Fate and occurrence of alkylphenolic compounds in sewage sludges determined by liquid chromatography tandem mass spectrometry

This is the author's accepted manuscript. The final published article is available from the link below. Copyright @ 2009 Taylor & Francis.An analytical method has been developed and applied to determine the concentrations of the nonionic alkylphenol polyethoxylate surfactants and their metabolites, alkylphenoxy carboxylates and alkyphenols, in sewage sludges. The compounds were extracted with methanol/acetone (1:1 v/v) from sludge, and concentrated extracts were cleaned by silica solid‐phase extraction prior to determination by liquid chromatography tandem mass spectrometry. The recoveries, determined by spiking sewage sludge at two concentrations, ranged from 51% to 89% with method detection limits from 6 µg kg−1 to 60 µg kg−1. The methodology was subsequently applied to sludge samples obtained from a carbonaceous activated sludge plant, a nitrifying/denitrifying activated sludge plant and a nitrifying/denitrifying activated sludge plant with phosphorus removal. Concentrations of nonylphenolic compounds were two to three times higher than their octyl analogues. Long‐chain nonylphenol polyethoxylates (NP3–12EO) ranged from 16 µg kg−1 to 11754 µg kg−1. The estrogenic metabolite nonylphenol was present at concentrations ranging from 33 µg kg−1 to 6696 µg kg−1.Public Utilities Board of Singapore, Thames Water and Yorkshire Water

Entanglement of photons

It is argued that the title of this paper represents a misconception. Contrary to widespread beliefs it is electromagnetic field modes that are ``systems'' and can be entangled, not photons. The amount of entanglement in a given state is shown to depend on redefinitions of the modes; we calculate the minimum and maximum over all such redefinitions for several examples.Comment: 5 pages ReVTe

Dynamics of Entanglement in One-Dimensional Spin Systems

We study the dynamics of quantum correlations in a class of exactly solvable Ising-type models. We analyze in particular the time evolution of initial Bell states created in a fully polarized background and on the ground state. We find that the pairwise entanglement propagates with a velocity proportional to the reduced interaction for all the four Bell states. Singlet-like states are favored during the propagation, in the sense that triplet-like states change their character during the propagation under certain circumstances. Characteristic for the anisotropic models is the instantaneous creation of pairwise entanglement from a fully polarized state; furthermore, the propagation of pairwise entanglement is suppressed in favor of a creation of different types of entanglement. The ``entanglement wave'' evolving from a Bell state on the ground state turns out to be very localized in space-time. Further support to a recently formulated conjecture on entanglement sharing is given.Comment: 25 pages, 21 figures; revte

A Thermal Graviton Background from Extra Dimensions

Inflationary cosmology predicts a low-amplitude graviton background across a wide range of frequencies. This Letter shows that if one or more extra dimensions exist, the graviton background may have a thermal spectrum instead, dependent on the fundamental scale of the extra dimensions. The energy density is shown to be significant enough that it can affect nucleosynthesis in a substantial way. The possibility of direct detection of a thermal graviton background using the 21-cm hydrogen line is discussed. Alternative explanations for the creation of a thermal graviton background are also examined.Comment: 5 pages, 1 figure, requires autart.cls, to appear in Phys. Lett. B, 1 reference adde

Spin-gravity coupling and gravity-induced quantum phases

External gravitational fields induce phase factors in the wave functions of particles. The phases are exact to first order in the background gravitational field, are manifestly covariant and gauge invariant and provide a useful tool for the study of spin-gravity coupling and of the optics of particles in gravitational or inertial fields. We discuss the role that spin-gravity coupling plays in particular problems.Comment: 18 pages, 1 figur

Emotion, Meaning, and Appraisal Theory

According to psychological emotion theories referred to as appraisal theory, emotions are caused by appraisals (evaluative judgments). Borrowing a term from Jan Smedslund, it is the contention of this article that psychological appraisal theory is “pseudoempirical” (i.e., misleadingly or incorrectly empirical). In the article I outline what makes some scientific psychology “pseudoempirical,” distinguish my view on this from Jan Smedslund’s, and then go on to show why paying heed to the ordinary meanings of emotion terms is relevant to psychology, and how appraisal theory is methodologically off the mark by employing experiments, questionnaires, and the like, to investigate what follows from the ordinary meanings of words. The overarching argument of the article is that the scientific research program of appraisal theory is fundamentally misguided and that a more philosophical approach is needed to address the kinds of questions it seeks to answer

Level models of continuing professional development evaluation: a grounded review and critique

Continuing professional development (CPD) evaluation in education has been heavily influenced by ‘level models’, deriving from the work of Kirkpatrick and Guskey in particular, which attempt to trace the processes through which CPD interventions achieve outcomes. This paper considers the strengths and limitations of such models, and in particular the degree to which they are able to do justice to the complexity of CPD and its effects. After placing level models within the broader context of debates about CPD evaluation, the paper reports our experience of developing such models heuristically for our own evaluation practice. It then draws on positivist, realist and constructivist traditions to consider some more fundamental ontological and epistemological questions to which they give rise. The paper concludes that level models can be used in a number of ways and with differing emphases, and that choices made about their use will need to reflect both theoretical choices and practical considerations

Generation of Primordial Cosmological Perturbations from Statistical Mechanical Models

The initial conditions describing seed fluctuations for the formation of structure in standard cosmological models, i.e.the Harrison-Zeldovich distribution, have very characteristic ``super-homogeneous'' properties: they are statistically translation invariant, isotropic, and the variance of the mass fluctuations in a region of volume V grows slower than V. We discuss the geometrical construction of distributions of points in ${\bf R}^3$ with similar properties encountered in tiling and in statistical physics, e.g. the Gibbs distribution of a one-component system of charged particles in a uniform background (OCP). Modifications of the OCP can produce equilibrium correlations of the kind assumed in the cosmological context. We then describe how such systems can be used for the generation of initial conditions in gravitational $N$-body simulations.Comment: 7 pages, 3 figures, final version with minor modifications, to appear in PR

The Glass-like Universe: Real-space correlation properties of standard cosmological models

After reviewing the basic relevant properties of stationary stochastic processes (SSP), defining basic terms and quantities, we discuss the properties of the so-called Harrison-Zeldovich like spectra. These correlations, usually characterized exclusively in k-space (i.e. in terms of power spectra P(k)), are a fundamental feature of all current standard cosmological models. Examining them in real space we note their characteristics to be a {\it negative} power law tail \xi(r) \sim - r^{-4} and a {\it sub-poissonian} normalised variance in spheres \sigma^2(R) \sim R^{-4} \ln R. We note in particular that this latter behaviour is at the limit of the most rapid decay (\sim R^{-4}) of this quantity possible for any stochastic distribution (continuous or discrete). This very particular characteristic is usually obscured in cosmology by the use of Gaussian spheres. In a simple classification of all SSP into three categories, we highlight with the name ``super-homogeneous'' the properties of the class to which models like this, with P(0)=0, belong. In statistical physics language they are well described as glass-like. They do not have either ``scale-invariant'' features, in the sense of critical phenomena, nor fractal properties. We illustrate their properties with some simple examples, in particular that of a ``shuffled'' lattice.Comment: 20 pages, 3 postscript figures, corrected some typos and minor changes to match the accepted version in Physical Review