14 research outputs found

    Optimization of the Cascade Code Parameters by the Criterion of the Boundary Value of the Interference Band and the Selection of the Decoding Algorithm

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    РассмотрСн ΠΊΠΎΠ³Π΅Ρ€Π΅Π½Ρ‚Π½Ρ‹ΠΉ ΠΊΠ°Π½Π°Π» ΠΏΠ΅Ρ€Π΅Π΄Π°Ρ‡ΠΈ Π΄Π°Π½Π½Ρ‹Ρ… с псСвдослучайной пСрСстройкой Ρ€Π°Π±ΠΎΡ‡Π΅ΠΉ частоты (ППРЧ), каскадным ΠΊΠΎΠ΄ΠΎΠΌ Π½Π° основС ансамбля ΠΎΡ€Ρ‚ΠΎΠ³ΠΎΠ½Π°Π»ΡŒΠ½Ρ‹Ρ… сигналов ΠΈ ΠΊΠΎΠ΄Π° Π ΠΈΠ΄Π°-Π‘ΠΎΠ»ΠΎΠΌΠΎΠ½Π°, с Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹ΠΌΠΈ Π°Π»Π³ΠΎΡ€ΠΈΡ‚ΠΌΠ°ΠΌΠΈ ΠΏΡ€ΠΈΠ΅ΠΌΠ°-дСкодирования Π² условиях ΠΎΠ΄Π½ΠΎΠ²Ρ€Π΅ΠΌΠ΅Π½Π½ΠΎΠ³ΠΎ дСйствия Π½Π° ΠΊΠ°Π½Π°Π» Π΄Π²ΡƒΡ… ΠΏΠΎΠΌΠ΅Ρ… – Π·Π°Π³Ρ€Π°Π΄ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΉ ΠΈ сосрСдоточСнной Π² части полосы ППРЧ. ΠŸΠΎΠ»ΡƒΡ‡Π΅Π½Ρ‹ ΠΎΡ†Π΅Π½ΠΊΠΈ Π³Ρ€Π°Π½ΠΈΡ‡Π½ΠΎΠ³ΠΎ значСния части полосы ППРЧ, Π½Π°ΠΊΡ€Ρ‹Ρ‚ΠΎΠΉ ΠΏΠΎΠΌΠ΅Ρ…ΠΎΠΉ, характСристики ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½ΠΎΠ³ΠΎ каскадного ΠΊΠΎΠ΄Π°, Π° Ρ‚Π°ΠΊΠΆΠ΅ Π²Ρ‹Π±Ρ€Π°Π½ Π°Π»Π³ΠΎΡ€ΠΈΡ‚ΠΌ ΠΏΡ€ΠΈΠ΅ΠΌΠ°-дСкодирования, ΠΏΡ€ΠΈ ΠΊΠΎΡ‚ΠΎΡ€ΠΎΠΌ Π³Ρ€Π°Π½ΠΈΡ‡Π½ΠΎΠ΅ Π·Π½Π°Ρ‡Π΅Π½ΠΈΠ΅ части полосы, Π½Π°ΠΊΡ€Ρ‹Ρ‚ΠΎΠΉ ΠΏΠΎΠΌΠ΅Ρ…ΠΎΠΉ, ΠΏΡ€ΠΈΠ½ΠΈΠΌΠ°Π΅Ρ‚ максимальноС Π·Π½Π°Ρ‡Π΅Π½ΠΈΠ΅ Π² Π·Π°Π΄Π°Π½Π½ΠΎΠΉ ΠΏΠΎΠΌΠ΅Ρ…ΠΎΠ²ΠΎΠΉ обстановкСA coherent data transmission channel with pseudo-random tuning of the operating frequency (FH) is considered, a concatenated code based on an ensemble of orthogonal signals and a Reed-Solomon code, with various reception-decoding algorithms under conditions of simultaneous action on the channel of two interference – a barrage and a FH concentrated in a part of the band. The estimates of the boundary value of the part of the FH band covered by the interference, the characteristics of the optimal concatenated code, are obtained, and also the receive-decoding algorithm is selected, in which the boundary value of the part of the band covered by the interference takes the maximum value in a given interference environmen

    A Generalized Technique for Studying the Information Properties of Channels and Recognition Systems

