Thermally induced behavior of the K-exchanged erionite. A further step in understanding the structural modifications of the erionite group upon heating

Fibrous erionite is a naturally occurring zeolite considered to be highly carcinogenic upon inhalation, even more than crocidolite. Since no iron is typically present in erionite, its toxicity has been attributed to ion-exchanged Fe participating in Fenton chemistry. Recently, a study aimed at investigating possible fiber inactivation routes surprisingly showed that, despite having completely occluded all available pores with K ions, the erionite-Na sample preserved the property to upload Fe (II) within the structure. In this work, the thermal behavior of the K-exchanged erionite-Na was investigated by TG/ DSC and in situ XRPD analyses in order to provide relevant information for modeling the thermally induced behavior of the erionite group. Rietveld refinement results evidenced a general trend of cell parameters and volume with temperature similar to that observed for erionite-K from Rome (Oregon, USA). However, the dependence of Tdehydrand Tbreakfrom Si/Si+Al ratio observed in zeolites (high Si content favours a lower Tdehydrand a higher Tbreak) is not observed, possibly due to the effect of the relevant amount of large K ions dispersed within the erionite cage, acting as reinforcing blocks for the framework. Heating produces a progressive emptying of the Ca sites, common effect previously observed in erionite samples showing different chemistry. In addition, K1 s.s. remains unchanged evidencing the absence of any “internal ion exchange” process, whereas s.s. at K2 increases in the range 438-573 K and then slowly decreases in the range 700-1218 K. Both Rietveld and DSC data suggest the motion of K ions from OW sites toward the walls of the erionite cavity during dehydration

Labor share as an "automatic stabilizer" of income inequality

We provide a new and unexplored explanation of the relationship between the functional and personal distribution of income. By proposing a simple theoretical framework, we show that, in the noncomprehensive personal income tax (PIT) hypothesis (i.e., when some or all capital income items are excluded from the PIT base), the correlation between disposable and market income inequality depends on the labor share level, which may influence the overall effectiveness of the tax-benefit system in addition to the PIT progressivity. We test our hypothesis using panel data on 33 OECD countries from 2000 to 2017 and find that a 10-pp increase in labor share is related to a 0.06 reduction in the correlation between market and disposable income inequality. This significant result obtained after controlling for country and year fixed effects, country-specific linear trends, and several confounders capturing the characteristics of the tax-benefit system suggests that labor share may act as an "automatic stabilizer" of market income inequality. Relevant implications for tax policy concern the role of the PIT's base for the public budget's overall redistributive effect

Cognitive behavioral group therapy versus psychoeducational intervention in Parkinson's disease

Objective: The aim of the current study was to evaluate whether cognitive behavioral group therapy has a positive impact on psychiatric, and motor and non-motor symptoms in Parkinson’s disease (PD). Methods: We assigned 20 PD patients with a diagnosis of psychiatric disorder to either a 12-week cognitive behavioral therapy (CBT) group or a psychoeducational protocol. For the neurological examination, we administered the Unified Parkinson’s Disease Rating Scale and the non-motor symptoms scale. The severity of psychiatric symptoms was assessed by means of the Hamilton Depression Rating Scale, the Hamilton Anxiety Rating Scale, the Brief Psychiatric Rating Scale, and the Clinical Global Impressions. Results: Cognitive behavioral group therapy was effective in treating depression and anxiety symptoms as well as reducing the severity of non-motor symptoms in PD patients; whereas, no changes were observed in PD patients treated with the psychoeducational protocol. Conclusion: CBT offered in a group format should be considered in addition to standard drug therapy in PD patient

Primary cosmic ray spectrum in the 10 to the 12th power - 10 to the 16th power eV energy range from the NUSEX experiment

A primary cosmic ray spectrum was derived which fits both experimental multiple muon rates and the all-nucleon flux derived from the single muon intensities underground. In the frame of the interaction model developed by Gaisser, Elbert and Stanev, it is possible to reproduce NUSEX muon data with a primary composition in which the iron spectrum is only slightly flatter than the proton one. This result rules out the popular idea that the primary composition varies drastically with increasing energy, leading to the dominance of heavier nuclei at energies 10 to the 15th power to 10 to the 16th power eV

Avaliação da fertilidade dos solos do Distrito Federal.

