576 research outputs found

    Comment on ``Solidification of a Supercooled Liquid in a Narrow Channel''

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    Comment on PRL v. 86, p. 5084 (2001) [cond-mat/0101016]. We point out that the authors' simulations are consistent with the known theory of steady-state solutions in this system

    Rescaling the dynamics of evaporating drops

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    The dynamics of evaporation of wetting droplets has been investigated experimentally in an extended range of drop sizes, in order to provide trends relevant for a theoretical analysis. A model is proposed, which generalises Tanner's law, allowing us to smooth out the singularities both in dissipation and in evaporative flux at the moving contact line. A qualitative agreement is obtained, which represents a first step towards the solution of a very old, complex problem

    Extending the scope of microscopic solvability: Combination of the Kruskal-Segur method with Zauderer decomposition

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    Successful applications of the Kruskal-Segur approach to interfacial pattern formation have remained limited due to the necessity of an integral formulation of the problem. This excludes nonlinear bulk equations, rendering convection intractable. Combining the method with Zauderer's asymptotic decomposition scheme, we are able to strongly extend its scope of applicability and solve selection problems based on free boundary formulations in terms of partial differential equations alone. To demonstrate the technique, we give the first analytic solution of the problem of velocity selection for dendritic growth in a forced potential flow.Comment: Submitted to Europhys. Letters, No figures, 5 page

    Observation of the Inverse Cotton-Mouton Effect

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    We report the observation of the Inverse Cotton-Mouton Effect (ICME) i.e. a magnetization induced in a medium by non resonant linearly polarized light propagating in the presence of a transverse magnetic field. We present a detailed study of the ICME in a TGG crystal showing the dependence of the measured effect on the light intensity, the optical polarization, and on the external magnetic field. We derive a relation between the Cotton-Mouton and Inverse Cotton-Mouton effects that is roughly in agreement with existing experimental data. Our results open the way to applications of the ICME in optical devices

    Morphogenesis in space offers challenges and opportunities for soft matter and biophysics

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    Abstract The effects of microgravity on soft matter morphogenesis have been documented in countless experiments, but physical understanding is still lacking in many cases. Here we review how gravity affects shape emergence and pattern formation for both inert matter and living systems of different biological complexities. We highlight the importance of building physical models for understanding the experimental results available. Answering these fundamental questions will not only solve basic scientific problems, but will also enable several industrial applications relevant to space exploration

    Shaft Resistance During Driving in Clay from Laboratory Tests

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    This paper presents a laboratory study which aimed at investigating the soil/pile interaction during driving. A short review of past experimental works justifies the need for more consistent data. The test equipment (a rod driven through a sample of soil) is briefly presented and some signals are displayed to illustrate the quality of the measurements. The tests were performed on samples of normally consolidated Kaolinit clay. The analysis of the stress waves propagating in the rod, during driving, provided a good estimation of interaction forces, bar velocities and displacements of the pile model in the sample. Relationships were established between the interaction force, the energy dissipated in the sample of soil, the velocity and the displacement of the rod, and the confining pressure of the sample. Observations and relationships were used (1) to identify the physical phenomena occurring at the soil/pile interface during driving, and (2) to base a law governing this shaft interaction

