biofuels. Comparative measurements are reported for engine performance as well as the emissions of NOx, particle number and size distribution, and the concentration of the reactive oxygen species (which provide a measure of the toxicity of emitted particles). \ud \ud It is shown that the biodiesels used in this study produce lower mean effective pressure, somewhat proportionally with their lower calorific values; however, the molecular structure has been shown to have little impact on the performance of the engine. The peak in-cylinder pressure is lower for the biodiesels that produce a smaller number of emitted particles, compared to fossil diesel, but the concentration of the reactive oxygen species is significantly higher because of oxygen in the fuels. \ud \ud The differences in the physicochemical properties amongst the biofuels and the fossil diesel significantly affect the engine combustion and emission characteristics. Saturated short chain length fatty acid methyl esters are found to enhance combustion efficiency, reduce NOx and particle number concentration, but results in high levels of fuel consumption

Diesel engine emissions with oxygenated fuels: A comparative study into cold-start and hot-start operation

As biofuels are increasingly represented in the fuel market, the use of these oxygenated fuels should be evaluated under various engine operating conditions, such as cold-start. However, to-date quantification has been mostly done under hot-start engine operation. By using a custom test designed for this study, a comparative investigation was performed on exhaust emissions during cold- and hot-start with diesel and three oxygenated fuels based on waste cooking biodiesel and triacetin. This study used a six-cylinder, turbocharged, after-cooled diesel engine with a common rail injection system. The results during cold-start with diesel showed lower NOx (up to 15.4%), PN (up to 48%), PM1 (up to 44%) and PM2.5 (up to 63%). However, the oxygenated fuels during cold-start showed a significant increase in NOx (up to 94%), PN (up to 27 times), PM1 (up to 7.3 times) and PM2.5 (up to 5 times) relative to hot-start. The use of oxygenated fuels instead of diesel during hot-start decreased the PN, PM2.5 and PM1 (up to 91%) while, during cold-start, it only decreased PM1 and PM2.5 at some engine operating modes and increased PN significantly up to 17 times. In both cold- and hot-start, the use of oxygenated fuels resulted in an increase in NOx emission. For cold-start this was up to 125%, for hot-start it was up to 13.9%. In comparison with hot-start, the use of oxygenated fuels during cold-start increased nucleation mode particles significantly, which are harmful. This should be taken into consideration, since cold-start operation is an inevitable part of the daily driving schedule for a significantly high portion of vehicles, especially in cities

A parametric study on engine performance and emissions with neat diesel and diesel-butanol blends in the 13-Mode European Stationary Cycle

© 2017 Elsevier Ltd This paper presents a comprehensive study of a wide range of engine performance parameters, including: indicated torque (IT), indicated power (IP), indicated mean effective pressure (IMEP) and indicated specific fuel consumption (ISFC). Further, the combustion parameters measured include: start of injection timing, in-cylinder peak pressure, boost pressure and rate of maximum pressure rise. Resultant emission parameters investigated include: exhaust blow by, unburned hydrocarbon (UBHC), oxides of nitrogen (NOx), particulate matter (PM), particle number (PN) and particle size distribution (PSD). Normal butanol (n-butanol) was chosen to blend with a reference diesel fuel. The experiment was conducted using a 6-cylinder, turbocharged common rail diesel engine in accordance with the 13-Mode European Stationary Cycle (ESC). Considering limits of solubility of n-butanol in reference diesel, a maximum of 30% n-butanol was blended with 70% reference diesel. Three different butanol blends having 10% butanol with 90% reference diesel, 20% butanol with 80% reference diesel and 30% butanol with 70% reference diesel (the blending percentages were on a volume basis) were prepared. The engine experimental results show that without considerably deteriorating engine performance, most of the emissions were significantly reduced with the butanol blends compared to those of the reference diesel

Engine performance during transient and steady-state operation with oxygenated fuels

© 2017 American Chemical Society. Owing to the increasing share of biofuels in combustion engines, use of these oxygenated fuels instead of diesel should be evaluated under different engine operating conditions. This paper studies the influence of oxygenated fuels on engine performance parameters under transient, compared to steady-state, operation on a six-cylinder, turbocharged, compression-ignition engine with a common rail injection system. The fuels used in this study were diesel, waste cooking biodiesel, and triacetin (as a highly oxygenated additive). A custom test was used to investigate different engine performance parameters during acceleration, load increase, and steady-state modes of operation. Additionally, a legislative transient cycle (NRTC), composed of many discrete transient modes, was used to study engine performance during a whole transient cycle. In this paper, different engine performance-related parameters were investigated, such as IMEP, BMEP, FMEP, turbocharger lag, air-to-fuel ratio, engine speed and torque, start of injection, start of combustion, injection pressure, maximum in-cylinder pressure, maximum rate of pressure rise, intake and exhaust manifold pressures, and CoV of IMEP. The investigation demonstrates that engine behavior during transient operation is different from steady-state operation. Results during NRTC indicated that, in comparison with diesel, the oxygenated fuels have lower IMEP (up to 18.7%), BMEP (up to 21.7%), and FMEP (up to 12.7%). During transient modes of the custom test, using oxygenated fuels rather than diesel resulted in higher indicated torque, maximum in-cylinder pressure, and maximum rate of pressure rise; however, during steady-state, most of the oxygenated fuels had lower values in these three parameters. Each advance in SOI corresponds to a rise in the maximum in-cylinder pressure and in the maximum rate of pressure rise. Oxygenated fuels had lower intake manifold pressure and CoV of IMEP than diesel. Different fuel properties were used to interpret engine behavior

Exergy analysis of a diesel engine with waste cooking biodiesel and triacetin

This study uses the first and second laws of thermodynamics to investigate the effect of oxygenated fuels on the quality and quantity of energy in a turbo-charged, common-rail six-cylinder diesel engine. This work was performed using a range of fuel oxygen content based on diesel, waste cooking biodiesel, and a triacetin. The experimental engine performance and emission data was collected at 12 engine operating modes. Energy and exergy parameters were calculated, and results showed that the use of oxygenated fuels can improve the thermal efficiency leading to lower exhaust energy loss. Waste cooking biodiesel (B100) exhibited the lowest exhaust loss fraction and highest thermal efficiency (up to 6% higher than diesel). Considering the exergy analysis, lower exhaust temperatures obtained with oxygenated fuels resulted in lower exhaust exergy loss (down to 80%) and higher exergetic efficiency (up to 10%). Since the investigated fuels were oxygenated, this study used the oxygen ratio (OR) instead of the equivalence ratio to provide a better understanding of the concept. The OR has increased with decreasing engine load and increasing engine speed. Increasing the OR decreased the fuel exergy, exhaust exergy and destruction efficiency. With the use of B100, there was a very high exergy destruction (up to 55%), which was seen to decrease with the addition of triacetin (down to 29%). © 2019 Elsevier Lt