Quantitative ultraviolet measurements on wetted thin-layer chromatography plates using a charge-coupled device camera

This paper presents the first study of the UV imaging of spots on thin-layer chromatographic plates whilst still wet with solvent. Imaging of spots of benzophenone during and after development was carried out using a charge-coupled device camera. Limits of detection were found to be 5 ng on a wetted plate and 3 ng for a dry plate and the relationship between peak area and sample loading was found to be linear in the low nanograrn range over an order of magnitude for both wet and dry modes with r(2) values > 0.99. It was found that UV measurements on wet glass-backed plates suffer from low sensitivity; however, the use of aluminium-backed plates gave increased sensitivity. The apparent absorption coefficient (epsilon(app)) of 10AU m(2) g(-1) at 254 nm is consistent with reflection of the light from the aluminium surface with a double pass through the sorbent layer, and suggests that use of aluminium-backed plates should enable monitoring of separations by UV absorbance during TLC development. (c) 2008 Elsevier B.V. All rights reserved

Middle-Upper Ordovician conodonts from the Ffairfach and Golden Grove groups in South Wales, United Kingdom

The conodont fauna of the reference succession of the regional British Llandeilian Stage of the Llanvirn Series was first described in a classical study by Rhodes more than 65 years ago using single element (form) taxonomy. Although several subsequent authors have recorded a substantial number of conodont taxa from the Llandeilo area, the present study is the first to present a modern taxonomic review of these late Darriwilian-early Sandbian faunas that include approximately 20 multielement species. Most prominent are representatives of Amorphognathus, Baltoniodus, Eoplacognathus, and Plectodina. The study faunas have their own biogeographical character. The distinctive genera Complexodus, Protopanderodus, and Pygodus, which are common in coeval Baltoscandic faunas, are not present, but the occurrence of Amorphognathus, Baltoniodus, and Eoplacognathus provides a link to age equivalent Baltoscandic faunas. The presence of abundant specimens of Plectodina and less common representatives of Erismodus and Icriodella are reminiscent of North American Midcontinent faunas. This type of faunal assemblage is in some respects similar to those of the early Caradoc Series of the Welsh Borderland. Biostratigraphically diagnostic species indicate that the Llandeilo study succession ranges from the Eoplacognathus lindstroemi Subzone of the Pygodus serra Zone to the Baltoniodus variabilis Subzone of the Amorphognathus tvaerensis Zone

Microscopic calculation of 6Li elastic and transition form factors

Variational Monte Carlo wave functions, obtained from a realistic Hamiltonian consisting of the Argonne v18 two-nucleon and Urbana-IX three-nucleon interactions, are used to calculate the 6Li ground-state longitudinal and transverse form factors as well as transition form factors to the first four excited states. The charge and current operators include one- and two-body components, leading terms of which are constructed consistently with the two-nucleon interaction. The calculated form factors and radiative widths are in good agreement with available experimental data.Comment: 9 pages, 2 figures, REVTeX, submitted to Physical Review Letters, with updated introduction and reference

Kinetic decoupling of neutralino dark matter

After neutralinos cease annihilating in the early Universe, they may still scatter elastically from other particles in the primordial plasma. At some point in time, however, they will eventually stop scattering. We calculate the cross sections for neutralino elastic scattering from standard-model particles to determine the time at which this kinetic decoupling occurs. We show that kinetic decoupling occurs above a temperature $T\sim$ MeV. Thereafter, neutralinos act as collisionless cold dark matter.Comment: Replaced with revised version, new references adde

Pilin expression and processing in pilus mutants of Neisseria gonorrhoeae : critical role of Gly -1 in assembly

Spontaneous mutants of Neisseria gonorrheae failing to express pili or having diminished levels of piliation were studied with regard to pilin expression. All mutants displayed altered pilin processing detectable as the release of soluble, truncated pilin molecules (S-pilin). Of particular interest was the finding, in one mutant, that substitution of serine for glycine at position -1 of propilin, a highly conserved residue among N -metPhe and related pilins, abolished pilus expression but not S-pilin release. The degree of S-pilin processing and the levels of membrane-associated pilin varied among the different classes of mutants, suggesting that each was blocked at a distinct step of pilus biogenesis. The data support a model in which increased S-pilin processing is a result of a decreased rate of pilus polymerization.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/74951/1/j.1365-2958.1991.tb02108.x.pd

Can Heavy WIMPs Be Captured by the Earth?

