4,757 research outputs found

    A new polymorph of phenylselenium trichloride

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    A second polymorph of phenylselenium trichloride, PhSeCl3 or C6H5Cl3Se, is disclosed, which is comprised of asymmetric chlorine-bridged noncovalent dimer units rather than polymeric chains. These dimers are each weakly bound to an adjacent dimer through noncovalent Se...Cl bonding interactions. Phenyl rings within each dimer are oriented in a syn fashion. Density functional theory (DFT) calculations reveal that the putative anti isomer is within 5 kJ mol-1 of the experimentally observed form. This structure represents the first additional polymorph discovered for an organoselenium trihalide compound.https://doi.org/10.1107/S205322961901301

    Worst Case Reliability Prediction Based on a Prior Estimate of Residual Defects

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    In this paper we extend an earlier worst case bound reliability theory to derive a worst case reliability function R(t), which gives the worst case probability of surviving a further time t given an estimate of residual defects in the software N and a prior test time T. The earlier theory and its extension are presented and the paper also considers the case where there is a low probability of any defect existing in the program. For the "fractional defect" case, there can be a high probability of surviving any subsequent time t. The implications of the theory are discussed and compared with alternative reliability models

    A Methodology for Safety Case Development

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    This paper will outline a safety case methodology that seeks to minimise safety risks and commercial risks by constructing a demonstrable safety case. The safety case ideas presented here were initially developed in an EU-sponsored SHIP project [1] and was then further developed in the UK Nuclear Safety Research Programme (the QUARC Project [2]). Some of these concepts have subsequently been incorporated in safety standards such as MOD Def Stan 00-55, and have also been used to establish specific safety cases for clients. A generalisation of the concepts also appears in Def Stan 00-42 Part 2, in the form of the software reliability case

    Magnetism and Magnetic Isomers in Free Chromium Clusters

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    We have used the Stern-Gerlach deflection technique to study magnetism in chromium clusters of 20-133 atoms. Between 60 K and 100 K, we observe that these clusters have large magnetic moments and respond superparamagnetically to applied magnetic fields. Using superparamagnetic theory, we have determined the moment per atom for each cluster size and find that it often far exceeds the moment per atom present anywhere in the bulk antiferromagnetic lattice. Remarkably, our cluster beam contains two magnetically distinguishable forms of each cluster size with >= 34 atoms. We attribute this observation to structural isomers
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