Oxygen surface exchange kinetics of erbia-stabilized bismuth oxide

The surface oxygen exchange kinetics of bismuth\ud oxide stabilized with 25 mol% erbia (BE25) has been studied\ud in the temperature and pO2 ranges 773–1,023 K and 0.1–\ud 0.95 atm, respectively, using pulse-response 18O–16O isotope\ud exchange measurements. The results indicate that BE25\ud exhibits a comparatively high exchange rate, which is rate\ud determined by the dissociative adsorption of oxygen. Defect\ud chemical considerations and the observed pO2\ud 1=2 dependence\ud of the rate of dissociative oxygen adsorption suggest\ud electron transfer to intermediate superoxide ions as the rate\ud determining step in surface oxygen exchange on BE2

Changing paradigms of renal replacement therapy in chronic kidney disease patients: ultrapure dialysis fluid and high-efficiency hemodiafiltration for all?

Ultrapurity of dialysis fluid is important for the biocompatibility of renal replacement therapy systems. Penne and collaborators have assessed the microbiological quality of water and dialysis fluid in dialysis facilities. No side effects were noted in 97 patients who received 11,258 online hemodiafiltration sessions. This study confirms that ultrapure water and dialysis fluid may be easily produced and used for online hemodiafiltration

The Vacuum Chamber of the GANIL SSC

http://accelconf.web.cern.ch/AccelConf/c78/papers/a-14.pdfInternational audienc

Infinite N phase transitions in continuum Wilson loop operators

We define smoothed Wilson loop operators on a four dimensional lattice and check numerically that they have a finite and nontrivial continuum limit. The continuum operators maintain their character as unitary matrices and undergo a phase transition at infinite N reflected by the eigenvalue distribution closing a gap in its spectrum when the defining smooth loop is dilated from a small size to a large one. If this large N phase transition belongs to a solvable universality class one might be able to calculate analytically the string tension in terms of the perturbative Lambda-parameter. This would be achieved by matching instanton results for small loops to the relevant large-N-universal function which, in turn, would be matched for large loops to an effective string theory. Similarities between our findings and known analytical results in two dimensional space-time indicate that the phase transitions we found only affect the eigenvalue distribution, but the traces of finite powers of the Wilson loop operators stay smooth under scaling.Comment: 31 pages, 9 figures, typos and references corrected, minor clarifications adde

Science-based decision support for formulating crop fertilizer recommendations in sub-Saharan Africa

Open Access Article; Published online: 31 Jan 2020In sub-Saharan Africa, there is considerable spatial and temporal variability in relations between nutrient application and crop yield, due to varying inherent soil nutrients supply, soil moisture, crop management and germplasm. This variability affects fertilizer use efficiency and crop productivity. Therefore, development of decision systems that support formulation and delivery of site-specific fertilizer recommendations is important for increased crop yield and environmental protection. Nutrient Expert (NE) is a computer-based decision support system, which enables extension advisers to generate field- or area-specific fertilizer recommendations based on yield response to fertilizer and nutrient use efficiency. We calibrated NE for major maize agroecological zones in Nigeria, Ethiopia and Tanzania, with data generated from 735 on-farm nutrient omission trials conducted between 2015 and 2017. Between 2016 and 2018, 368 NE performance trials were conducted across the three countries in which recommendations generated with NE were evaluated relative to soil-test based recommendations, the current blanket fertilizer recommendations and a control with no fertilizer applied. Although maize yield response to fertilizer differed with geographic location; on average, maize yield response to nitrogen (N), phosphorus (P) and potassium (K) were respectively 2.4, 1.6 and 0.2 t ha−1 in Nigeria, 2.3, 0.9 and 0.2 t ha−1 in Ethiopia, and 1.5, 0.8 and 0.2 t ha−1 in Tanzania. Secondary and micronutrients increased maize yield only in specific areas in each country. Agronomic use efficiencies of N were 18, 22 and 13 kg grain kg−1 N, on average, in Nigeria, Ethiopia and Tanzania, respectively. In Nigeria, NE recommended lower amounts of P by 9 and 11 kg ha−1 and K by 24 and 38 kg ha−1 than soil-test based and regional fertilizer recommendations, respectively. Yet maize yield (4 t ha−1) was similar among the three methods. Agronomic use efficiencies of P and K (300 and 250 kg kg−1, respectively) were higher with NE than with the blanket recommendation (150 and 70 kg kg−1). In Ethiopia, NE and soil-test based respectively recommended lower amounts of P by 8 and 19 kg ha−1 than the blanket recommendations, but maize yield (6 t ha−1) was similar among the three methods. Overall, fertilizer recommendations generated with NE maintained high maize yield, but at a lower fertilizer input cost than conventional methods. NE was effective as a simple and cost-effective decision support tool for fine-tuning fertilizer recommendations to farm-specific conditions and offers an alternative to soil testing, which is hardly available to most smallholder farmers