Structural disorder, magnetism, and electrical and thermoelectric properties of pyrochlore Nd2Ru2O7

Polycrystalline Nd2Ru2O7 samples have been prepared and examined using a combination of structural, magnetic, and electrical and thermal transport studies. Analysis of synchrotron X-ray and neutron diffraction patterns suggests some site disorder on the A-site in the pyrochlore sublattice: Ru substitutes on the Nd-site up to 7.0(3)%, regardless of the different preparative conditions explored. Intrinsic magnetic and electrical transport properties have been measured. Ru 4d spins order antiferromagnetically at 143 K as seen both in susceptibility and specific heat, and there is a corresponding change in the electrical resistivity behaviour. A second antiferromagnetic ordering transition seen below 10 K is attributed to ordering of Nd 4f spins. Nd2Ru2O7 is an electrical insulator, and this behaviour is believed to be independent of the Ru-antisite disorder on the Nd site. The electrical properties of Nd2Ru2O7 are presented in the light of data published on all A2Ru2O7 pyrochlores, and we emphasize the special structural role that Bi3+ ions on the A-site play in driving metallic behaviour. High-temperature thermoelectric properties have also been measured. When considered in the context of known thermoelectric materials with useful figures-of-merit, it is clear that Nd2Ru2O7 has excessively high electrical resistivity which prevents it from being an effective thermoelectric. A method for screening candidate thermoelectrics is suggested.Comment: 19 pages, 10 figure

Development of a Risk Framework for Industry 4.0 in the Context of Sustainability for Established Manufacturers

The concept of “Industry 4.0” is expected to bring a multitude of benefits for industrial value creation. However, the associated risks hamper its implementation and lack a comprehensive overview. In response, the paper proposes a framework of risks in the context of Industry 4.0 that is related to the Triple Bottom Line of sustainability. The framework is developed from a literature review, as well as from 14 in-depth expert interviews. With respect to economic risks, the risks that are associated with high or false investments are outlined, as well as the threatened business models and increased competition from new market entrants. From an ecological perspective, the increased waste and energy consumption, as well as possible ecological risks related to the concept “lot size one”, are described. From a social perspective, the job losses, risks associated with organizational transformation, and employee requalification, as well as internal resistance, are among the aspects that are considered. Additionally, risks can be associated with technical risks, e.g., technical integration, information technology (IT)-related risks such as data security, and legal and political risks, such as for instance unsolved legal clarity in terms of data possession. Conclusively, the paper discusses the framework with the extant literature, proposes managerial and theoretical implications, and suggests avenues for future research

Process-informed subsampling improves subseasonal rainfall forecasts in Central America

Subseasonal rainfall forecast skill is critical to support preparedness for hydrometeorological extremes. We assess how a process-informed evaluation, which subsamples forecasting model members based on their ability to represent potential predictors of rainfall, can improve monthly rainfall forecasts within Central America in the following month, using Costa Rica and Guatemala as test cases. We generate a constrained ensemble mean by subsampling 130 members from five dynamic forecasting models in the C3S multimodel ensemble based on their representation of both (a) zonal wind direction and (b) Pacific and Atlantic sea surface temperatures (SSTs), at the time of initialization. Our results show in multiple months and locations increased mean squared error skill by 0.4 and improved detection rates of rainfall extremes. This method is transferrable to other regions driven by slowly-changing processes. Process-informed subsampling is successful because it identifies members that fail to represent the entire rainfall distribution when wind/SST error increases

On The Injection Spectrum of Ultrahigh Energy Cosmic Rays in the Top-Down Scenario

We analyze the uncertainties involved in obtaining the injection spectra of UHECR particles in the top-down scenario of their origin. We show that the DGLAP $Q^2$ evolution of fragmentation functions (FF) to $Q=M_X$ (mass of the X particle) from their initial values at low $Q$ is subject to considerable uncertainties. We therefore argue that, for x\lsim 0.1 (the $x$ region of interest for most large $M_X$ values of interest, $x\equiv 2E/M_X$ being the scaled energy variable), the FF obtained from DGLAP evolution is no more reliable than that provided, for example, by a simple Gaussian form (in the variable $\ln(1/x)$) obtained under the Modified Leading Log Approximation (MLLA). Additionally, we find that for x\gsim0.1, the evolution in $Q^2$ of the singlet FF, which determines the injection spectrum, is ``minimal'' -- the singlet FF changes by barely a factor of 2 after evolving it over $\sim$ 14 orders of magnitude in $Q\sim M_X$. We, therefore, argue that as long as the measurement of the UHECR spectrum above \sim10^{20}\ev is going to remain uncertain by a factor of 2 or larger, it is good enough for most practical purposes to directly use any one of the available initial parametrisations of the FFs in the $x$ region x\gsim0.1 based on low energy data even without evolving them to the requisite $Q^2$ value.Comment: Minor changes, added a reference, version to appear in Phys. Rev.

