131 research outputs found
Drude model and Lifshitz formula
Since nearly 10 years, it is known that inserting the permittivity of the
Drude model into the Lifshitz formula for free energy causes a violation of the
third law of thermodynamics. In this paper we show that the standard Matsubara
formulation for free energy contains a contribution that is non-perturbative in
the relaxation parameter. We argue that the correct formula must have a
perturbative expansion and conclude that the standard Matsubara formulation
with the permittivity of the Drude model inserted is not correct. We trace the
non-perturbative contribution in the complex frequency plane, where it shows up
as a self-intersection or a bifurcation of the integration path.Comment: accepted for publication in EPJ
Thermal correction to the Casimir force, radiative heat transfer, and an experiment
The low-temperature asymptotic expressions for the Casimir interaction
between two real metals described by Leontovich surface impedance are obtained
in the framework of thermal quantum field theory. It is shown that the Casimir
entropy computed using the impedance of infrared optics vanishes in the limit
of zero temperature. By contrast, the Casimir entropy computed using the
impedance of the Drude model attains at zero temperature a positive value which
depends on the parameters of a system, i.e., the Nernst heat theorem is
violated. Thus, the impedance of infrared optics withstands the thermodynamic
test, whereas the impedance of the Drude model does not. We also perform a
phenomenological analysis of the thermal Casimir force and of the radiative
heat transfer through a vacuum gap between real metal plates. The
characterization of a metal by means of the Leontovich impedance of the Drude
model is shown to be inconsistent with experiment at separations of a few
hundred nanometers. A modification of the impedance of infrared optics is
suggested taking into account relaxation processes. The power of radiative heat
transfer predicted from this impedance is several times less than previous
predictions due to different contributions from the transverse electric
evanescent waves. The physical meaning of low frequencies in the Lifshitz
formula is discussed. It is concluded that new measurements of radiative heat
transfer are required to find out the adequate description of a metal in the
theory of electromagnetic fluctuations.Comment: 19 pages, 4 figures. svjour.cls is used, to appear in Eur. Phys. J.
Objective assessment of the cryoprotective effects of dimethylformamide for freezing goat semen
AbstractThe aim of this work was to assess the cryoprotective effects of dimethylformamide (DMF) for freezing goat semen, using an objective analysis by computer-assisted sperm analysis (CASA). Twenty-one ejaculates (seven per animal) were collected from three stud bucks with the aid of an artificial vagina and immediately evaluated for gross and microscopic characteristics. The semen was diluted in two steps with a Tris–egg yolk extender containing 6% glycerol or 6% DMF, frozen in 0.50-mL straws, and stored in liquid nitrogen. Samples were accessed for sperm morphology, sperm membrane structural and functional integrity, and by CASA, immediately after thawing. There were differences (P<0.05) between glycerol and DMF with regard to subjective progressive motility (23.9±2.2% vs. 16.6±2.0%), objective progressive motility (3.5±0.4% vs. 1.8±0.3%), linearity (53.9±1.6% vs. 48.1±1.4%) and amplitude of lateral head (2.3±0.1 vs. 2.9±0.1mm), which confirmed the efficiency of glycerol. In conclusion, dimethylformamide could be used as an alternative cryoprotectant for goat semen freezing. However it was showed that no benefits were derived by using dimethylformamide to replace glycerol at an equal 6% concentration
Chemical Functionalization of Cellulosic Materials — Main Reactions and Applications in the Contaminants Removal of Aqueous Medium
The cellulose is the most abundant biopolymer in the world and presents a higher chemical variability for presence of several hydroxyl groups. These hydroxyl groups allow surface modification of biomaterials, with insertion of several chemical groups which change cellulose characteristics. This natural biopolymer and its derivatives have been used a lot as adsorbent, from several contaminants of aqueous medium due to biocompatibility, chemical degradability, and variability. Therefore, this chapter has the objective to review the literature about several cellulose surfaces or cellulosic material (incorporation of carboxymethyl, phosphorus, carboxyl, amines, and sulfur), presenting the main characteristics of reactions and showing its adsorption in application of aqueous medium (metals, dyes, and drugs), locating the main interactions between biomaterial/contaminant
Exact Casimir-Polder potential between a particle and an ideal metal cylindrical shell and the proximity force approximation
We derive the exact Casimir-Polder potential for a polarizable microparticle
inside an ideal metal cylindrical shell using the Green function method. The
exact Casimir-Polder potential for a particle outside a shell, obtained
recently by using the Hamiltonian approach, is rederived and confirmed. The
exact quantum field theoretical result is compared with that obtained using the
proximity force approximation and a very good agreement is demonstrated at
separations below 0.1, where is the radius of the cylinder. The
developed methods are applicable in the theory of topological defects.Comment: 8 pages, 4 figures, Accepted for publication in Eur. Phys. J.