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    Π’ Ρ€Π°Π±ΠΎΡ‚Π΅ ΠΏΡ€Π΅Π΄Π»ΠΎΠΆΠ΅Π½Π° обобщённая ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΈΠΊΠ° исслСдования ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Ρ… свойств ΠΊΠ°Π½Π°Π»ΠΎΠ² ΠΈ систСм распознавания, примСнимая для Π°Π½Π°Π»ΠΈΠ·Π° комплСксных систСм распознавания. ΠŸΡ€ΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΈΠΊΠΈ ΠΏΠΎΠΊΠ°Π·Π°Π»ΠΎ, Ρ‡Ρ‚ΠΎ ΠΏΡ€ΠΈ объСдинСнии Ρ€Π°Π·Π½ΠΎΡ€ΠΎΠ΄Π½Ρ‹Ρ… ΠΊΠ°Π½Π°Π»ΠΎΠ² для распознавания эффСктивно использованиС Π½Π΅ Ρ‚ΠΎΠ»ΡŒΠΊΠΎ прямой, Π½ΠΎ ΠΈ косвСнной ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΈ ΠΎ принадлСТности ΠΎΠ±ΡŠΠ΅ΠΊΡ‚Π° ΠΊ классам Π² Π°Π»Ρ„Π°Π²ΠΈΡ‚Π΅ ΠΎΠΊΠΎΠ½Ρ‡Π°Ρ‚Π΅Π»ΡŒΠ½Ρ‹Ρ… (ΠΎΠ±Ρ‰ΠΈΡ…) Ρ€Π΅ΡˆΠ΅Π½ΠΈΠΉ. ОбъСдинСниС ΠΊΠ°Π½Π°Π»ΠΎΠ² с основной ΠΈ косвСнной ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠ΅ΠΉ ΡƒΠ²Π΅Π»ΠΈΡ‡ΠΈΠ»ΠΎ количСство ΠΏΠΎΠ»ΡƒΡ‡Π°Π΅ΠΌΠΎΠΉ ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΈ Π½Π° 10–40 %The paper proposes a generalized methodology for studying the information properties of channels and recognition systems, applicable to the analysis of complex recognition systems. The application of the technique showed that when combining heterogeneous channels for recognition, it is effective to use not only direct, but also indirect information about the object’s belonging to classes in the alphabet of final (general) solutions. Combining channels with basic and indirect information increased the amount of information received by 10–40 percen

    Jamming Resistance of the Inbound Channel of an Identification System with Broadband Signals and Error Control Codes in the Conditions of Pulse Noise and Intra-System Jamming

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    ΠŸΡ€ΠΈΠ²ΠΎΠ΄ΡΡ‚ΡΡ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹ ΠΎΡ†Π΅Π½ΠΊΠΈ помСхоустойчивости запросного ΠΊΠ°Π½Π°Π»Π° Ρ€Π°Π΄ΠΈΠΎΠ»ΠΎΠΊΠ°Ρ†ΠΈΠΎΠ½Π½ΠΎΠ³ΠΎ опознавания с ΡˆΠΈΡ€ΠΎΠΊΠΎΠΏΠΎΠ»ΠΎΡΠ½Ρ‹ΠΌΠΈ сигналами Π² условиях ΠΈΠΌΠΏΡƒΠ»ΡŒΡΠ½Ρ‹Ρ… ΡˆΡƒΠΌΠΎΠ²Ρ‹Ρ… ΠΈ внутрисистСмных ΠΏΠΎΠΌΠ΅Ρ…. ΠžΠΏΡ€Π΅Π΄Π΅Π»ΡΡŽΡ‚ΡΡ ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½Ρ‹Π΅ сигнально-ΠΊΠΎΠ΄ΠΎΠ²Ρ‹Π΅ конструкции ΠΎΡ€Ρ‚ΠΎΠ³ΠΎΠ½Π°Π»ΡŒΠ½Ρ‹Ρ… ΡˆΠΈΡ€ΠΎΠΊΠΎΠΏΠΎΠ»ΠΎΡΠ½Ρ‹Ρ… сигналов с ΠΊΠΎΡ€Ρ€Π΅ΠΊΡ‚ΠΈΡ€ΡƒΡŽΡ‰ΠΈΠΌΠΈ ΠΊΠΎΠ΄Π°ΠΌΠΈ Π ΠΈΠ΄Π°-Π‘ΠΎΠ»ΠΎΠΌΠΎΠ½Π° для Ρ€Π°Π·Π»ΠΈΡ‡Π½Ρ‹Ρ… характСристик Π²ΠΎΠ·Π΄Π΅ΠΉΡΡ‚Π²ΡƒΡŽΡ‰ΠΈΡ… ΠΏΠΎΠΌΠ΅Ρ…Results of an assessment of a noise stability of the request channel of a radar-tracking identification with broadband signals in the conditions of pulse noise and intersystem hindrances are given. Optimum alarm and code designs of orthogonal broadband signals decide on Read-Solomon’s correcting codes for various characteristics of influencing hindrance

