Thermodiffusion in model nanofluids by molecular dynamics simulations

In this work, a new algorithm is proposed to compute single particle (infinite dilution) thermodiffusion using Non-Equilibrium Molecular Dynamics simulations through the estimation of the thermophoretic force that applies on a solute particle. This scheme is shown to provide consistent results for simple Lennard-Jones fluids and for model nanofluids (spherical non-metallic nanoparticles + Lennard-Jones fluid) where it appears that thermodiffusion amplitude, as well as thermal conductivity, decrease with nanoparticles concentration. Then, in nanofluids in the liquid state, by changing the nature of the nanoparticle (size, mass and internal stiffness) and of the solvent (quality and viscosity) various trends are exhibited. In all cases the single particle thermodiffusion is positive, i.e. the nanoparticle tends to migrate toward the cold area. The single particle thermal diffusion 2 coefficient is shown to be independent of the size of the nanoparticle (diameter of 0.8 to 4 nm), whereas it increases with the quality of the solvent and is inversely proportional to the viscosity of the fluid. In addition, this coefficient is shown to be independent of the mass of the nanoparticle and to increase with the stiffness of the nanoparticle internal bonds. Besides, for these configurations, the mass diffusion coefficient behavior appears to be consistent with a Stokes-Einstein like law

Droplet evaporation in one-component fluids: Dynamic van der Waals theory

In a one-component fluid, we investigate evaporation of a small axysymmetric liquid droplet in the partial wetting condition on a heated wall at $T\sim 0.9 T_c$. In the dynamic van der Waals theory (Phys. Rev. E {\bf 75}, 036304 (2007)), we take into account the latent heat transport from liquid to gas upon evaporation. Along the gas-liquid interface, the temperature is nearly equal to the equilibrium coexisting temperature away from the substrate, but it rises sharply to the wall temperature close to the substrate. On an isothermal substrate, evaporation takes place mostly on a narrow interface region near the contact line in a late stage, which is a characteristic feature in one-component fluids.Comment: 6 pages, 6 figure

Supersymmetry solution for finitely extensible dumbbell model

Exact relaxation times and eigenfunctions for a simple mechanical model of polymer dynamics are obtained using supersymmetry methods of quantum mechanics. The model includes the finite extensibility of the molecule and does not make use of the self-consistently averaging approximation. The finite extensibility reduces the relaxation times when compared to a linear force. The linear viscoelastic behaviour is obtained in the form of the ``generalized Maxwell model''. Using these results, a numerical integration scheme is proposed in the presence of a given flow kinematics.Comment: 5 pages, 2 figure

IGR J11215-5952: a hard X-ray transient displaying recurrent outbursts

The hard X-ray source IGRJ11215-5952 has been discovered with INTEGRAL during a short outburst in 2005 and proposed as a new member of the class of supergiant fast X-ray transients. We analysed INTEGRAL public observations of the source field in order to search for previous outbursts from this transient, not reported in literature.Our results are based on a systematic re-analysis of INTEGRAL archival observations, using the latest analysis software and instrument calibrations. We report the discovery of two previously unnoticed outbursts, spaced by intervals of ~330 days, that occurred in July 2003 and May 2004. The 5-100keV spectrum is well described by a cut-off power law, with a photon index of 0.5, and a cut-off energy ~15-20keV, typical of High Mass X-ray Binaries hosting a neutron star. A 5-100keV luminosity of 3E36 erg/s has been derived (assuming 6.2kpc, the distance of the likely optical counterpart). The 5-100keV spectral properties, the recurrent nature of the outbursts,together with the reduced error region containing the blue supergiant star HD306414,support the hypothesis that IGRJ11215-5952 is a member of the class of the Supergiant Fast X-ray Transients.Comment: 4 pages, 4 figures, accepted for publication in Astronomy and Astrophysics Letter

Dynamic van der Waals Theory of two-phase fluids in heat flow

We present a dynamic van der Waals theory. It is useful to study phase separation when the temperature varies in space. We show that if heat flow is applied to liquid suspending a gas droplet at zero gravity, a convective flow occurs such that the temperature gradient within the droplet nearly vanishes. As the heat flux is increased, the droplet becomes attached to the heated wall that is wetted by liquid in equilibrium. In one case corresponding to partial wetting by gas, an apparent contact angle can be defined. In the ther case with larger heat flux, the droplet completely wets the heated wall expelling liquid.Comment: 6pages, 8figure

