103 research outputs found
Reactivity of polar organometallic compounds in unconventional reaction media : challenges and opportunities
Developing new green solvents in designing chemical products and processes or successfully employing the already existing ones is one of the key subjects in green chemistry and is especially important in organometallic chemistry, which is an interdisciplinary field. Can we advantageously also use unconventional reaction media in place of current harsh organic solvents for polar organometallic compounds? This microreview critically analyses the state of the art with regard to this topic and showcases recent developments and breakthroughs that are becoming new research directions in this field. Because metals cover a vast swath of the Periodic Table the content is organised into three sections discussing the reactivity of organometallic compounds of s-, p- and d-block elements in unconventional solvents
Catalytic Activity Dependency on Catalyst Components in Aerobic Copper-TEMPO Oxidation
ChemInform Abstract: Palladium-Catalyzed Cross-Coupling of Organozinc Bromides with Aryl Iodides in Perfluorinated Solvents.
ChemInform Abstract: A Selenium-Catalyzed Epoxidation in Perfluorinated Solvents with Hydrogen Peroxide.
ChemInform Abstract: Wacker Oxidation of Alkenes Using a Fluorous Biphasic System. A Mild Preparation of Polyfunctional Ketones.
ChemInform Abstract: Copper-Catalyzed Aerobic Oxidation of Alcohols under Fluorous Biphasic Conditions.
Cobalt(II) Perfluorooctane Sulfonate Catalyzed Highly Efficient Aerobic Oxidation of Alcohols in Fluorous Biphasic Systems
High Fluorine Content Bis(fluoro-Ponytailed) Bipyridine Palladium Complexes as Catalyst for Mizoroki-Heck Reactions under Fluorous Biphasic Catalysis Conditions
Copper(I) Complexes of Bipyridine and Terpyridine with Fluorous Tails and the Formation of Crystalline Materials with Fluorous Layers
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