    Characteristics of Strobeless Identification of Trajectories of Air Objects in Positioning and Radar Identification

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    ΠŸΡ€Π΅Π΄ΡΡ‚Π°Π²Π»Π΅Π½Ρ‹ характСристики отоТдСствлСния Π΄Π°Π½Π½Ρ‹Ρ… ΡΠΏΠ΅Ρ†ΠΈΠ°Π»ΡŒΠ½ΠΎΠ³ΠΎ (Π²ΠΎΠ΅Π½Π½ΠΎΠ³ΠΎ) автоматичСского зависимого ΠΈ Ρ€Π°Π΄ΠΈΠΎΠ»ΠΎΠΊΠ°Ρ†ΠΈΠΎΠ½Π½ΠΎΠ³ΠΎ наблюдСний Π²ΠΎΠ·Π΄ΡƒΡˆΠ½Ρ‹Ρ… ΠΎΠ±ΡŠΠ΅ΠΊΡ‚ΠΎΠ² ΠΏΡ€ΠΈ ΠΈΡ… ΠΊΠΎΠΎΡ€Π΄ΠΈΠ½Π°Ρ‚Π½ΠΎ-связном ΠΎΠΏΠΎΠ·Π½Π°Π²Π°Π½ΠΈΠΈ. Π₯арактСристики ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Ρ‹ Π² Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Π΅ статистичСского ΠΈΠΌΠΈΡ‚Π°Ρ†ΠΈΠΎΠ½Π½ΠΎΠ³ΠΎ модСлирования Π°Π»Π³ΠΎΡ€ΠΈΡ‚ΠΌΠ° бСсстробового отоТдСствлСния Ρ‚Ρ€Π°Π΅ΠΊΡ‚ΠΎΡ€ΠΈΠΉ, синтСзированного ΠΏΠΎ ΠΌΠ΅Ρ‚ΠΎΠ΄Ρƒ, основанному Π½Π° Ρ‚Π΅ΠΎΡ€ΠΈΠΈ ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½ΠΎΠΉ Ρ„ΠΈΠ»ΡŒΡ‚Ρ€Π°Ρ†ΠΈΠΈ дискрСтно-Π½Π΅ΠΏΡ€Π΅Ρ€Ρ‹Π²Π½Ρ‹Ρ… марковских случайных процСссов. Π’Ρ‹ΠΏΠΎΠ»Π½Π΅Π½ΠΎ сравнСниС этих характСристик с характСристиками бСсстробового ΠΈ стробового отоТдСствлСний ΠΏΡ€ΠΈ Ρ€Π°Π΄ΠΈΠΎΠ»ΠΎΠΊΠ°Ρ†ΠΈΠΎΠ½Π½ΠΎΠΌ ΠΎΠΏΠΎΠ·Π½Π°Π²Π°Π½ΠΈΠΈThe characteristics of identification of data of special (military) automatic dependent and radar observations of air objects during their coordinate-connected identification are presented. The characteristics are obtained as a result of statistical simulation of the algorithm for strobeless identification of trajectories, synthesized by a method based on the theory of optimal filtering of discrete-continuous Markov random processes. These characteristics are compared with the characteristics of strobeless and strobe identification in radar identificatio

    Immunity of the Data Transmission Channel with FHSS when Soft Decoding by Means of Spectral Density Estimation of Interference Power

