2 research outputs found
Mechanistic insights into the reversible lithium storage in an open porous carbon via metal cluster formation in all solid-state batteries
Porous carbons are promising anode materials for next generation lithium batteries due to their large lithium storage capacities. However, their highsloping capacity during lithiation and delithiation as well as capacity fading due to intense formation of solid electrolyte interphase (SEI) limit their gravimetric and volumetric energy densities. Herein we compare a microporous carbide derived carbon material (MPC) as promising future anode for all solid state batteries with a commercial high performance hard
carbon anode. The MPC obtains high and reversible lithiation capacities of 1000 mAh g 1 carbon in half cells exhibiting an extended plateau region near 0 V vs. Li/Liþ preferable for full cell application. The well defined microporosity of the MPC with a specific surface area of >1500 m2 g 1 combines well with the argyrodite type electrolyte (Li6PS5Cl) suppressing extensive SEI formation to deliver high coulombic efficiencies. Preliminary full cell measurements vs. nickel rich NMC cathodes (LiNi0.9Co0.05Mn0.05O2) provide a considerably improved average potential of 3.76 V leading to a projected energy density as high as 449 Wh kg 1 and reversible cycling for more than 60 cycles. 7Li Nuclear Magnetic Resonance spectroscopy was combined with ex situ Small Angle X ray Scattering to elucidate the storage mechanism of lithium inside the carbon matrix. The formation of extended quasi metallic lithium clusters after electrochemical lithiation was revealed
Sodium sulfide cathodes superseding hard carbon pre-sodiation for the production and operation of sodium-sulfur batteries at room temperature
This study demonstrates for the first time a room temperature sodium–sulfur (RT Na–S) full cell assembled based on a pristine hard carbon (HC) anode combined with a nanostructured Na2S/C cathode. The development of cells without the demanding, time‐consuming and costly pre‐sodiation of the HC anode is essential for the realization of practically relevant RT Na–S prototype batteries. New approaches for Na2S/C cathode fabrication employing carbothermal reduction of Na2SO4 at varying temperatures (660 to 1060 °C) are presented. Initial evaluation of the resulting cathodes in a dedicated cell setup reveals 36 stable cycles and a capacity of 740 mAh gS−1, which correlates to ≈85% of the maximum value known from literature on Na2S‐based cells. The Na2S/C cathode with the highest capacity utilization is implemented into a full cell concept applying a pristine HC anode. Various full cell electrolyte compositions with fluoroethylene carbonate (FEC) additive have been combined with a special charging procedure during the first cycle supporting in situ solid electrolyte interphase (SEI) formation on the HC anode to obtain increased cycling stability and cathode utilization. The best performing cell setup has delivered a total of 350 mAh gS−1, representing the first functional full cell based on a Na2S/C cathode and a pristine HC anode today