345 research outputs found

    Projeto Rondon promovendo saúde para além da saúde: expandindo conceitos

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    Trabalho apresentado no II Congresso Nacional do PROJETO RONDON, realizado em Florianópolis, SC, no período de 23 a 25 de setembro de 2015 - Universidade Federal de Santa Catarina.O conceito de promoção de saúde se constitui em diferentes estratégias que buscam melhores condições e qualidade de vida para a população e tem como objetivo promover saúde, prevenindo doenças e evitando que as pessoas venham a se expor a fatores de riscos, para tanto programas de prevenção são elaborados a fim de alcançar tais objetivos, com base não somente em aspectos físicos e biológicos, mas principalmente em fatores sociais, ambientais e psicológicos. Nesse sentido, pensar saúde está para além de prevenir doenças, abarcando nesta perspectiva o acesso das pessoas a diferentes fontes de “saúde”, como a cultura, lazer, educação, direitos humanos e justiça, bem como recursos sanitários suficientes e de qualidade, considerando que este conjunto irá favorecer uma qualidade de vida digna. É de conhecimento público que devido à grande extensão territorial do Brasil algumas regiões acabam tendo menos acesso a tais recursos de saúde, como, por exemplo, o nordeste brasileiro, pois mesmo havendo altos investimentos nesta região, a mesma ainda carece de serviços que impulsionem a promoção de saúde. Neste sentido, o Projeto Rondon vai além de fornecer aos universitários extensionistas à experiência de aprimorar seus conhecimentos técnicos-profissionais e humanos; o Projeto também age como promotor de saúde em determinadas regiões do país. Sendo que nestas regiões nota-se constantemente o aperfeiçoamento dos dispositivos promotores de saúde, tornando-se perceptível a influência do Projeto Rondon no desenvolvimento sócio-histórico e cultural destas comunidades assistidas. Contudo, havendo a necessidade de se mensurar em termos qualitativos os efeitos das ações do Projeto Rondon dentro desse contexto, o objetivo do presente trabalho é discutir a atuação e os impactos da prática rondonista na cidade de Mogeiro, no Sertão da Paraíba / Brasil. Para isso serão utilizados como dados de análise materiais de oficinas e formações realizadas e embasamento bibliográfico quanto às diferentes maneiras de se promover saúde dentro de contextos escassos de recursos, bem como a ampliação dos mesmos. Por fim, vivenciar a prática extensionista de ambas as perspectivas, tanto da comunidade atendida quanto dos estudantes, são experiências idiossincráticas, que podem favorecer para expansão do conceito de saúde e as formas de promovê-la

    Poly[[1-(2-pyrid­yl)ethanone-κ2 N,O]di-μ2-thio­cyanato-κ2 N:S;κ2 S:N-cadmium(II)]

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    In the title compound, [Cd(NCS)2(C7H7NO)]n, the Cd2+ ion is six-coordinated by one N,O-bidentate 1-(2-pyridyletahanone ligand, two N-bonded thio­cyanate ions and two S-bonded thio­cyanate ions. In the resulting distorted CdOS2N3 octa­hedron, the N atoms adopt a fac arrangement. The bridging thio­cyanate ions lead to infinite sheets oriented parallel to (101) in the crystal structure

    Bis[1-(4-cyano­benz­yl)pyrazinium] bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)

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    The asymmetric unit of the title complex, (C12H10N3)2[Ni(C4N2S2)2], consists of one 1-(4-cyano­benz­yl)pyrazinium cation and one half of an [Ni(mnt)2]2− dianion (mnt2− is 1,2-dicyano­ethene-1,2-dithiol­ate). The Ni2+ ion is located on an inversion center and is coordinated by four S atoms from two mnt2− ligands, exhibiting a square-planar coordination geometry. The cation adopts a conformation where both the pyrazine ring and the benzene ring are twisted with respect to the C—C—N reference plane by 16.5 (2) and 69.8 (1)°, respectively

    FACÇÕES CRIMINOSAS: O CASO DO PCC - PRIMEIRO COMANDO DA CAPITAL

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    Este artigo elucida as teorias sobre o surgimento de uma das maiores organizações criminosas do Brasil: o Primeiro Comando da Capital – PCC. Criado na Casa de Custódia de Taubaté-SP por presos que prometiam lutar a favor de seus direitos e contra a opressão do Estado que tinha total descaso com a situação dos presídios do país: superpopulação carcerária, condições desumanas, castigos cruéis e outros fatores foram determinantes para que a revolta fosse instaurada. Ao longo dos 20 anos de sua história, o PCC construiu um império do crime, eliminando seus inimigos, aliando-se a outras facções e conquistando soldados que são fiéis aos mandamentos do “partido”, que praticamente monopoliza o crime, tendo em São Paulo, poucos concorrentes a altura

    Tetra­kis[μ-4-(diethyl­amino)benzoato-κ2 O:O′]bis­[(N,N-diethyl­nicotinamide-κN 1)zinc(II)]