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    ΠŸΠΎΠ»ΡƒΡ‡Π΅Π½Ρ‹ характСристики помСхоустойчивости ΠΊΠΎΠ³Π΅Ρ€Π΅Π½Ρ‚Π½ΠΎΠ³ΠΎ ΠΊΠ°Π½Π°Π»Π° ΠΏΠ΅Ρ€Π΅Π΄Π°Ρ‡ΠΈ Π΄Π°Π½Π½Ρ‹Ρ… с псСвдослучайной пСрСстройкой Ρ€Π°Π±ΠΎΡ‡Π΅ΠΉ частоты (ППРЧ), ΠΎΡ€Ρ‚ΠΎΠ³ΠΎΠ½Π°Π»ΡŒΠ½Ρ‹ΠΌΠΈ сигналами ΠΈ ΠΊΠΎΠ΄ΠΎΠΌ Π ΠΈΠ΄Π°-Π‘ΠΎΠ»ΠΎΠΌΠΎΠ½Π° ΠΏΡ€ΠΈ Π΅Π³ΠΎ мягком Π΄Π΅ΠΊΠΎΠ΄ΠΈΡ€ΠΎΠ²Π°Π½ΠΈΠΈ с использованиСм ΠΎΡ†Π΅Π½ΠΎΠΊ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠΉ плотности мощности ΠΏΠΎΠΌΠ΅Ρ…ΠΈ, ΠΏΡ€Π΅Π΄ΡΡ‚Π°Π²Π»ΡΡŽΡ‰Π΅ΠΉ собой ΡΠΎΠ²ΠΎΠΊΡƒΠΏΠ½ΠΎΡΡ‚ΡŒ Π΄Π²ΡƒΡ… гауссовских ΡˆΡƒΠΌΠΎΠ²Ρ‹Ρ… ΠΏΠΎΠΌΠ΅Ρ… – Π·Π°Π³Ρ€Π°Π΄ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΉ ΠΈ сосрСдоточСнной Π² части полосы ППРЧ. УстановлСно, Ρ‡Ρ‚ΠΎ ΠΏΡ€ΠΈ ΡƒΠ²Π΅Π»ΠΈΡ‡Π΅Π½ΠΈΠΈ объСма ансамбля ΠΎΡ€Ρ‚ΠΎΠ³ΠΎΠ½Π°Π»ΡŒΠ½Ρ‹Ρ… сигналов ΠΏΠΎΠΌΠ΅Ρ…ΠΎΡƒΡΡ‚ΠΎΠΉΡ‡ΠΈΠ²ΠΎΡΡ‚ΡŒ ΠΏΠΎΠ²Ρ‹ΡˆΠ°Π΅Ρ‚ΡΡ Π·Π° счСт ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΡ точности ΠΎΡ†Π΅Π½ΠΊΠΈ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠΉ плотности мощности ΠΏΠΎΠΌΠ΅Ρ…ΠΈ, Ρ‡Ρ‚ΠΎ Π² свою ΠΎΡ‡Π΅Ρ€Π΅Π΄ΡŒ обСспСчиваСт ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΠ΅ точности ΠΎΡ†Π΅Π½ΠΊΠΈ апостСриорной вСроятности, ΠΈΡΠΏΠΎΠ»ΡŒΠ·ΡƒΠ΅ΠΌΠΎΠΉ ΠΏΡ€ΠΈ Π΄Π΅ΠΊΠΎΠ΄ΠΈΡ€ΠΎΠ²Π°Π½ΠΈΠΈ мягких Ρ€Π΅ΡˆΠ΅Π½ΠΈΠΉThe characteristics of noise immunity of a coherent data transmission channel with Frequency Hopping Spread Spectrum (FHSS), orthogonal signals and Reed-Solomon code with its soft decoding have been obtained using spectral density estimation of interference power, which is a combination of two Gaussian noise interference, they are barrage jamming and one concentrated in the FHSS band part. It is found that when the volume of an orthogonal signals ensemble increases, noise immunity rises due to the accuracy growth of the spectral density estimation of the interference power, which in turn provides an accuracy growth of posterior probability estimation used for soft-decision decodin