O SNLCS tem procurado ampliar o alcance e a utilização prática, dos dados obtidos através dos levantamentos de solos que realiza. Prosseguindo as pesquisas que objetivam a elaboração do mapa de solos do Brasil a nível de reconhecimento, esta entidade vem complementando seus trabalhos com mapas de aptidão agrícola das terras, em relação com diferentes tipos de manejo e culturas. Dentro dos parâmetros usados para definir a aptidão agrícola dos solos, a fertilidade e o mais facilmente controlável e aquele cuja alteração modifica mais sensivelmente a produtividade das terras. Por outro lado, os mapas de aptidão, pela sua natureza, não mostram claramente as limitações de uso devido unicamente ao nível de fertilidade das terras. Tal informação é de grande importância ao estudo de viabilidade econômica de projetos agropecuários, por permitir estimar a necessidade de fertilizantes e corretivos para determinada área. A análise conjunta dos mapas de classificação e aptidão agrícola e ainda de uma avaliação da fertilidade dos solos, daria aos usuários dos trabalhos de levantamento uma visão mais completa dos recursos disponíveis, facilitando as decisões quanto ao tipo de exploração agrícola e ao sistema de manejo mais adequado em cada caso. O presente projeto propõe a complementação de cada trabalho de levantamento com uma avaliação e quantificação da fertilidade, cuja precisão e confiabilidade serão tanto maiores quanto maior for o nível de detalhe do levantamento de solos em que seja baseado.bitstream/item/62835/1/CNPS-BOL.-TEC.-74-80.pdf; bitstream/item/125962/1/Avaliacao-da-Fertilidade-dos-Solos-do-Distrito-Federal.pdfAcompanha 1 mapa, color. Escala 1:100.000

First evidence of wulfenite in Calabria Region (Southern Italy)

This data article contains mineralogical and chemical data of the wulfenite (PbMoO4) sampled from mine of Fiumarella in Calabria region (Southern Italy). Wulfenite is a rare mineral belonging to the class of minerals called molybdates and if found in large amounts it can be used for the extraction of molybdenum. In the mine of Fiumarella, in addition to primary minerals such as barite, galena, cerussite, anglesite, fluorite and chalcopyrite, wulfenite was also detected. Wulfenite crystals are bipyramidal, few microns in size and grow as single crystals that can reach 1 mm. Methods for obtaining the data sets include optical microscopy, micro X-Ray Fluorescence and micro-Raman spectroscopy

Experimental and theoretical evaluations on Oleuropein as a natural origin corrosion inhibitor for copper in acidic environment

none5siCopper corrosion in acidic cleaning solutions is a major worry for heat exchangers. Corrosion inhibitors derived from natural sources might be a viable option. The isolation of Oleuropein compound from olive leaf and investigation of its anticorrosion potential for copper in 1.0 M H2SO4 solution are reported here. All experimental results from LC-MS, FT-IR, 1H and 13C-NMR characterizations support the molecular structure of Oleuropein. Electrochemical and gravimetric tests were used to evaluate the corrosion inhibition capabilities of Oleuropein. According to polarization investigation, Oleuropein is a mixed-type inhibitor. Oleuropein's inhibitory efficacy increases with concentration, attaining an optimum value (98.92%) at 100 mg L-1. At high temperatures, Oleuropein can be considered an efficient inhibitor. Thermodynamic variables for the activation operation and copper dissolution were computed and addressed as well. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) examinations revealed that Oleuropein produced an outer layer on the copper surface, shielding it from severe acid damage. Quantum chemical simulations were employed to propose molecular explanations for Oleuropein's inhibitory actions.Deyab, M A; Mohsen, Q; Bloise, E; Lazzoi, M R; Mele, GDeyab, M A; Mohsen, Q; Bloise, E; Lazzoi, M R; Mele,

High-statistics study of the low-energy cosmic-muons angular distribution - Results from MICRO

We present results from MICRO, a muon telescope with good angular resolution, which has collected more than 31·106 cosmic muons. Upper limits are given for the flux coming from point sources and for the periodic component from Cygnus X3