44 research outputs found

    A Geochemical Approach for Monitoring a CO 2

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    This paper presents the geochemical characterization of various gas end-members involved in a depleted gas field CO2 storage pilot (Rousse, France). In this pilot, CO2 is produced by oxycombustion from natural gas transformed into fuel gas at the Lacq plant, and transported in a pipeline 30 km away to the depleted gas reservoir of Rousse. Gases produced at Rousse before CO2 injection, the Lacq fuel gas and the CO2 resulting from the oxy-fuel combustion were sampled, together with gases from a –45 m monitoring well and from soils in the vicinity of the Rousse structure. For all samples, the bulk gas composition, the carbon isotopic compositions and the abundance and isotopic signatures of the noble gases were determined. The bulk gas compositions of the Rousse natural gas are comparable to the Lacq fuel gas with methane as the main compound with residual C2-C5 and CO2. Soil gases are typical mixtures of air with biogenic CO2 (up to 9-10%), while the monitoring well gases display typical air compositions with no excess CO2 The Rousse gas and the Lacq fuel gas have δ13CCH4 values of –41.0‰ and –43.0‰ respectively. The injected CO2 out of the oxycombustion chamber has a δ13CCO2 of –40.0‰, whereas δ13CCO2 value for soils samples is comprised between –15 and –25‰. The Rousse natural gas and the Lacq fuel gas are both characterized by a high He enrichment, and depletion in Ne, Ar and Kr compared to the air values. The oxyfuel combustion process provides a CO2 with the He enrichment of the Lacq fuel gas, and a Ne, Ar and Kr composition reflecting that of the oxygen produced at the Air Separation Unit (ASU). Indeed, Ne is depleted relatively to the air, while Kr is enriched up to tenfold, which results from the cryogenic separation of the air noble gases within the ASU. Soil samples noble gas compositions are equivalent to that of the air. In the light of these results, the compositions of the various end-members involved in this CO2 storage pilot suggest that noble gas compositions produced by oxyfuel process are sufficiently exotic compared to compositions found in nature (reservoir, aquifer and air) to be directly used as tracers of the injected CO2, and to detect and quantify leaks at soil and aquifer levels

    A Geochemical Approach for Monitoring a CO

    No full text
    This paper presents the geochemical characterization of various gas end-members involved in a depleted gas field CO2 storage pilot (Rousse, France). In this pilot, CO2 is produced by oxycombustion from natural gas transformed into fuel gas at the Lacq plant, and transported in a pipeline 30 km away to the depleted gas reservoir of Rousse. Gases produced at Rousse before CO2 injection, the Lacq fuel gas and the CO2 resulting from the oxy-fuel combustion were sampled, together with gases from a –45 m monitoring well and from soils in the vicinity of the Rousse structure. For all samples, the bulk gas composition, the carbon isotopic compositions and the abundance and isotopic signatures of the noble gases were determined. The bulk gas compositions of the Rousse natural gas are comparable to the Lacq fuel gas with methane as the main compound with residual C2-C5 and CO2. Soil gases are typical mixtures of air with biogenic CO2 (up to 9-10%), while the monitoring well gases display typical air compositions with no excess CO2 The Rousse gas and the Lacq fuel gas have δ13CCH4 values of –41.0‰ and –43.0‰ respectively. The injected CO2 out of the oxycombustion chamber has a δ13CCO2 of –40.0‰, whereas δ13CCO2 value for soils samples is comprised between –15 and –25‰. The Rousse natural gas and the Lacq fuel gas are both characterized by a high He enrichment, and depletion in Ne, Ar and Kr compared to the air values. The oxyfuel combustion process provides a CO2 with the He enrichment of the Lacq fuel gas, and a Ne, Ar and Kr composition reflecting that of the oxygen produced at the Air Separation Unit (ASU). Indeed, Ne is depleted relatively to the air, while Kr is enriched up to tenfold, which results from the cryogenic separation of the air noble gases within the ASU. Soil samples noble gas compositions are equivalent to that of the air. In the light of these results, the compositions of the various end-members involved in this CO2 storage pilot suggest that noble gas compositions produced by oxyfuel process are sufficiently exotic compared to compositions found in nature (reservoir, aquifer and air) to be directly used as tracers of the injected CO2, and to detect and quantify leaks at soil and aquifer levels

    On the Intention to Use an Online Learning Platform Feature

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    Our research project gives more insight into antecedents of students’ intention to use features of an online learning platform. This paper introduces the study year in the UTAUT (Unified Theory of Acceptance and Use of Technology) model. We also include three constructs that are mentioned in literature on student satisfaction with classic (offline) classes. Statistical tests show that new constructs are statistically significant antecedents of the intent of students to use the new feature. Two new constructs seem as important as the most important UTAUT variables performance expectancy and effort expectancy. The R² of our model is significantly higher than the R² that is achieved when the classic UTAUT is applied to our datase

    Comparative evaluation of the stability of two different dental implant designs and surgical protocols—a pilot study

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    Abstract Background The purpose of this study was to compare a parallel wall design implant to a tapered apex design implant when placed in the posterior maxilla using two different surgical protocols. Methods Twenty-seven patients (30 implants) were divided into three groups. All implants were 4 mm wide in diameter and 8 mm long. Group A received 10 tapered implants (OSPTX) (Astra Tech OsseoSpeed TX™) using the soft bone surgical protocol (TXSoft). Group B received 10 tapered implants (OSPTX) (AstraTech OsseoSpeedTX™) using the standard surgical protocol (TXStd). Group C received 10 parallel wall implants (OSP) (AstraTech OsseoSpeed™) using the standard surgical protocol (OStd). All implants were placed in the posterior maxilla in areas with a minimum of 8-mm crestal bone height. Resonance frequency measurements (implant stability quotient (ISQ)) and torque values were recorded to determine initial implant stability. All implants were uncovered 6 weeks after placement and restored with a functionally loaded resin provisional screw-retained crown. Resonance frequency measurements were recorded at the time of implant placement, at 6 weeks and 6 and 12 months. Twelve months after implant placement, the stability of the implants was recorded and the final restorations were placed using custom CAD/CAM fabricated abutments and cement-retained PFM DSIGN porcelain crowns. After implant restoration, bone levels were measured at 6 and 12 months with standardized radiographs. Results Radiographic mean bone loss was less than 0.5 mm in all groups, with no statistically significant differences between the groups. Implant survival rate at 1 year was 93.3%, with 2/30 implants failing to integrate prior to functional loading at 6 weeks. No statistically significant difference was found between ISQ measurements between the three groups at all time intervals measured. Strong positive correlations were found between overall bone loss at 6 months and insertion torque at time of placement. A very weak correlation was found between insertion torque and ISQ values at time of implant placement. Conclusions Survival and stability of OSPTX and OSP implants is comparable. Osteotomy preparation by either standard or soft bone surgical protocol presented no significant effect on implant survival and stability for the specific implant designs
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