109 research outputs found
Proton configurations in the hydrogen bonds of KH2PO4 as seen by resonant x-ray diffraction
KH2PO4 (KDP) belongs to the class of hydrogen-bonded ferroelectrics, whose
paraelectric to ferroelectric phase transition is driven by the ordering of the
protons in the hydrogen bonds. We demonstrate that forbidden reflections of
KDP, when measured at an x-ray absorption edge, are highly sensitive to the
asymmetry of proton configurations. The change of average symmetry caused by
the "freezing" of the protons during the phase transition is clearly evidenced.
In the paraelectric phase, we identify in the resonant spectra of the forbidden
reflections a contribution related to the transient proton configurations in
the hydrogen bonds, which violates the high average symmetry of the sites of
the resonant atoms. The analysis of the temperature dependence reveals a change
of relative probabilities of the different proton configurations. They follow
the Arrhenius law, and the activation energies of polar and Slater
configurations are 18.6 and 7.3 meV, respectively
Resonant x-ray scattering study of charge superstructures in layered L a2-x C axCo O4±d (0.4=x=0.7) and L a1.5 S r0.5Co O4 compounds
We propose a model for the Co charge disproportionation in La2-xCaxCoO4±d (0.4=x=0.7) and La1.5Sr0.5CoO4 layered cobaltites based on the photon energy, azimuthal angle, and polarization dependence of the scattered intensity of selected reflections in a resonant x-ray scattering experiment. Tetragonal superlattice (h/2, h/2, l)-type reflections were detected at room temperature for all the samples independently from the Ca (or Sr) doping rate in agreement with a checkerboard ordering of two different Co sites. The corresponding average charge disproportion is accounted for by a semiempirical model from which the imaginary part of the resonant atomic scattering factors of each of the two Co atoms is obtained resulting in about 0.5±0.1 electron. Moreover, no forbidden (h/4, h/4, l)-type reflections were observed at room temperature indicating the lack of any local anisotropy ordering in contrast with the behavior found in the related layered manganites. Finally, we found the pattern of small distortions (~0.05Å) around the two Co sites compatible with the resonant x-ray scattering results. The symmetry of this displacement pattern is consistent with the A2mm (or Ammm) orthorhombic structure of the ordered phase and the structural transition is accounted for by the condensation of two soft modes - X1+(B2u) and X1+(A1) - acting on the oxygen atoms
Direct observation of charge order in triangular metallic AgNiO2 by single-crystal resonant X-ray scattering
We report resonant X-ray scattering measurements on the orbitally-degenerate
triangular metallic antiferromagnet 2H-AgNiO2 to probe the spontaneous
transition to a triple-cell superstructure at temperatures below 365 K. We
observe a strong resonant enhancement of the supercell reflections through the
Ni K-edge. The empirically extracted K-edge shift between the
crystallographically-distinct Ni sites of 2.5(3) eV is much larger than the
value expected from the shift in final states, and implies a core-level shift
of ~1 eV, thus providing direct evidence for the onset of spontaneous honeycomb
charge order in the triangular Ni layers. We also provide band-structure
calculations that explain quantitatively the observed edge shifts in terms of
changes in the Ni electronic energy levels due to charge order and
hybridization with the surrounding oxygens.Comment: 5 pages, 4 figure
An X-ray study of the Dzyaloshinskii-Moriya interaction in the weak ferromagnet FeBO3
International audienceWe report on the axis, magnitude and direction of the Dzyaloshinskii-Moriya (DM) interaction in the weak ferromagnet FeBO3. The latter relies on the determination of the phase of the magnetic x-ray scattering amplitude. We outline a new technique based on interference with forbidden quadrupole resonant scattering to obtain this phase information
Phase transition of KDP observed by Resonant X-ray Diffraction at forbidden reflections
International audienceWe report observations of space-group-forbidden Bragg reflections in Potassium (KH2PO4), at the potassium K edge. We find clear evidence for a transition from one class of space-group-forbidden reflections, where scattering is ruled out by the electric dipole approximation, to a second class, in the ferroelectric phase, where scattering can proceed due to resonant anisotropy within the dipole approximation. The change of symmetry is clearly evidenced by the sudden change of intensity and energy spectrum of the forbidden reflections
Magnetically induced femtoscale strain modulations in HoMn2O5
International audienceX-ray scattering was used to investigate the magnetically induced ionic displacements in the low-temperature commensurate ferroelectric/antiferromagnetic phase of the multiferroic HoMn2O5. The structural modulation signal appearing at twice the magnetic wave vector km=(1/201/4) has been used, combined with symmetry analysis, to determine a model for the ionic displacements up to a precision of 10-3Ă…. The symmetry-breaking operations that are associated to the active irreducible representation have been experimentally determined from the analysis of the modulation modes. They reveal a lowering of symmetry to the polar point group m2m. Calculations based on the determined model show that the magnetic structure along the c direction is stabilized via nearest-neighbor and next-nearest-neighbor interactions through the rare-earth layer. We also show that by knowing both the magnetic and the magnetically induced strain waves patterns, it is possible to remove any phase ambiguity between the crystal and magnetic structures
Combined coherent x-ray micro-diffraction and local mechanical loading on copper nanocrystals
Coherent x-ray micro-diffraction and local mechanical loading can be combined
to investigate the mechanical deformation in crystalline nanostructures. Here
we present measurements of plastic deformation in a copper crystal of
sub-micron size obtained by loading the sample with an Atomic Force Microscopy
tip. The appearance of sharp features in the diffraction pattern, while
conserving its global shape, is attributed to crystal defects induced by the
tip
Interplay of inequivalent atomic positions in resonant x-ray diffraction of Fe3BO6
'Forbidden' Bragg reflections of iron orthoborate Fe3BO6 were studied
theoretically and experimentally in the vicinity of the iron K edge. Their
energy spectra are explained as resulting from the interference of x-rays
scattered from two inequivalent crystallographic sites occupied by iron ions.
This particular structure property gives rise to complex azimuthal dependences
of the reflection intensities in the pre-edge region as they result from the
interplay of site specific dipole-quadrupole and quadrupole-quadrupole resonant
scattering. Also evidenced is an isotropic character of the absorption
spectrum. Self-absorption correction to the diffraction data, as well as
possible contributions of thermal vibrations and magnetic order, are discussed.
Particular care is given to extracting clean spectra from the data, and it is
demonstrated that excellent results can be obtained even from measurements that
appear corrupted by several effects such as poor crystal quality and multiple
scattering.Comment: 12 page
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