Dynamic van der Waals Theory of two-phase fluids in heat flow

We present a dynamic van der Waals theory. It is useful to study phase separation when the temperature varies in space. We show that if heat flow is applied to liquid suspending a gas droplet at zero gravity, a convective flow occurs such that the temperature gradient within the droplet nearly vanishes. As the heat flux is increased, the droplet becomes attached to the heated wall that is wetted by liquid in equilibrium. In one case corresponding to partial wetting by gas, an apparent contact angle can be defined. In the ther case with larger heat flux, the droplet completely wets the heated wall expelling liquid.Comment: 6pages, 8figure

X-ray, optical and infrared investigation of the candidate Supergiant Fast X-ray Transient IGR J18462-0223

We report on a broad-band X-ray study (0.5-60 keV) of the poorly known candidate Supergiant Fast X-ray Transient (SFXT) IGR J18462-0223, and on optical and near-infrared (NIR) followup observations of field objects. The out-of-outburst X-ray state has been investigated for the first time with archival INTEGRAL/IBIS, ASCA, Chandra and Swift/XRT observations. This allowed us to place stringent 3 sigma upper limits on the soft (0.5-10 keV) and hard (18-60 keV) X-ray emission of 2.9x10^-13 erg cm^-2 s^-1 and 8x10^-12 erg cm^-2 s^-1, respectively; the source was also detected during an intermediate soft X-ray state with flux equal to 1.6x10^-11 erg cm^-2 s^-1 (0.5-10 keV). In addition, we report on the INTEGRAL/IBIS discovery of three fast hard X-ray flares (18-60 keV) having a duration in the range 1-12 hours: the flaring behavior was also investigated in soft X-rays (3-10 keV) with archival INTEGRAL/JEM-X observations. The duty cycle (1.2%) and the dynamic ranges (> 1,380 and > 190 in the energy bands 0.5-10 keV and 18-60 keV, respectively) were measured for the first time. Archival UKIDSS JHK NIR data, together with our deep R-band imaging of the field, unveiled a single, very red object inside the intersection of the Swift/XRT and XMM-Newton error circles: this source has optical/NIR photometric properties compatible with a very heavily absorbed blue supergiant located at about 11 kpc, thus being a strong candidate counterpart for IGR J18462-0223. NIR spectroscopy is advised to confirm the association. Finally, a hint of a possible orbital period was found at about 2.13 days. If confirmed by further studies, this would make IGR J18462-0223 the SFXT with the shortest orbital period among the currently known systems.Comment: accepted for publication in A&A, 9 pages, 7 figures, 2 table

Statistical mechanical theory of an oscillating isolated system. The relaxation to equilibrium

In this contribution we show that a suitably defined nonequilibrium entropy of an N-body isolated system is not a constant of the motion in general and its variation is bounded, the bounds determined by the thermodynamic entropy, i.e., the equilibrium entropy. We define the nonequilibrium entropy as a convex functional of the set of n-particle reduced distribution functions (n=0,......., N) generalizing the Gibbs fine-grained entropy formula. Additionally, as a consequence of our microscopic analysis we find that this nonequilibrium entropy behaves as a free entropic oscillator. In the approach to the equilibrium regime we find relaxation equations of the Fokker-Planck type, particularly for the one-particle distribution function

Direct conversion of rheological compliance measurements into storage and loss moduli

We remove the need for Laplace/inverse-Laplace transformations of experimental data, by presenting a direct and straightforward mathematical procedure for obtaining frequency-dependent storage and loss moduli ($G'(\omega)$ and $G"(\omega)$ respectively), from time-dependent experimental measurements. The procedure is applicable to ordinary rheological creep (stress-step) measurements, as well as all microrheological techniques, whether they access a Brownian mean-square displacement, or a forced compliance. Data can be substituted directly into our simple formula, thus eliminating traditional fitting and smoothing procedures that disguise relevant experimental noise.Comment: 4 page

A depression before a bump in the highest energy cosmic ray spectrum

We re-examine the interaction of ultra high energy nuclei with the microwave background radiation. We find that the giant dipole resonance leaves a new signature in the differential energy spectrum of iron sources located around 3 Mpc: A depression before the bump which is followed by the expected cutoff.Comment: revisited version, 5 pages RevTex, 5 figure

Universality in edge-source diffusion dynamics

We show that in edge-source diffusion dynamics the integrated concentration N(t) has a universal dependence with a characteristic time-scale tau=(A/P)^2 pi/(4D), where D is the diffusion constant while A and P are the cross-sectional area and perimeter of the domain, respectively. For the short-time dynamics we find a universal square-root asymptotic dependence N(t)=N0 sqrt(t/tau) while in the long-time dynamics N(t) saturates exponentially at N0. The exponential saturation is a general feature while the associated coefficients are weakly geometry dependent.Comment: 4 pages including 4 figures. Minor changes. Accepted for PR

Slip boundary conditions for shear flow of polymer melts past atomically flat surfaces

Molecular dynamics simulations are carried out to investigate the dynamic behavior of the slip length in thin polymer films confined between atomically smooth thermal surfaces. For weak wall-fluid interactions, the shear rate dependence of the slip length acquires a distinct local minimum followed by a rapid growth at higher shear rates. With increasing fluid density, the position of the local minimum is shifted to lower shear rates. We found that the ratio of the shear viscosity to the slip length, which defines the friction coefficient at the liquid/solid interface, undergoes a transition from a nearly constant value to the power law decay as a function of the slip velocity. In a wide range of shear rates and fluid densities, the friction coefficient is determined by the product of the value of surface induced peak in the structure factor and the contact density of the first fluid layer near the solid wall.Comment: 27 pages, 11 figure

"How May I Help You?": Modeling Twitter Customer Service Conversations Using Fine-Grained Dialogue Acts

Given the increasing popularity of customer service dialogue on Twitter, analysis of conversation data is essential to understand trends in customer and agent behavior for the purpose of automating customer service interactions. In this work, we develop a novel taxonomy of fine-grained "dialogue acts" frequently observed in customer service, showcasing acts that are more suited to the domain than the more generic existing taxonomies. Using a sequential SVM-HMM model, we model conversation flow, predicting the dialogue act of a given turn in real-time. We characterize differences between customer and agent behavior in Twitter customer service conversations, and investigate the effect of testing our system on different customer service industries. Finally, we use a data-driven approach to predict important conversation outcomes: customer satisfaction, customer frustration, and overall problem resolution. We show that the type and location of certain dialogue acts in a conversation have a significant effect on the probability of desirable and undesirable outcomes, and present actionable rules based on our findings. The patterns and rules we derive can be used as guidelines for outcome-driven automated customer service platforms.Comment: 13 pages, 6 figures, IUI 201

History Memorized and Recalled upon Glass Transition

The memory effect upon glassification is studied in the glass to rubber transition of vulcanized rubber with the strain as a controlling parameter. A phenomenological model is proposed taking the history of the temperature and the strain into account, by which the experimental results are interpreted. The data and the model demonstrate that the glassy state memorizes the time-course of strain upon glassification, not as a single parameter but as the history itself. The data also show that the effect of irreversible deformation in the glassy state is beyond the scope of the present model. Authors' remark: The title of the paper in the accepted version is above. The title appeared in PRL is the one changed by a Senior Assistant Editor after acceptance of the paper. The recovery of the title was rejected in the correction process.Comment: 4 pages, 4 figure