    Structure and electrical properties of zinc oxide base iron doped ceramics

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    The search for new economically advantageous technologies of new zinc oxide based composite ceramic materials and the study of their structure and properties attract special attention today. These ceramics have a number of advantages as compared with materials prepared by more expensive technologies, due to the possibility to fabricate items having different shapes and sizes and particularly to vary their morphology, structure and phase composition. This allows controlling their functional properties by varying the powder particle size in charge, the temperatures, durations and atmospheres of synthesis and heat treatment, and the types of doping impurities in the ceramics. The structure and electrical properties of (FexOy)10(ZnO)90 ceramics (0 ≀ x ≀ 3; 1 ≀ y ≀ 4) synthesized in air using single- and two-stage synthesis methods have been studied. FeO, Ξ±-Fe2O3 and Fe3O4 powders or (Ξ±-Fe2O3 + FeO) mixture have been used for ZnO doping. X-ray diffraction, gamma-ray resonance spectroscopy and Raman spectroscopy data suggest that at average iron concentrations of 1–3 at.% the ceramic specimens contain at least three phases: the Zn1-Ξ΄FeΞ΄O solid solution with a wurtzite structure, the ZnFe2O4 ferrite phase with a spinel structure and FexOy residual iron oxides which were used as doping impurities. Scanning electron microscopy and energy dispersion X-ray analysis have shown that the wurtzite phase grain size in the ceramic specimens decreases from several decades of microns for single-stage synthesis to submicron sizes for two- stage synthesis. We show that iron addition to ZnO induces a compression of the wurtzite phase crystal lattice, the compression of lattice magnitude being proportional to the oxygen content in the FexOy iron oxide doping agent. The temperature dependences of the electrical resistivity suggest that deep donor centers with an activation energy of about 0.37 eV are formed in the Zn1-Ξ΄FeΞ΄O wurtzite phase. The temperature dependences of the electrical resistivity of electrons for undoped ZnO in the 6–300 K range and for doped (FeO)10(ZnO)90 ceramic synthesized in one stage exhibit a variable activation energy below 50 K which indicates a heavily disordered structure

    Estimation of Parameters of Signal Mixture with Noise Based on Monitoring Outputs of the Multichannel Device of Orthogonal Signals Distinction at Coherent Reception

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    ΠŸΠΎΠ»ΡƒΡ‡Π΅Π½Ρ‹ матСматичСскиС выраТСния для ΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½Ρ‹Ρ… ΠΈ ΠΊΠ²Π°Π·ΠΈΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½Ρ‹Ρ… ΠΎΡ†Π΅Π½ΠΎΠΊ ΠΎΡ‚Π½ΠΎΡˆΠ΅Π½ΠΈΡ сигнал/ΡˆΡƒΠΌ ΠΈ ΡΠΏΠ΅ΠΊΡ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠΉ плотности мощности ΡˆΡƒΠΌΠ°, Ρ„ΠΎΡ€ΠΌΠΈΡ€ΡƒΠ΅ΠΌΡ‹Ρ… ΠΏΠΎ наблюдСнию Π²Ρ‹Ρ…ΠΎΠ΄ΠΎΠ² ΠΊΠΎΠ³Π΅Ρ€Π΅Π½Ρ‚Π½ΠΎΠ³ΠΎ многоканального устройства различСния ΠΎΡ€Ρ‚ΠΎΠ³ΠΎΠ½Π°Π»ΡŒΠ½Ρ‹Ρ… сигналов. УстановлСно, Ρ‡Ρ‚ΠΎ, обрабатывая Π²Ρ‹Ρ…ΠΎΠ΄Ρ‹ ΠΊΠ°Π½Π°Π»ΠΎΠ² Π² ΠΌΠ½ΠΎΠ³ΠΎΠΊΠ°Π½Π°Π»ΡŒΠ½Ρ‹Ρ… устройствах различСния ΠΎΡ€Ρ‚ΠΎΠ³ΠΎΠ½Π°Π»ΡŒΠ½Ρ‹Ρ… сигналов, ΠΌΠΎΠΆΠ½ΠΎ Ρ„ΠΎΡ€ΠΌΠΈΡ€ΠΎΠ²Π°Ρ‚ΡŒ практичСски Ρ€Π΅Π°Π»ΠΈΠ·ΡƒΠ΅ΠΌΡ‹Π΅ ΠΊΠ²Π°Π·ΠΈΠΎΠΏΡ‚ΠΈΠΌΠ°Π»ΡŒΠ½Ρ‹Π΅ ΠΎΡ†Π΅Π½ΠΊΠΈ ΠΎΡ‚Π½ΠΎΡˆΠ΅Π½ΠΈΡ сигнал/ΡˆΡƒΠΌ ΠΈΠ»ΠΈ ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€ΠΎΠ² ΡˆΡƒΠΌΠ° с достаточно высокой Ρ‚ΠΎΡ‡Π½ΠΎΡΡ‚ΡŒΡŽMathematical expressions for optimal and quasi-optimal estimations of signal/noise relation and spectral density of noise capacity, based on monitoring outputs of the coherent multichannel device of distinction of orthogonal signals have been received. It was found that, by means of processing outputs of channels in multichannel devices of distinction of orthogonal signals, one can make almost implementable quasi-optimal estimations of signal/noise relation or noise parameters with rather high accurac