Violation of the Nernst heat theorem in the theory of thermal Casimir force between Drude metals
We give a rigorous analytical derivation of low-temperature behavior of the
Casimir entropy in the framework of the Lifshitz formula combined with the
Drude dielectric function. An earlier result that the Casimir entropy at zero
temperature is not equal to zero and depends on the parameters of the system is
confirmed, i.e. the third law of thermodynamics (the Nernst heat theorem) is
violated. We illustrate the resolution of this thermodynamical puzzle in the
context of the surface impedance approach by several calculations of the
thermal Casimir force and entropy for both real metals and dielectrics.
Different representations for the impedances, which are equivalent for real
photons, are discussed. Finally, we argue in favor of the Leontovich boundary
condition which leads to results for the thermal Casimir force that are
consistent with thermodynamics.Comment: 24 pages, 3 figures, accepted for publication in Phys. Rev.
Improved tests of extra-dimensional physics and thermal quantum field theory from new Casimir force measurements
We report new constraints on extra-dimensional models and other physics
beyond the Standard Model based on measurements of the Casimir force between
two dissimilar metals for separations in the range 0.2--1.2 m. The Casimir
force between an Au-coated sphere and a Cu-coated plate of a
microelectromechanical torsional oscillator was measured statically with an
absolute error of 0.3 pN. In addition, the Casimir pressure between two
parallel plates was determined dynamically with an absolute error of mPa. Within the limits of experimental and theoretical errors, the results
are in agreement with a theory that takes into account the finite conductivity
and roughness of the two metals. The level of agreement between experiment and
theory was then used to set limits on the predictions of extra-dimensional
physics and thermal quantum field theory. It is shown that two theoretical
approaches to the thermal Casimir force which predict effects linear in
temperture are ruled out by these experiments. Finally, constraints on Yukawa
corrections to Newton's law of gravity are strengthened by more than an order
of magnitude in the range 56 nm to 330 nm.Comment: Revtex 4, 35 pages, 14 figures in .gif format, accepted for
publication in Phys. Rev.
Van der Waals-Casimir-Polder interaction of an atom with a composite surface
We study the dispersion interaction of the van der Waals and Casimir-Polder
(vdW-CP) type between a neutral atom and the surface of a metal by allowing for
nonlocal electrodynamics, i.e. electron diffusion. We consider two models: (i)
bulk diffusion, and (ii) diffusion in a surface charge layer. In both cases the
transition to a semiconductor is continuous as a function of the conductivity,
unlike the case of a local model. The relevant parameter is the electric
screening length and depends on the carrier diffusion constant. We find that
for distances comparable to the screening length, vdW-CP data can distinguish
between bulk and surface diffusion, hence it can be a sensitive probe for
surface states.Comment: v2: expanded references, statements on current status in the field.
10 pages, 6 figure
Frequência de anticorpos e fatores de risco para a infecção pelo vírus da diarreia viral bovina em fêmeas bovinas leiteiras não vacinadas na região Amazônica Maranhense, Brasil
- …