12 research outputs found
Spontaneous and induced dynamic correlations in glass-formers II: Model calculations and comparison to numerical simulations
We study in detail the predictions of various theoretical approaches, in
particular mode-coupling theory (MCT) and kinetically constrained models
(KCMs), concerning the time, temperature, and wavevector dependence of
multi-point correlation functions that quantify the strength of both induced
and spontaneous dynamical fluctuations. We also discuss the precise predictions
of MCT concerning the statistical ensemble and microscopic dynamics dependence
of these multi-point correlation functions. These predictions are compared to
simulations of model fragile and strong glass-forming liquids. Overall, MCT
fares quite well in the fragile case, in particular explaining the observed
crucial role of the statistical ensemble and microscopic dynamics, while MCT
predictions do not seem to hold in the strong case. KCMs provide a simplified
framework for understanding how these multi-point correlation functions may
encode dynamic correlations in glassy materials. However, our analysis
highlights important unresolved questions concerning the application of KCMs to
supercooled liquids.Comment: 23 pages, 12 fig
Critical fluctuations and breakdown of Stokes-Einstein relation in the Mode-Coupling Theory of glasses
We argue that the critical dynamical fluctuations predicted by the
mode-coupling theory (MCT) of glasses provide a natural mechanism to explain
the breakdown of the Stokes-Einstein relation. This breakdown, observed
numerically and experimentally in a region where MCT should hold, is one of the
major difficulty of the theory, for which we propose a natural resolution based
on the recent interpretation of the MCT transition as a bona fide critical
point with a diverging length scale. We also show that the upper critical
dimension of MCT is d_c=8.Comment: Proceedings of the workshop on non-equilibrium phenomena in
supercooled fluids, glasses and amorphous materials (17-22 September, 2006,
Pisa
Analytic determination of dynamical and mosaic length scales in a Kac glass model
We consider a disordered spin model with multi-spin interactions undergoing a
glass transition. We introduce a dynamic and a static length scales and compute
them in the Kac limit (long--but--finite range interactions). They diverge at
the dynamic and static phase transition with exponents (respectively) -1/4 and
-1. The two length scales are approximately equal well above the mode coupling
transition. Their discrepancy increases rapidly as this transition is
approached. We argue that this signals a crossover from mode coupling to
activated dynamics.Comment: 4 pages, 4 eps figures. New version conform to the published on
Dynamical field theory for glass-forming liquids, self-consistent resummations and time-reversal symmetry
We analyse the symmetries and the self-consistent perturbative approaches of
dynamical field theories for glassforming liquids. In particular, we focus on
the time-reversal symmetry (TRS), which is crucial to obtain
fluctuation-dissipation relations (FDRs). Previous field theoretical treatment
violated this symmetry, whereas others pointed out that constructing symmetry
preserving perturbation theories is a crucial and open issue. In this work we
solve this problem and then apply our results to the mode-coupling theory of
the glass transition (MCT). We show that in the context of dynamical field
theories for glass-forming liquids TRS is expressed as a nonlinear field
transformation that leaves the action invariant. Because of this nonlinearity,
standard perturbation theories generically do not preserve TRS and in
particular FDRs. We show how one can cure this problem and set up
symmetry-preserving perturbation theories by introducing some auxiliary fields.
As an outcome we obtain Schwinger-Dyson dynamical equations that automatically
preserve FDRs and that serve as a basis for carrying out symmetry-preserving
approximations. We apply our results to MCT, revisiting previous field theory
derivations of MCT equations and showing that they generically violate FDR. We
obtain symmetry-preserving mode-coupling equations and discuss their advantages
and drawbacks. Furthermore, we show, contrary to previous works, that the
structure of the dynamic equations is such that the ideal glass transition is
not cut off at any finite order of perturbation theory, even in the presence of
coupling between current and density. The opposite results found in previous
field theoretical works, such as the ones based on nonlinear fluctuating
hydrodynamics, were only due to an incorrect treatment of TRS.Comment: 54 pages, 21 figure
Non-linear susceptibilities of spherical models
The static and dynamic susceptibilities for a general class of mean field
random orthogonal spherical spin glass models are studied. We show how the
static and dynamical properties of the linear and nonlinear susceptibilities
depend on the behaviour of the density of states of the two body interaction
matrix in the neighbourhood of the largest eigenvalue. Our results are compared
with experimental results and also with those of the droplet theory of spin
glasses.Comment: 20 pages, 2 fig
Growing dynamical length, scaling and heterogeneities in the 3d Edwards-Anderson model
We study numerically spatio-temporal fluctuations during the
out-of-equilibrium relaxation of the three-dimensional Edwards-Anderson model.
We focus on two issues. (1) The evolution of a growing dynamical length scale
in the glassy phase of the model, and the consequent collapse of the
distribution of local coarse-grained correlations measured at different pairs
of times on a single function using {\it two} scaling parameters, the value of
the global correlation at the measuring times and the ratio of the coarse
graining length to the dynamical length scale (in the thermodynamic limit). (2)
The `triangular' relation between coarse-grained local correlations at three
pairs of times taken from the ordered instants .
Property (1) is consistent with the conjecture that the development of
time-reparametrization invariance asymptotically is responsible for the main
dynamic fluctuations in aging glassy systems as well as with other mechanisms
proposed in the literature. Property (2), we stress, is a much stronger test of
the relevance of the time-reparametrization invariance scenario.Comment: 24 pages, 12 fig
Fluctuations in glassy systems
We summarize a theoretical framework based on global time-reparametrization
invariance that explains the origin of dynamic fluctuations in glassy systems.
We introduce the main ideas without getting into much technical details. We
describe a number of consequences arising from this scenario that can be tested
numerically and experimentally distinguishing those that can also be explained
by other mechanisms from the ones that we believe, are special to our proposal.
We support our claims by presenting some numerical checks performed on the 3d
Edwards-Anderson spin-glass. Finally, we discuss up to which extent these ideas
apply to super-cooled liquids that have been studied in much more detail up to
present.Comment: 33 pages, 7 figs, contribution to JSTAT special issue `Principles of
Dynamical Systems' work-shop at Newton Institute, Univ. of Cambridge, U