1,061 research outputs found
Thermodynamics, Structure, and Dynamics of Water Confined between Hydrophobic Plates
We perform molecular dynamics simulations of 512 water-like molecules that
interact via the TIP5P potential and are confined between two smooth
hydrophobic plates that are separated by 1.10 nm. We find that the anomalous
thermodynamic properties of water are shifted to lower temperatures relative to
the bulk by K. The dynamics and structure of the confined water
resemble bulk water at higher temperatures, consistent with the shift of
thermodynamic anomalies to lower temperature. Due to this shift, our
confined water simulations (down to K) do not reach sufficiently low
temperature to observe a liquid-liquid phase transition found for bulk water at
K using the TIP5P potential. We find that the different
crystalline structures that can form for two different separations of the
plates, 0.7 nm and 1.10 nm, have no counterparts in the bulk system, and
discuss the relevance to experiments on confined water.Comment: 31 pages, 14 figure
Mesoscopic Phase Fluctuations: General Phenomenon in Condensed Matter
General conditions for the occurrence of mesoscopic phase fluctuations in
condensed matter are considered. The description of different thermodynamic
phases, which coexist as a mixture of mesoscopically separated regions, is
based on the {\it theory of heterophase fluctuations}. The spaces of states,
typical of the related phases, are characterized by {\it weighted Hilbert
spaces}. Several models illustrate the main features of heterophase condensed
matter.Comment: 23 pages, Latex, no figure
Origin of the Electron-Phonon Interaction of Topological Semimetal Surfaces Measured with Helium Atom Scattering
He atom scattering has been demonstrated to be a sensitive probe of the
electron-phonon interaction parameter at metal and metal-overlayer
surfaces. Here it is shown that the theory linking to the thermal
attenuation of atom scattering spectra (the Debye-Waller factor), can be
applied to topological semimetal surfaces, like the quasi-one dimensional
charge-density-wave system Bi(114) and the layered pnictogen chalcogenides
Comparison of Bond Character in Hydrocarbons and Fullerenes
We present a comparison of the bond polarizabilities for carbon-carbon bonds
in hydrocarbons and fullerenes, using two different models for the fullerene
Raman spectrum and the results of Raman measurements on ethane and ethylene. We
find that the polarizabilities for single bonds in fullerenes and hydrocarbons
compare well, while the double bonds in fullerenes have greater polarizability
than in ethylene.Comment: 7 pages, no figures, uses RevTeX. (To appear in Phys. Rev. B.
NEXUS/Physics: An interdisciplinary repurposing of physics for biologists
In response to increasing calls for the reform of the undergraduate science
curriculum for life science majors and pre-medical students (Bio2010,
Scientific Foundations for Future Physicians, Vision & Change), an
interdisciplinary team has created NEXUS/Physics: a repurposing of an
introductory physics curriculum for the life sciences. The curriculum interacts
strongly and supportively with introductory biology and chemistry courses taken
by life sciences students, with the goal of helping students build general,
multi-discipline scientific competencies. In order to do this, our two-semester
NEXUS/Physics course sequence is positioned as a second year course so students
will have had some exposure to basic concepts in biology and chemistry.
NEXUS/Physics stresses interdisciplinary examples and the content differs
markedly from traditional introductory physics to facilitate this. It extends
the discussion of energy to include interatomic potentials and chemical
reactions, the discussion of thermodynamics to include enthalpy and Gibbs free
energy, and includes a serious discussion of random vs. coherent motion
including diffusion. The development of instructional materials is coordinated
with careful education research. Both the new content and the results of the
research are described in a series of papers for which this paper serves as an
overview and context.Comment: 12 page
Libri novi
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43271/1/11046_2005_Article_BF02051463.pd
Sequential superradiant scattering from atomic Bose-Einstein condensates
We theoretically discuss several aspects of sequential superradiant
scattering from atomic Bose-Einstein condensates. Our treatment is based on the
semiclassical description of the process in terms of the Maxwell-Schroedinger
equations for the coupled matter-wave and optical fields. First, we investigate
sequential scattering in the weak-pulse regime and work out the essential
mechanisms responsible for bringing about the characteristic fan-shaped
side-mode distribution patterns. Second, we discuss the transition between the
Kapitza-Dirac and Bragg regimes of sequential scattering in the strong-pulse
regime. Finally, we consider the situation where superradiance is initiated by
coherently populating an atomic side mode through Bragg diffraction, as in
studies of matter-wave amplification, and describe the effect on the sequential
scattering process.Comment: 9 pages, 4 figures. Submitted to Proceedings of LPHYS'06 worksho
Libri novi
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43270/1/11046_2005_Article_BF02089882.pd
Theoretical investigations of a highly mismatched interface: the case of SiC/Si(001)
Using first principles, classical potentials, and elasticity theory, we
investigated the structure of a semiconductor/semiconductor interface with a
high lattice mismatch, SiC/Si(001). Among several tested possible
configurations, a heterostructure with (i) a misfit dislocation network pinned
at the interface and (ii) reconstructed dislocation cores with a carbon
substoichiometry is found to be the most stable one. The importance of the slab
approximation in first-principles calculations is discussed and estimated by
combining classical potential techniques and elasticity theory. For the most
stable configuration, an estimate of the interface energy is given. Finally,
the electronic structure is investigated and discussed in relation with the
dislocation array structure. Interface states, localized in the heterostructure
gap and located on dislocation cores, are identified
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