1,472 research outputs found
Crystal nucleation mechanism in melts of short polymer chains under quiescent conditions and under shear flow
We present a molecular dynamics simulation study of crystal nucleation from
undercooled melts of n-alkanes, and we identify the molecular mechanism of
homogeneous crystal nucleation under quiescent conditions and under shear flow.
We compare results for n-eicosane(C20) and n-pentacontahectane(C150), i.e. one
system below the entanglement length and one above. Under quiescent conditions,
we observe that entanglement does not have an effect on the nucleation
mechanism. For both chain lengths, the chains first align and then straighten
locally. Then the local density increases and finally positional ordering sets
in. At low shear rates the nucleation mechanism is the same as under quiescent
conditions, while at high shear rates the chains align and straighten at the
same time. We report on the effects of shear rate and temperature on the
nucleation rates and estimate the critical shear rates, beyond which the
nucleation rates increase with the shear rate. We show that the viscosity of
the system is not affected by the crystalline nuclei.Comment: 9 page
Mutual information for examining correlations in DNA
This paper examines two methods for finding whether long-range correlations
exist in DNA: a fractal measure and a mutual information technique. We evaluate
the performance and implications of these methods in detail. In particular we
explore their use comparing DNA sequences from a variety of sources. Using
software for performing in silico mutations, we also consider evolutionary
events leading to long range correlations and analyse these correlations using
the techniques presented. Comparisons are made between these virtual sequences,
randomly generated sequences, and real sequences. We also explore correlations
in chromosomes from different species.Comment: 8 pages, 3 figure
Non-Unitary Neutrino Propagation From Neutrino Decay
Neutrino propagation in space-time is not constrained to be unitary if very
light states - lighter than the active neutrinos - exist into which neutrinos
may decay. If this is the case, neutrino flavor-change is governed by a handful
of extra mixing and "oscillation" parameters, including new sources of
CP-invariance violation. We compute the transition probabilities in the two-
and three-flavor scenarios and discuss the different phenomenological
consequences of the new physics. These are qualitatively different from other
sources of unitarity violation discussed in the literature.Comment: 8 pages, no figure
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