If weakly interacting massive particles (WIMPs) in bound solar orbits are systematically driven into the Sun by solar-system resonances (as Farinella et al. have shown is the case for many Earth-crossing asteroids), then the capture of high-mass WIMPs by the Earth would be affected dramatically because high-mass WIMPs are captured primarily from bound orbits. WIMP capture would be eliminated for M_x>630 GeV and would be highly suppressed for M_x>~150 GeV. Annihilation of captured WIMPs and anti-WIMPs is expected to give rise to neutrinos coming from the Earth's center. The absence of such a neutrino signal has been used to place limits on WIMP parameters. At present, one does not know if typical WIMP orbits are in fact affected by these resonances. Until this question is investigated and resolved, one must (conservatively) assume that they are. Hence, limits on high-mass WIMP parameters are significantly weaker than previously believed.Comment: 8 pages + 1 figure. Submitted to Ap

The Plausibility of a String Quartet Performance in Virtual Reality

We describe an experiment that explores the contribution of auditory and other features to the illusion of plausibility in a virtual environment that depicts the performance of a string quartet. ‘Plausibility’ refers to the component of presence that is the illusion that the perceived events in the virtual environment are really happening. The features studied were: Gaze (the musicians ignored the participant, the musicians sometimes looked towards and followed the participant’s movements), Sound Spatialization (Mono, Stereo, Spatial), Auralization (no sound reflections, reflections corresponding to a room larger than the one perceived, reflections that exactly matched the virtual room), and Environment (no sound from outside of the room, birdsong and wind corresponding to the outside scene). We adopted the methodology based on color matching theory, where 20 participants were first able to assess their feeling of plausibility in the environment with each of the four features at their highest setting. Then five times participants started from a low setting on all features and were able to make transitions from one system configuration to another until they matched their original feeling of plausibility. From these transitions a Markov transition matrix was constructed, and also probabilities of a match conditional on feature configuration. The results show that Environment and Gaze were individually the most important factors influencing the level of plausibility. The highest probability transitions were to improve Environment and Gaze, and then Auralization and Spatialization. We present this work as both a contribution to the methodology of assessing presence without questionnaires, and showing how various aspects of a musical performance can influence plausibility

Cosmic antiprotons as a probe for supersymmetric dark matter?

The flux of cosmic ray antiprotons from neutralino annihilations in the galactic halo is computed for a large sample of models in the MSSM (the Minimal Supersymmetric extension of the Standard Model). We also revisit the problem of estimating the background of low-energy cosmic ray induced secondary antiprotons, taking into account their subsequent interactions (and energy loss) and the presence of nuclei in the interstellar matter. We consider a two-zone diffusion model, with and without a galactic wind. We find that, given the uncertainties in the background predictions, there is no need for a primary (exotic) component to explain present data. However, allowing for a signal by playing with the uncertainties in the background estimate, we discuss the characteristic features of the supersymmetric models which give a satisfactory description of the data. We point out that in some cases the optimal kinetic energy to search for a signal from supersymmetric dark matter is above several GeV, rather than the traditional sub-GeV region. The large astrophysical uncertainties involved do not, one the other hand, allow the exclusion of any of the MSSM models we consider, on the basis of data. We present besides numerical results also convenient parameterizations of the antiproton yields of all `basic' two-body final states. We also give examples of the yield and differential energy spectrum for a set of supersymmetric models with high rates. We also remark that it is difficult to put a limit on the antiproton lifetime from present measurements, since the injection of antiprotons from neutralino annihilation can compensate the loss from decay.Comment: 22 pages, 11 figures, uses emulateapj.st