Pulsar kicks from neutrino oscillations

Neutrino oscillations in a core-collapse supernova may be responsible for the observed rapid motions of pulsars. Given the present bounds on the neutrino masses, the pulsar kicks require a sterile neutrino with mass 2-20 keV and a small mixing with active neutrinos. The same particle can be the cosmological dark matter. Its existence can be confirmed the by the X-ray telescopes if they detect a 1-10 keV photon line from the decays of the relic sterile neutrinos. In addition, one may be able to detect gravity waves from a pulsar being accelerated by neutrinos in the event of a nearby supernova.Comment: invited review article to appear in Int. J. Mod. Phys. (21 pages, 6 figures

Status of Schottky Diagnostics in the ANKA Storage Ring

The status of longitudinal and transverse Schottky observation systems for the synchrotron light source ANKA is presented. ANKA regularly operates in a dedicated low alpha mode with short bunches for the generation of coherent THz radiation. The Schottky measurement results are shown and compared with theoretical predictions for the regular as well as the different stages of the low alpha mode of operation. Special care had to be taken to control and mitigate the impact from strong coherent lines of the short bunches on the signal processing chain. The system setup is shown, expected and unexpected observations as well as applications are discussed

Rapid Microwave Preparation of Thermoelectric TiNiSn and TiCoSb Half-Heusler Compounds

The 18-electron ternary intermetallic systems TiNiSn and TiCoSb are promising for applications as high-temperature thermoelectrics and comprise earth-abundant, and relatively nontoxic elements. Heusler and half-Heusler compounds are usually prepared by conventional solid state methods involving arc-melting and annealing at high temperatures for an extended period of time. Here, we report an energy-saving preparation route using a domestic microwave oven, reducing the reaction time significantly from more than a week to one minute. A microwave susceptor material rapidly heats the elemental starting materials inside an evacuated quartz tube resulting in near single phase compounds. The initial preparation is followed by a densification step involving hot-pressing, which reduces the amount of secondary phases, as verified by synchrotron X-ray diffraction, leading to the desired half-Heusler compounds, demonstrating that hot-pressing should be treated as part of the preparative process. For TiNiSn, high thermoelectric power factors of 2 mW/mK^2 at temperatures in the 700 to 800 K range, and zT values of around 0.4 are found, with the microwave-prepared sample displaying somewhat superior properties to conventionally prepared half-Heuslers due to lower thermal conductivity. The TiCoSb sample shows a lower thermoelectric figure of merit when prepared using microwave methods because of a metallic second phase

Superheavy dark matter and ultrahigh energy cosmic rays

The phase of inflationary expansion in the early universe produces superheavy relics in a mass window between 10^{12} GeV and 10^{14} GeV. Decay or annihilation of these superheavy relics can explain the observed ultrahigh energy cosmic rays beyond the Greisen-Zatsepin-Kuzmin cutoff. We emphasize that the pattern of cosmic ray arrival directions with energies beyond 20 EeV will decide between the different proposals for the origin of ultrahigh energy cosmic rays.Comment: Based on an invited talk given by RD at Theory Canada 1, Vancouver, June 2-5, 200

Measuring High Energy Neutrino-Nucleon Cross Sections With Future Neutrino Telescopes

Next generation kilometer-scale neutrino telescopes, such as ICECUBE, can test standard model predictions for neutrino-nucleon cross sections at energies well beyond the reach of collider experiments. At energies near a PeV and higher, the Earth becomes opaque to neutrinos. At these energies, the ratio of upgoing and downgoing events can be used to measure the total neutrino-nucleon cross section given the presence of an adequate high energy neutrino flux.Comment: 4 pages, 5 figure