The size and polydispersity of silica nanoparticles under simulated hot spring conditions

The nucleation and growth of silica nanoparticles in supersaturated geothermal waters was simulated using a flow-through geothermal simulator system. The effect of silica concentration ([SiO2]), ionic strength (IS), temperature (T) and organic additives on the size and polydispersity of the forming silica nanoparticles was quantified. A decrease in temperature (58 to 33°C) and the addition of glucose restricted particle growth to sizes <20 nm, while varying [SiO2] or ISdid not affect the size (30-35 nm) and polydispersity (±9 nm) observed at 58°C. Conversely, the addition of xanthan gum induced the development of thin films that enhanced silica aggregation

Evaluation and test of xenon lamps, phase 4, volume 1 Final report

Anode configurations for xenon lamp

The metagenomics of biosilicification: causes and effects

In order to determine the links between geochemical parameters controlling the formation of silica sinter in hot springs and their associated microbial diversity, a detailed characterisation of the waters and of in situ-grown silica sinters was combined with molecular phylogenetic analyses of the bacterial communities in Icelandic geothermal environments. At all but one site, the microorganisms clearly affected, and in part controlled, the formation of the macroscopic textures and structures of silica sinter edifices. In addition, the class and genera level phylogenetic diversity and distribution appeared to be closely linked to variations in temperature, salinity and pH regimes

Controlled biomineralization of magnetite (Fe₃O₄) by <i>Magnetospirillum gryphiswaldense</i>

Results from a study of the chemical composition and micro-structural characteristics of bacterial magnetosomes extracted from the magnetotactic bacterial strain Magnetospirillum gryphiswaldense are presented here. Using high-resolution transmission electron microscopy combined with selected-area electron diffraction and energy dispersive X-ray microanalysis, biogenic magnetite particles isolated from mature cultures were analysed for variations in crystallinity and particle size, as well as chain character and length. The analysed crystals showed a narrow size range (∼14-67 nm) with an average diameter of 46±6.8 nm, cuboctahedral morphologies and typical Gamma type crystal size distributions. The magnetite particles exhibited a high chemical purity (exclusively Fe3O4) and the majority fall within the single-magnetic-domain range

Ice sheets as a significant source of highly reactive nanoparticulate iron to the oceans

The Greenland and Antarctic Ice Sheets cover ~\n10% of global land surface, but are rarely considered as active components of the global iron cycle. The ocean waters around both ice sheets harbour highly productive coastal ecosystems, many of which are iron limited. Measurements of iron concentrations in subglacial runoff from a large Greenland Ice Sheet catchment reveal the potential for globally significant export of labile iron fractions to the near-coastal euphotic zone. We estimate that the flux of bioavailable iron associated with glacial runoff is 0.40–2.54?Tg per year in Greenland and 0.06–0.17?Tg per year in Antarctica. Iron fluxes are dominated by a highly reactive and potentially bioavailable nanoparticulate suspended sediment fraction, similar to that identified in Antarctic icebergs. Estimates of labile iron fluxes in meltwater are comparable with aeolian dust fluxes to the oceans surrounding Greenland and Antarctica, and are similarly expected to increase in a warming climate with enhanced melting

Goose Marketing and Production: Characteristics and Problems of South Dakota\u27s Goose Industry

The objectives of this study were to survey South Dakota goose producers and processors to determine: (1) production and nutritional practices and problems associated with goose raising, (2) marketing patterns and problems encountered by producers, (3) future production intentions, and (4) production cost and revenue data

A comparison of spectral mixture analysis an NDVI for ascertaining ecological variables

In this study, we compare the performance of spectral mixture analysis to the Normalized Difference Vegetation Index (NDVI) in detecting change in a grassland across topographically-induced nutrient gradients and different management schemes. The Konza Prairie Research Natural Area, Kansas, is a relatively homogeneous tallgrass prairie in which change in vegetation productivity occurs with respect to topographic positions in each watershed. The area is the site of long-term studies of the influence of fire and grazing on tallgrass production and was the site of the First ISLSCP (International Satellite Land Surface Climatology Project) Field Experiment (FIFE) from 1987 to 1989. Vegetation indices such as NDVI are commonly used with imagery collected in few (less than 10) spectral bands. However, the use of only two bands (e.g. NDVI) does not adequately account for the complex of signals making up most surface reflectance. Influences from background spectral variation and spatial heterogeneity may confound the direct relationship with biological or biophysical variables. High dimensional multispectral data allows for the application position of techniques such as derivative analysis and spectral curve fitting, thereby increasing the probability of successfully modeling the reflectance from mixed surfaces. The higher number of bands permits unmixing of a greater number of surface components, separating the vegetation signal for further analyses relevant to biological variables

Identification of black sturgeon caviar pigment as eumelanin

Reported herein is the purification of the pigment of black sturgeon caviar and its unambiguous identification as a typical eumelanin by means of chemical degradation coupled with electron paramagnetic resonance (EPR) evidence. HPLC and LC-MS analysis of oxidative degradation mixtures revealed the formation of pyrrole-2,3,5-tricarboxylic acid (PTCA), a specific marker of eumelanin pigments, in yields compatible with a 6.5% w/w pigment content. EPR spectral features and parameters were in close agreement with those reported for a typical natural eumelanin such as Sepia melanin from squid ink. The identification for the first time of eumelanin in a fish roe is expected to provide a novel molecular basis for the valorization of black caviar and production wastes thereof in food chemistry and diet

Forging Partnerships, Experiential Learning, and Community Impact: Capacity Building Matters

Capacity building can be an important step in working to help more Native American engineering students to earn degrees. Funding agencies often look first at numbers of students who succeed at matriculation. We make the case that a broader view of success in the early years of program development with tribal college pre-engineering partner schools may include capacity building. If continued funding of such initiatives is withheld because of quantitative assessment alone, coalitions with tribal colleges may not reach their true potential because capacity building is often crucial, and it takes time. In this paper, one co-author interviewed the other three co-authors, using a predetermined questionnaire. Thus, while all the authors are the researchers, three of the co-authors are the research subjects. All are PhD engineers and scientists. In the resulting essays, the interviewees expressed their opinions about capacity building in their roles in an NSF-sponsored pre-engineering alliance between two mainline universities and a tribally controlled college. Those interviewed describe their unique qualifications to assess capacity building in this instance. From the perspective of one of the mainline universities in the alliance, they address categories of capacity building at the following levels: the tribal college; the two participating mainline universities; the reservation hosting the summer camp; student and faculty participants; tribal, State, and Federal agencies; and STEM disciplines in general. We present common themes in all three essays that reportedly encouraged capacity building, including: (1) coalition-building, (2) engaging in experiential learning, and (3) emphasizing improving the quality of life on Pine Ridge Reservation. We present secondary themes and non-consensus opinions as additional support for the merits of qualitative assessment