Bimodality in the transverse fluctuations of a grafted semiflexible polymer and the diffusion-convection analogue: An effective-medium approach

Recent Monte Carlo simulations of a grafted semiflexible polymer in 1+1 dimensions have revealed a pronounced bimodal structure in the probability distribution of the transverse (bending) fluctuations of the free end, when the total contour length is of the order of the persistence length G. Lattanzi , Phys. Rev E 69, 021801 (2004)]. In this paper, we show that the emergence of bimodality is related to a similar behavior observed when a random walker is driven in the transverse direction by a certain type of shear flow. We adapt an effective-medium argument, which was first introduced in the context of the sheared random-walk problem E. Ben-Naim , Phys. Rev. A 45, 7207 (1992)], in order to obtain a simple analytic approximation of the probability distribution of the free-end fluctuations. We show that this approximation captures the bimodality and most of the qualitative features of the free-end fluctuations. We also predict that relaxing the local inextensibility constraint of the wormlike chain could lead to the disappearence of bimodality

Bundle formation in parallel aligned polymers with competing interactions

Aggregation of like-charged polymers is widely observed in biological and soft matter systems. In many systems, bundles are formed when a short-range attraction of diverse physical origin like charge-bridging, hydrogen-bonding or hydrophobic interaction, overcomes the longer- range charge repulsion. In this Letter, we present a general mechanism of bundle formation in these systems as the breaking of the translational invariance in parallel aligned polymers with competing interactions of this type. We derive a criterion for finite-sized bundle formation as well as for macroscopic phase separation (formation of infinite bundles).Comment: accepted for publication in Europhys Let

Linear response of a grafted semiflexible polymer to a uniform force field

We use the worm-like chain model to analytically calculate the linear response of a grafted semiflexible polymer to a uniform force field. The result is a function of the bending stiffness, the temperature, the total contour length, and the orientation of the field with respect to that of the grafted end. We also study the linear response of a worm-like chain with a periodic alternating sequence of positive and negative charges. This can be considered as a model for a polyampholyte with intrinsic bending siffness and negligible intramolecular interactions. We show how the finite intrinsic persistence length affects the linear response to the external field.Comment: 6 pages, 3 figure

Hydrodynamics of liquids of arbitrarily curved flux-lines and vortex loops

We derive a hydrodynamic model for a liquid of arbitrarily curved flux-lines and vortex loops using the mapping of the vortex liquid onto a liquid of relativistic charged quantum bosons in 2+1 dimensions recently suggested by Tesanovic and by Sudbo and collaborators. The loops in the flux-line system correspond to particle-antiparticle fluctuations in the bosons. We explicitly incorporate the externally applied magnetic field which in the boson model corresponds to a chemical potential associated with the conserved charge density of the bosons. We propose this model as a convenient and physically appealing starting point for studying the properties of the vortex liquid

Force-extension relation of cross-linked anisotropic polymer networks

Cross-linked polymer networks with orientational order constitute a wide class of soft materials and are relevant to biological systems (e.g., F-actin bundles). We analytically study the nonlinear force-extension relation of an array of parallel-aligned, strongly stretched semiflexible polymers with random cross-links. In the strong stretching limit, the effect of the cross-links is purely entropic, independent of the bending rigidity of the chains. Cross-links enhance the differential stretching stiffness of the bundle. For hard cross-links, the cross-link contribution to the force-extension relation scales inversely proportional to the force. Its dependence on the cross-link density, close to the gelation transition, is the same as that of the shear modulus. The qualitative behavior is captured by a toy model of two chains with a single cross-link in the middle.Comment: 7 pages, 4 figure

Orientational order and glassy states in networks of semiflexible polymers

Motivated by the structure of networks of cross-linked cytoskeletal biopolymers, we study the orientationally ordered phases in two-dimensional networks of randomly cross-linked semiflexible polymers. We consider permanent cross-links which prescribe a finite angle and treat them as quenched disorder in a semi-microscopic replica field theory. Starting from a fluid of un-cross-linked polymers and small polymer clusters (sol) and increasing the cross-link density, a continuous gelation transition occurs. In the resulting gel, the semiflexible chains either display long range orientational order or are frozen in random directions depending on the value of the crossing angle, the crosslink concentration and the stiffness of the polymers. A crossing angle $\theta\sim 2\pi/M$ leads to long range $M$-fold orientational order, e.g., "hexatic" or "tetratic" for $\theta=60^{\circ}$ or $90^{\circ}$, respectively. The transition is discontinuous and the critical cross-link density depends on the bending stiffness of the polymers and the cross-link geometry: the higher the stiffness and the lower $M$, the lower the critical number of cross-links. In between the sol and the long range ordered state, we always observe a gel which is a statistically isotropic amorphous solid (SIAS) with random positional and random orientational localization of the participating polymers.Comment: 20 pages, added references, minor changes, final version as published in PR

Weak point disorder in strongly fluctuating flux-line liquids

We consider the effect of weak uncorrelated quenched disorder (point defects) on a strongly fluctuating flux-line liquid. We use a hydrodynamic model which is based on mapping the flux-line system onto a quantum liquid of relativistic charged bosons in 2+1 dimensions [P. Benetatos and M. C. Marchetti, Phys. Rev. B 64, 054518, (2001)]. In this model, flux lines are allowed to be arbitrarily curved and can even form closed loops. Point defects can be scalar or polar. In the latter case, the direction of their dipole moments can be random or correlated. Within the Gaussian approximation of our hydrodynamic model, we calculate disorder-induced corrections to the correlation functions of the flux-line fields and the elastic moduli of the flux-line liquid. We find that scalar disorder enhances loop nucleation, and polar (magnetic) defects decrease the tilt modulus.Comment: 15 pages, submitted to Pramana-Journal of Physics for the special volume on Vortex State Studie

Variational theory of flux-line liquids

We formulate a variational (Hartree like) description of flux line liquids which improves on the theory we developed in an earlier paper [A.M. Ettouhami, Phys. Rev. B 65, 134504 (2002)]. We derive, in particular, how the massive term confining the fluctuations of flux lines varies with temperature and show that this term vanishes at high enough temperatures where the vortices behave as freely fluctuating elastic lines.Comment: 10 pages, 1 postscript figur

Transverse fluctuations of grafted polymers

We study the statistical mechanics of grafted polymers of arbitrary stiffness in a two-dimensional embedding space with Monte Carlo simulations. The probability distribution function of the free end is found to be highly anisotropic and non-Gaussian for typical semiflexible polymers. The reduced distribution in the transverse direction, a Gaussian in the stiff and flexible limits, shows a double peak structure at intermediate stiffnesses. We also explore the response to a transverse force applied at the polymer free end. We identify F-Actin as an ideal benchmark for the effects discussed.Comment: 10 pages, 4 figures, submitted to Physical Review

Tilt Modulus and Angle-Dependent Flux Lattice Melting in the Lowest Landau Level Approximation

For a clean high-T$_c$ superconductor, we analyze the Lawrence-Doniach free energy in a tilted magnetic field within the lowest Landau level (LLL) approximation. The free energy maps onto that of a strictly $c$-axis field, but with a reduced interlayer coupling. We use this result to calculate the tilt modulus $C_{44}$ of a vortex lattice and vortex liquid. The vortex contribution to $C_{44}$ can be expressed in terms of the squared $c$-axis Josephson plasmon frequency $\omega_{pl}^2$. The transverse component of the field has very little effect on the position of the melting curve.Comment: 8 pages, 2 figures, accepted for publication in Physical Review B (Rapid Communications