Asymmetric Jaw Morphology in an Herbivorous Cichlid from Lake Malawi

Cichlid fish exhibit a high frequency of variation across species. This study focused on a particular asymmetry in the jaws of fish in the genus Tropheops. An asymmetry towards the left side was observed and then tested. Each side of the jaw was measured in a number of individuals from different Tropheops species. These measurements were then analyzed to see if the left side was indeed longer than the right. Statistical analysis was utilized to test the significance of sided differences. It was found that Tropheops species exhibit a left sided bias, some species having a significant bias, and others showing a leftward trend. Two other species, Labeotropheus fuelleborni and Cyanotilapia afra, were tested for comparison to see if this leftward trend is specific to Tropheops species. These species did not have a significant bias, but did show a trend toward a longer left side. It is predicted that the pronounced asymmetry in Tropheop jaw morphology is reflective of methods of food collection and diet

Phase transformations induced by spherical indentation in ion-implanted amorphous silicon

The deformation behavior of ion-implanted (unrelaxed) and annealed ion-implanted (relaxed) amorphous silicon(a-Si) under spherical indentation at room temperature has been investigated. It has been found that the mode of deformation depends critically on both the preparation of the amorphous film and the scale of the mechanical deformation.Ex situmeasurements, such as Raman microspectroscopy and cross-sectional transmission electron microscopy, as well as in situ electrical measurements reveal the occurrence of phase transformations in all relaxed a-Si films. The preferred deformation mode of unrelaxed a-Si is plastic flow, only under certain high load conditions can this state of a-Si be forced to transform. In situ electrical measurements have revealed more detail of the transformation process during both loading and unloading. We have used ELASTICA simulations to obtain estimates of the depth of the metallic phase as a function of load, and good agreement is found with the experiment. On unloading, a clear change in electrical conductivity is observed to correlate with a “pop-out” event on load versus penetration curves

Effect of oxygen concentration on nanoindentation-induced phase transformations in ion-implanted amorphous silicon

The effect of the local oxygen concentration in ion-implanted amorphous Si (a-Si) on nanoindentation-inducedphase transformations has been investigated. Implantation of oxygen into the a-Sifilms has been used to controllably introduce an approximately constant concentration of oxygen, ranging from ∼10¹⁸ to ∼10²¹ cm⁻³, over the depth range of the phase transformed zones. Nanoindentation was performed under conditions that ensure a phase transformed zone composed completely of Si-III/XII in the nominally oxygen-free a-Si. The effect of the local oxygen concentration has been investigated by analysis of the unloading curves, Raman microspectroscopy, and cross-sectional transmission electron microscopy (XTEM). The formation of Si-III/XII is suppressed with increasing oxygen concentration, favoring a greater volume of a-Si within the zones. The Raman microspectroscopy and XTEM verify that the volume of Si-III/XII decreases with increasing O concentration. With the smaller volumes of Si-III/XII, the pop-out normally observed on load versus penetration depth curves during unloading decreases in magnitude, becoming more kinklike and is barely discernable at high concentrations of oxygen. The probability of forming any high pressure phases is reduced from 1 to ∼0.1 for a concentration of 10²¹ cm⁻³. We suggest that the bonding of O with Si reduces the formation of Si-III/XII during unloading through a similar mechanism to that of oxygen-retarded solid phase crystallization of a-Si.This project is funded by the Australian Research Council and WRiota Pty Ltd

Experimental evidence of new tetragonal polymorphs of silicon formed through ultrafast laser-induced confined microexplosion

Ordinary materials can transform into novel phases at extraordinary high pressure and temperature. The recently developed method of ultrashort laser-induced confined microexplosions initiates a non-equilibrium disordered plasma state. Ultra-high quenching rates overcome kinetic barriers to the formation of new metastable phases, which are preserved in the surrounding pristine crystal for subsequent exploitation. Here we demonstrate that confined microexplosions in silicon produce several metastable end phases. Comparison with an ab initio random structure search reveals six energetically competitive potential phases, four tetragonal and two monoclinic structures. We show the presence of bt8 and st12, which have been predicted theoretically previously, but have not been observed in nature or in laboratory experiments. In addition, the presence of the as yet unidentified silicon phase, Si-VIII and two of our other predicted tetragonal phases are highly likely within laser-affected zones. These findings may pave the way for new materials with novel and exotic properties

Temperature dependent deformation mechanisms in pure amorphous silicon

High temperature nanoindentation has been performed on pure ion-implanted amorphous silicon (unrelaxed a-Si) and structurally relaxed a-Si to investigate the temperature dependence of mechanical deformation, including pressure-induced phase transformations. Along with the indentation load-depth curves, ex situ measurements such as Raman micro-spectroscopy and cross-sectional transmission electron microscopy analysis on the residual indents reveal the mode of deformation under the indenter. While unrelaxed a-Si deforms entirely via plastic flow up to 200°C, a clear transition in the mode of deformation is observed in relaxed a-Si with increasing temperature. Up to 100°C, pressure-induced phase transformation and the observation of either crystalline (r8/bc8) end phases or pressure-induced a-Si occurs in relaxed a-Si. However, with further increase of temperature, plastic flow rather than phase transformation is the dominant mode of deformation. It is believed that the elevated temperature and pressure together induce bond softening and "defect"formation in structurally relaxed a-Si, leading to the inhibition of phase transformation due to pressure-releasing plastic flow under the indenter