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    In the centrosymmetric binuclear title complex, [Zn2(C11H14NO2)4(C10H14N2O)2], the two ZnII ions [Zn⋯Zn = 2.8874 (3) Å] are bridged by four 4-(diethyl­amino)benzoate (DEAB) ligands. The four nearest O atoms around each ZnII ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination being completed by the pyridine N atom of an N,N-diethyl­nicotinamide (DENA) ligand at a distance of 2.0484 (12) Å. The dihedral angle between the benzene ring and the carboxyl­ate group is 4.89 (6)° in one of the independent DEAB ligands and 7.13 (7)° in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.58 (5)°. The pyridine ring is oriented at dihedral angles of 31.17 (4) and 58.38 (4)° with respect to the two benzene rings. In the crystal, weak inter­molecular C—H⋯O inter­actions link the mol­ecules into a three-dimensional network. Two weak C—H⋯π inter­actions are also present. The two ethyl groups of one of the DEAB ligands are disordered over two orientations, with occupancy ratios of 0.798 (5):0.202 (5) and 0.890 (5):0.110 (5)

    Diaqua­bis(4-methyl­amino­benzoato-κO)bis­(nicotinamide-κN 1)cobalt(II)

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    The asymmetric unit of the title CoII complex, [Co(C8H8NO2)2(C6H6N2O)2(H2O)2], contains two half complex mol­ecules with similar structures. The CoII atoms are each located on an inversion center and each is coordinated by two 4-methyl­amino­benzoate (PMAB), two nicotinamide (NA) ligands and two water mol­ecules in a distorted octa­hedral coordination. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 3.0 (3) and 2.54 (19)°, while the pyridine and benzene rings are oriented at dihedral angles of 67.40 (8) and 66.25 (8)°. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure

    Poly[[diaqua­manganese(II)]-bis­(μ-4-fluoro­benzoato-κ2 O:O′)]

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    In the crystal structure of the title complex, [Mn(C7H4FO2)2(H2O)2]n, the MnII atom is located on an inversion centre. It is coordinated by two water mol­ecules in the apical directions and four 4-fluoro­benzoate (PFB) anions, bridging the symmetry related Mn atoms in the basal plane to form an infinite two-dimensional polymeric structure parallel to (100). The four O atoms of the PFB anions around the MnII atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two O atoms of the water mol­ecules. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 27.29 (16)°. The O—H⋯O hydrogen bonds further connect the manganese-carboxyl­ate units. π–π contacts between the benzene rings [centroid-centroid distance = 3.6894 (15) Å] further stabilize the crystal structure

    Tetra­kis(μ-4-methyl­benzoato-κ2 O:O′)bis­[(isonicotinamide-κN)copper(II)]

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    In the title centrosymmetric binuclear complex, [Cu2(C8H7O2)4(C6H6N2O)2], the Cu atoms [Cu⋯Cu = 2.6375 (6) Å] are bridged by four 4-methyl­benzoate (PMB) ligands. The four nearest O atoms around each CuII ion form a distorted square-planar arrangement, and the distorted square-pyramidal coordination is completed by the pyridine N atom of the isonicotinamide (INA) ligand. Each CuII ion is displaced by 0.2633 (1) Å from the plane of the four O atoms, with an average Cu—O distance of 1.974 (2) Å. The dihedral angles between carboxyl­ate groups and the adjacent benzene rings are 7.88 (19) and 9.68 (10)°, while the benzene rings are oriented at a dihedral angle of 85.90 (9)°. The pyridine ring is oriented at dihedral angles of 8.59 (7) and 83.89 (9)° with respect to the benzene rings. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the benzene rings and between the pyridine and benzene rings, [centroid–centroid distances = 3.563 (2) and 3.484 (2) Å, respectively] may further stabilize the crystal structure

    Diaqua­bis(4-methyl­benzoato-κO)bis­(nicotinamide-κN 1)manganese(II)

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    In the mononuclear title complex, [Mn(C8H7O2)2(C6H6N2O)2(H2O)2], the MnII ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methyl­benzoate anion, one nicotinamide (NA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the MnII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 9.01 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44 (5)°. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, and O—H⋯π and C—H⋯π inter­actions link the mol­ecules into a two-dimensional network parallel to (001)

    Diaqua­bis(N,N-diethyl­nicotinamide-κN 1)bis­(4-methyl­benzoato-κO)cobalt(II)

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    In the centrosymmetric mononuclear title complex, [Co(C8H7O2)2(C10H14N2O)2(H2O)2], the CoII ion is located on an inversion center. The asymmetric unit contains one 4-methyl­benzoate (PMB) anion, one N,N-diethyl­nicotinamide (DENA) ligand and one coordinated water mol­ecule. The four O atoms in the equatorial plane around the CoII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 3.73 (14)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.28 (6)°. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (001). The structure is further stabilized by π–π contacts between the pyridine rings [centroid–centroid distance = 3.544 (1) Å] and weak C—H⋯π inter­actions involving the benzene ring
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