Structure, bonding and morphology of hydrothermally synthesised xonotlite

The authors have systematically investigated the role of synthesis conditions upon the structure and morphology of xonotlite. Starting with a mechanochemically prepared, semicrystalline phase with Ca/Si=1, the authors have prepared a series of xonotlite samples hydrothermally, at temperatures between 200 and 250 degrees C. Analysis in each case was by X-ray photoelectron spectroscopy, environmental scanning electron microscopy and X-ray diffraction. The authors’ use of a much lower water/solid ratio has indirectly confirmed the ‘through solution’ mechanism of xonotlite formation, where silicate dissolution is a key precursor of xonotlite formation. Concerning the role of temperature, too low a temperature (~200 degrees C) fails to yield xonotlite or leads to increased number of structural defects in the silicate chains of xonotlite and too high a temperature (>250 degrees C) leads to degradation of the xonotlite structure, through leaching of interchain calcium. Synthesis duration meanwhile leads to increased silicate polymerisation due to diminishing of the defects in the silicate chains and more perfect crystal morphologies

Evolution and complexity: the double-edged sword

We attempt to provide a comprehensive answer to the question of whether, and when, an arrow of complexity emerges in Darwinian evolution. We note that this expression can be interpreted in different ways, including a passive, incidental growth, or a pervasive bias towards complexification. We argue at length that an arrow of complexity does indeed occur in evolution, which can be most reasonably interpreted as the result of a passive trend rather than a driven one. What, then, is the role of evolution in the creation of this trend, and under which conditions will it emerge? In the later sections of this article we point out that when certain proper conditions (which we attempt to formulate in a concise form) are met, Darwinian evolution predictably creates a sustained trend of increase in maximum complexity (that is, an arrow of complexity) that would not be possible without it; but if they are not, evolution will not only fail to produce an arrow of complexity, but may actually prevent any increase in complexity altogether. We conclude that, with regard to the growth of complexity, evolution is very much a double-edged sword

The Behaviour of Finely Ground Bottom Ash in Portland Cement

The aim of this project was to assess the effects of finely ground MSWI bottom ash in Portland cement. Mortar mixes were prepared with 10% and 40% replacement of cement by ground IBA and then tested with regards to their material composition and engineering behaviour. IBA was found not to be inert, but showed some degree of reactivity. Replacement of cement with IBA was found to have no detrimental effects at low concentrations. This was not the case for 40% replacement, where cement replacement greatly affected strength, creep and drying shrinkage

A new nickel-base wrought superalloy for applications up to 1033 K (1400 F)

Alloy was melted from high purity raw materials and cast ingots extruded at 1422 K. Material was hot rolled to 0.013 m diameter bar stock. Partial solution heat-treatment followed by aging produced structure of fine gamma prime precipitate reinforcing gamma matrix containing coarser blocky gamma prime particles. Alloy can be processed by powder metallurgy

Molecular clouds in the centers of galaxies: Constraints from HCN and CO-13 line emission

We have searched for HCN J=1-0 line emission in the centers of 12 galaxies and have detected it in 10 of them. We have obtained complementary data on J=1-0 and 2-1 transitions of CO-12 and CO-13 in these systems. The ratio of integrated intensities, I(CO 1-0)/I(HCN 1-0) = 25 +/- 11 for this sample. We find that HCN emission of this strength can be produced under conditions of subthermal excitation. In combination with the line ratios in CO and CO-13, HCN puts constraints on the mean conditions of molecular clouds and on the mix of cloud types within the projected beam

The Effect of Co-Combusted Biomass-Coal Fly Ash on the Behaviour Portland Cement

This project has investigated the hydration behaviour of pfa-OPC blended cements, comparing conventional pfa with that obtained from co-firing of coal with biomass (palm kernel expeller). Calorimetry, thermal analysis and electron microscopy have been used to investigate the compositions and microstructures of the hydrated pastes. These have been used to explain the materials’ engineering properties (strength development and workability). The results showed that, in the short term, the behaviour of the co-fired material is comparable with that of conventional pfa, there being no discernable differences between the two systems

Possible Observational Criteria for Distinguishing Brown Dwarfs from Planets

The difference in formation process between binary stars and planetary systems is reflected in their composition as well as their orbital architecture, particularly orbital eccentricity as a function of orbital period. It is suggested here that this difference can be used as an observational criterion to distinguish between brown dwarfs and planets. Application of the orbital criterion suggests that with three possible exceptions, all of the recently-discovered substellar companions discovered to date may be brown dwarfs and not planets. These criterion may be used as a guide for interpretation of the nature of sub-stellar mass companions to stars in the future.Comment: LaTeX, 11 pages including 2 figures, accepted for publication in the Astrophysical Journal Letter

Spinor Dynamics in an Antiferromagnetic Spin-1 Condensate

We observe coherent spin oscillations in an antiferromagnetic spin-1 Bose-Einstein condensate of sodium. The variation of the spin oscillations with magnetic field shows a clear signature of nonlinearity, in agreement with theory, which also predicts anharmonic oscillations near a critical magnetic field. Measurements of the magnetic phase diagram agree with predictions made in the approximation of a single spatial mode. The oscillation period yields the best measurement to date of the sodium spin-dependent interaction coefficient, determining that the difference between the sodium spin-dependent s-wave scattering lengths $a_{f=2}-a_{f=0}$ is $2.47\pm0.27$ Bohr radii.Comment: 5 pages, 2 figures. Changes: added reference, minor correction