Mexican American adolescents’ perceptions of dating violence programs: Recommendations for effective program design and implementation

Although promising dating violence programs have emerged, little is known about their effectiveness for Mexican American youth, a vulnerable and understudied population. The purpose of this study was: (1) to offer culturally-grounded recommendations towards the development of effective Teen Dating Violence (TDV) programs and/or the modification of existing programs, and (2) to identify potential barriers to Mexican American youth’s participation in TDV programs. Using the perspectives of Mexican American youth (15 to 17 years old) and a phenomenological study design, focus groups (N = 14) were conducted that were homogeneous by gender and level of acculturation (low/bicultural/high). Youth provided recommendations for program design (i.e. Design it to explore between-group and within-group cultural variability, Design it to be broad in scope, and Keep it positive) and program implementation (i.e. Make the program fun and non-threatening, and Involve peers, couples, and individuals) within the context of acculturation. Adolescents’ suggestion of a program delivered in smaller groups that support sharing within peer relationships may stem from a desire for intimacy within close relationships – re-creating a sense of familismo. Teen dating violence programs best meets the needs of Mexican American adolescents by including programmatic components that are grounded in personalized cultural values

Black Feminist Citational Praxis and Disciplinary Belonging

What does a Black feminist citational practice look and feel like? This contribution to the #CiteBlackWomen colloquy focuses on two arguments: First, that Black feminist citational praxis is one of the major interventions Black women scholars contribute to the academy; and second, that anthropology’s neglect and erasure of Black feminist anthropologists relates to disciplinary (un)belonging. I explore how citation and “disciplinary belonging” influence hiring practices, doctoral training, intellectual genealogies, and what is valued as anthropological knowledge

Annealing of nanoindentation-induced high pressure crystalline phases created in crystalline and amorphous silicon

Thermally induced phase transformation of Si-III/Si-XII zones formed by nanoindentation has been studied during low temperature (200<T<300 °C) thermal annealing by Raman microspectroscopy and transmission electron microscopy. Two sizes of spherical indenter tips have been used to create substantially different volumes of phase transformed zones in both crystalline (c-Si) and amorphous silicon (a-Si) to study the zone size and starting matrix effects. The overall transformation is from Si-III/XII to poly- or nanocrystalline Si-I through intermediate phases of Si-XIII and Si-IV. Attempts have been made to determine the exact transformation pathways. Two scenarios are possible: either Si-XII first transforms to Si-III before transforming to Si-I through the intermediate phases or that Si-XII goes through the intermediate phases while Si-III transforms directly to Si-I. Finally, the phase transformations are slower in the larger indents and the starting matrix (crystalline or amorphous) has a substantial effect on the transformation kinetics of the small indents compared to the larger ones. We attribute this increased stability to both matrix effects (nucleation) and a difference in overall residual stress in indents made in a-Si compared to c-Si

Phase transformation pathways in amorphous germanium under indentation pressure

Nanoindentation-induced phase transformations have been studied in amorphous Ge thin films. These films initially tend to deform via plastic flow of the amorphous phase under load but at a critical pressure a sudden phase transformation occurs. This transformation, to a soft metallic (β-Sn-like)-Ge phase confined under the indenter, is signified by a "pop-in" event on loading. Following "pop-in," the indentation tests fall into two distinct types of behavior. In one case, the rate of deformation with increasing load after "pop-in" increases, and the observed end-phase following complete unloading is observed to be predominately diamond-cubic Ge. In the other case, the deformation rate (slope of the loading curve) remains the same as that before "pop-in," and the end phases following unloading are found to contain predominantly unstable r8 and more stable hexagonal Ge phases. The different transformation pathways for these two cases are shown to be related to the probability that the soft (β-Sn-like)-Ge phase volume, which suddenly forms at the transformation pressure, is either unconstrained by the indenter tip (the first case) or totally constrained under the indenter tip (in the latter case)

Phase transformations induced in relaxed amorphous silicon by indentation at room temperature

The deformation behavior of self-ion-implanted amorphous-Si (a-Si) has been studied using spherical nanoindentation in both relaxed (annealed) and unrelaxed (as-implanted) a-Si. Interestingly, phase transformations were clearly observed in the relaxed state, with the load–unload curves from these samples displaying characteristic discontinuities and cross-sectional transmission electron microscopy images indicating the presence of high-pressure crystalline phases Si-III and Si-XII following pressure release. Thus, an amorphous to crystalline phase transformation has been induced by indentation at room temperature. In contrast, no evidence of a phase transformation was observed in unrelaxed a-Si, which appeared to deform via plastic flow of the amorphous phase. Furthermore, in situ electrical measurements clearly indicate the presence of a metallic Si phase during loading of relaxed a-Si but no such behavior was observed for unrelaxed a-S