    Thermal and thermoelectric properties of metal-doped zinc oxide ceramics

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    The thermal, electrical and thermoelectric properties of ZnO–MexOy ceramics with 1 ≀ x, y ≀ 3, where Me = Al, Co, Fe, Ni, Ti, have been studied. The specimens have been synthesized using the ceramic sintering technology from two or more oxides in an open atmosphere with annealing temperature and time variation. The structural and phase data on the ceramics have shown that post-synthesis addition of MexOy doping powders to wurtzite-structured ZnO powder causes Znx (MΠ΅)yO4 spinel-like second phase precipitation and a 4-fold growth of ceramics porosity. Room temperature heat conductivity studies have testified to predominant lattice contribution. A decrease in the heat conductivity upon doping proves to be caused by phonon scattering intensification due to the following factors: size factor upon zinc ion substitution in the ZnO lattice (wurtzite) by MexOy doping oxide metal ions; defect formation, i.e., point defects, grain boundaries (microstructure refinement); porosity growth (density decline); secondary phase particle nucleation (Znx (MΠ΅)yO4 spinel-like ones). The above listed factors entailed by zinc ion substitution for metal ions (Co, Al, Ti, Ni, Fe) increase the figure-of-merit ZT by four orders of magnitude (due to a decrease in the electrical resistivity and heat conductivity coupled with a moderate thermo-emf decline). The decrease in the electrical resistivity originates from a more homogeneous distribution of doping metal ions in the wurtzite lattice upon longer annealing which increases the number of donor centers

    New Efficient Organic Scintillators Derived from Pyrazoline

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    We report on the synthesis, spectroscopic and scintillation properties of three new pyrazoline core based fluorophores. Fluorescence properties of the fluorophores have been studied both in a solution state and in a solid polyvinyltoluene (PVT) resin matrix of different porosity. The synthesized fluorophores were found to be promising candidates for application in plastic scintillators for detection of ionizing radiation (alpha, beta particles, Ξ³ rays and neutrons) and demonstrated superior efficiency in comparison to the existing commercially used fluorophores (2-(1-naphthyl)-5-phenyloxazole (Ξ±NPO), 9,10-diphenylanthracene, etc.). Moreover, the suggested synthetic route allows functionalization of the fluorophores with a vinyl group for further covalent bound to the PVT or other vinyl polymer matrices, which dramatically improves chemical stability of the system simultaneously improving the photoluminescence quantum yield. Possible mechanisms of the enhanced scintillation properties are discussed based on preliminary quantum mechanical calculations and spectroscopic characteristics of the fluorophores under study

    Evolution and Interdependence of Structure and Properties of Nanocomposites of Multiwall Carbon Nanotubes with Polyaniline

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    Structure–property relationships of nanocomposites of multiwall carbon nanotubes (MWCNTs) and polyaniline (PANI) doped with dodecylbenzenesulfonic acid (DBSA) are studied and discussed in terms of contribution of the PANI phase properties. Two phases of PANI-DBSA with different properties, such as a shell-wrapping carbon nanotube and separate neat PANI-DBSA domains, are revealed for the first time in the nanocomposites with a high or medium PANI-DBSA content. In the nanocomposites with lower PANI-DBSA contents (<40 wt %), only a core–shell morphology with ∼3 nm or lower thickness PANI shell on the nanotubes is observed. Under this condition, the degree of crystallinity of the PANI-DBSA shell increases almost 2-fold, and thermal stability of the nanocomposite grows sharply. As compared with the neat PANI-DBSA, this special PANI shell phase has more perfect molecular structure and is characterized by a reduced amount of DBSA. It is found that the latter is caused by a competition between the processes of doping of the formed PANI in the shell by the protonic acid and p-doping caused by the MWCNT surface. The nanocomposites demonstrate ppm/ppb range sensitivity to ammonia/methylamine gases with response times, which inversely depend on the PANI-DBSA contents and thickness of the shell
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