Anomalous lateral diffusion in a viscous membrane surrounded by viscoelastic media

We investigate the lateral dynamics in a purely viscous lipid membrane surrounded by viscoelastic media such as polymeric solutions. We first obtain the generalized frequency-dependent mobility tensor and focus on the case when the solvent is sandwiched by hard walls. Due to the viscoelasticity of the solvent, the mean square displacement of a disk embedded in the membrane exhibits an anomalous diffusion. An useful relation which connects the mean square displacement and the solvent modulus is provided. We also calculate the cross-correlation of the particle displacements which can be applied for two-particle tracking experiments.Comment: 6 pages, 2 figure

X-ray, optical and infrared investigation of the candidate Supergiant Fast X-ray Transient IGR J18462-0223

We report on a broad-band X-ray study (0.5-60 keV) of the poorly known candidate Supergiant Fast X-ray Transient (SFXT) IGR J18462-0223, and on optical and near-infrared (NIR) followup observations of field objects. The out-of-outburst X-ray state has been investigated for the first time with archival INTEGRAL/IBIS, ASCA, Chandra and Swift/XRT observations. This allowed us to place stringent 3 sigma upper limits on the soft (0.5-10 keV) and hard (18-60 keV) X-ray emission of 2.9x10^-13 erg cm^-2 s^-1 and 8x10^-12 erg cm^-2 s^-1, respectively; the source was also detected during an intermediate soft X-ray state with flux equal to 1.6x10^-11 erg cm^-2 s^-1 (0.5-10 keV). In addition, we report on the INTEGRAL/IBIS discovery of three fast hard X-ray flares (18-60 keV) having a duration in the range 1-12 hours: the flaring behavior was also investigated in soft X-rays (3-10 keV) with archival INTEGRAL/JEM-X observations. The duty cycle (1.2%) and the dynamic ranges (> 1,380 and > 190 in the energy bands 0.5-10 keV and 18-60 keV, respectively) were measured for the first time. Archival UKIDSS JHK NIR data, together with our deep R-band imaging of the field, unveiled a single, very red object inside the intersection of the Swift/XRT and XMM-Newton error circles: this source has optical/NIR photometric properties compatible with a very heavily absorbed blue supergiant located at about 11 kpc, thus being a strong candidate counterpart for IGR J18462-0223. NIR spectroscopy is advised to confirm the association. Finally, a hint of a possible orbital period was found at about 2.13 days. If confirmed by further studies, this would make IGR J18462-0223 the SFXT with the shortest orbital period among the currently known systems.Comment: accepted for publication in A&A, 9 pages, 7 figures, 2 table

Gaussian approximation for finitely extensible bead-spring chains with hydrodynamic interaction

The Gaussian Approximation, proposed originally by Ottinger [J. Chem. Phys., 90 (1) : 463-473, 1989] to account for the influence of fluctuations in hydrodynamic interactions in Rouse chains, is adapted here to derive a new mean-field approximation for the FENE spring force. This "FENE-PG" force law approximately accounts for spring-force fluctuations, which are neglected in the widely used FENE-P approximation. The Gaussian Approximation for hydrodynamic interactions is combined with the FENE-P and FENE-PG spring force approximations to obtain approximate models for finitely-extensible bead-spring chains with hydrodynamic interactions. The closed set of ODE's governing the evolution of the second-moments of the configurational probability distribution in the approximate models are used to generate predictions of rheological properties in steady and unsteady shear and uniaxial extensional flows, which are found to be in good agreement with the exact results obtained with Brownian dynamics simulations. In particular, predictions of coil-stretch hysteresis are in quantitative agreement with simulations' results. Additional simplifying diagonalization-of-normal-modes assumptions are found to lead to considerable savings in computation time, without significant loss in accuracy.Comment: 26 pages, 17 figures, 2 tables, 75 numbered equations, 1 appendix with 10 numbered equations Submitted to J. Chem. Phys. on 6 February 200