Moisture-resistant baffle material for fuel tanks

Test results indicated superiority of certain polyether-based polyurethanes as protective coatings and suggested that baffle-materials with one of these coatings should have useful life approximately twice that of uncoated foams now in use

Thiophenyl ether disiloxanes and trisiloxanes useful as lubricant fluids

The characteristics of organosilicon compounds for lubrication under extreme conditions are discussed. The substances considered are thiophenyl ether disiloxanes and trisiloxanes. These substances have low pour points and a high degree of radiation resistance. Substitution of sulfur for the phenoxy group oxygen of either siloxane compounds has been found to result in a marked improvement in lubricity. The chemical formulas of the organic compounds are presented

Development of an optimized intumescent coating

Intumescent coatings for small diameter air launched missiles were studied. An aerodynamically smooth, moderately flexible coating, with excellent thermal efficiency was developed

Metallized polymeric foam material

Open-celled polyurethane foams can be coated uniformly with thin film of metal by vapor deposition of aluminum or by sensitization of foam followed by electroless deposition of nickel or copper. Foam can be further processed to increase thickness of metal overcoat to impart rigidity or to provide inert surface with only modest increase in weight

Development of improved sterilizable potting compounds and conformal coatings for space applications Annual summary report, 1 Jul. 1965 - 30 Jun. 1966

Sterilizable potting compounds and conformal coatings for space application

Phosphorylated epoxy adhesives

Fire retardant adhesives for aircraft interiors are developed. Monomers, epoxy synthesis, diamine synthesis, acrylic modified epoxy, and phosphorylated amine epoxy blends are examined

Development of improved sterilizable potting and encapsulating compounds for space applications Second annual summary report, 1 Jul. 1964 - 30 Jun. 1965

Siloxyurethane and epoxysilicone investigations in program to develop sterilizable electronic embedment materials and conformal coatings for applications in aerospace environmen

New hyperthermal thermosetting heterocyclic polymers

Polyimidazopyrrolone polymers, formed by the condensation of aromatic dianhydrides with aromatic tetraamines in various solvents, form moldings that resist degradation in air and retain great strength at 400 to 700 degrees F. The resins have good insulating properties, are easy to mold, and make good protective coatings

Development of phosphorylated adhesives

The synthesis of epoxy prepolymers containing phosphorus was carried out in such a manner as to provide adhesives containing at least 5 percent of this element. The purpose of this was to impart fire retardant properties to the adhesive. The two epoxy derivatives, bis(4-glycidyl-oxyphenyl)phenylphosphine oxide and bis(4-glycidyl-2-methoxyphenyl)phenylphosphonate, and a curing agent, bis(3-aminophenyl)methylphosphine oxide, were used in conjunction with one another and along with conventional epoxy resins and curing agents to bond Tedlar and Polyphenylethersulfone films to Kerimid-glass syntactic foam-filled honeycomb structures. Elevated temperatures are required to cure the epoxy resins with the phosphorus-contaning diamine; however, when Tedlar is being bonded, lower curing temperatures must be used to avoid shrinkage and the concomitant formation of surface defects. Thus, the phosphorus-containing aromatic amine curing agent cannot be used alone, although it is possible to use it in conjunction with an aliphatic amine which would allow lower cure temperatures to be used. The experimental epoxy resins have not provided adhesive bonds quite as strong as those provided by Epon 828 when compared in peel tests, but the differences are not very significant. It should be noted, if optimum properties are to be realized. In any case the fire retardant characteristics of the neat resin systems obtained are quite pronounced, since in most cases the self-extinguishing properties are evident almost instantly when specimens are removed from a flame

Far-infrared study of the Jahn-Teller distorted C60 monoanion in C60 tetraphenylphosphoniumiodide

We report high-resolution far-infrared transmission measurements on C(60)-tetraphenylphosphoniumiodide as a function of temperature. In the spectral region investigated (20-650 cm(-1)), we assign intramolecular modes of the C(60) monoanion and identify low-frequency combination modes. The well-known F(1u)(1) and F(1u)(2) modes are split into doublers at room temperature, indicating a D(5d) or D(3d) distorted ball. This result is consistent with a dynamic Jahn-Teller effect in the strong-coupling limit or with a static distortion stabilized by low-symmetry perturbations. The appearance of silent odd modes is in keeping with symmetry reduction of the hall, while activation of even modes is attributed to interband electron-phonon coupling and orientational disorder in the fulleride salt. Temperature dependences reveal a weak transition in the region 125-150 K in both C(60)(-) and counterion modes, indicating a bulk, rather than solely molecular, effect. Anomalous softening (with decreasing temperature) in several modes may correlate with the radial character of those vibrations. [S0163-1829(98)03245-7]