    Traitement d'effluents de tannerie-mégisserie par microfiltration tangentielle

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    Dans ce travail un procĂ©dĂ© de traitement des effluents issus de l'unitĂ© de prĂ©paration des peaux des animaux au tannage (travail en riviĂšre) en tannerie-mĂ©gisserie a Ă©tĂ© Ă©tudiĂ© en utilisant la technique de microfiltration tangentielle sur membrane minĂ©rale en cĂ©ramique. Les performances de ce procĂ©dĂ© en terme de flux de filtration et de rendement Ă©puratoire dĂ©pendent aussi bien des paramĂštres hydrodynamiques de filtration que de la qualitĂ© des effluents (collectĂ©s en Ă©tĂ© et en printemps) issus des diffĂ©rents bains de traitement et de rinçage des peaux dans l'atelier de riviĂšre. Le flux de filtration varie entre 15 l/h.m2 pour l'effluent de printemps et 90 l/h.m2 pour l'effluent d'Ă©tĂ©. Les paramĂštres hydrodynamiques optimaux ont Ă©galement Ă©tĂ© dĂ©terminĂ©s: la vitesse de circulation U=3 m/s, la pression transmembranaire Ptm=2 bar et la tempĂ©rature T=43°C. L'Ă©tude de la microfiltration Ă  concentration variable conduit Ă  des facteurs de concentration volumique (FCV) de 6,5 pour l'effluent de l'Ă©tĂ© et de 2,4 pour l'effluent de printemps.The leather industry is responsible for the transformation of raw animal skin to a final form as shoes, bags, dresses, etc. This industry was known for centuries as a craft activity, and today with industrial development, environmental regulations and new emerging technologies, it has become necessary to include elaborate processes for its wastewater treatment. These industries consume a great amount of water. In Tunisia, more than 15000 tons of skin are treated per year, and about 600000 m3 per year of effluents are discharged. The waste water contains chemicals, fats, hair and protein, varying in composition depending on the season. Figure 1 represents the preparation of raw skin for the tanning operation and the amount of waste water produced. The amount of water used for the preparation of raw skin is about 70% of the total quantity of water used. This waste water has a significant polluting load (chemicals and organic matter), with 5000 - 7500 mg/l of COD and 100 to 150 mg/l of sulfur. Tunisian legislation and regulations concerning the standards for wastewater disposal are 1000 mg/l for COD, 3 mg/l for sulfur and a pH between 6.5-9. Different techniques for wastewater treatment such as: physico-chemical treatment, treatment by electrochemical oxidation and membrane technology were proposed. Wastewater treatment by microfiltration and ultrafiltration with mineral membranes is advantageous because no chemicals are used and it can be combined easily with other physico-chemical or biological pre-treatments. In this study, we have treated two types of effluents from the leather pre-treatment industry collected in the summer (effluent 1), and the spring (effluent 2) seasons. The physico-chemical characteristics of the two types effluents are given in Table 2. The filtration experiments were made on a test bench (Figure 2) equipped with a feed reservoir, a volumetric pump, a filtration module, flow meter, pressure transducers, a heat exchanger and control valves. Ceramic membranes of tubular geometry (7 channels), 0.08 m2 membrane surface area and of 0.1 ”m (mean diameter) pores were used. During the microfiltration experiments, the following physico-chemical parameters were analysed in the permeate and retentate: turbidity, specific conductivity, pH, viscosity, chemical oxygen demand (COD), sulfur (volumetric method), fats (Standard JIS 0102.24.2), protein (using Kjeldahl nitrogen), and organic nitrogen. Hydrodynamic parameters such as temperature (25 < T < 50 °C), transmembrane pressure (1 < Ptm < 2.2 bar) and feed velocity (1 < U < 3 m/s) were fixed for experimentation. The COD concentration in the effluent was adjusted and kept constant at 5000 mg/l. The raw effluent was pre-filtered on a screen filter (150 ”m pore size). For experiments with variable concentration, we regularly removed the filtrate and the concentration factor was represented by FCV=Vi / Vr, where Vi was the initial volume and Vr was the volume of the retentate. The performance of the microfiltration (J) was expressed in l/h×m2. The retention rate (TR) was defined by: TR=1 - (Cpermeate) / (Cfeed). The total hydraulic resistance (RT) was defined by Darcy's law: Jf=Ptm / ” RT. After each experiment, the membrane was regenerated following a standard protocol and it was verified by measuring water flux. Figure 3a represents the variation of the filtration flux with time for 4 different temperatures: 25 °C, 43 °C, 45 °C and 50 °C with effluent 1. The flux increased from 90 to 118 l/h×m2 when the temperature increased from 25 °C to 43 °C. After 90 min at 50 °C, the filtration flux was 123 l/h×m2. Table 3 shows that the viscosity of the effluent decreased with temperature, while the turbidity of the filtrate increased from 0.63 NTU at T=25 °C to 1.6 NTU for T=50 °C. The retention rate of COD was always superior to 50 %. On the basis of these results, we chose the optimum temperature of 43 °C for other experiments. Figure 4 summarises the variation of flux with transmembrane pressure at flow velocities of 1 m/s, 2 m/s and 3 m/s. The stabilized fluxes were practically the same for the flow velocities of 1 and 2 m/s (of the order of 80 l/h×m2), but were higher at 3 m/s (110 - 115 l/h×m2 at 2 bar). The physico-chemical characteristics of the raw effluent and the permeate obtained after 90 minutes of filtration are summarised in Table 4. Figure 7a shows the variation of filtration flux for 2 types of effluents. The filtration flux for the same conditions of experimentation and at stabilized conditions (at 90 min) was 118 l/h×m2 for effluent 1 and 20 l/h×m2 for effluent 2. The lower filtration flux for effluent 2 can be explained by high deposits of rejected matter on the membrane and in the pores. Table 5 gives a comparison of the characteristics of effluents 1 and 2 before and after microfiltration. At variable feed concentrations, FCV=6.5 for effluent 1 and FCV=2.4 for the effluent 2 and the stabilized flux was about 90 l/h×m2 for the effluent 1 and 15 l/h×m2 for the effluent 2. The time needed for treatment of effluent 1 was about 6 hours, while more that 16 hours was necessary for effluent 2. Table 6 provides physico-chemical characteristics for the two types of effluents. The contents of fat, protein, nitrogen and sulfur in the effluent were important factors for variation. These results indicate that microfiltration is very sensitive to the quantity of polluting matter present in the effluents, particularly sulfur and fat. Increased polluting matter in effluent 2 could be responsible for the membrane polarization and blocking of pores. The resistance model was used to verify this hypothesis. The irreversible resistance values for effluent 2 were greater, thus confirming the hypothesis that the increased adsorption on the membrane surface and passage of pores by the presence of sulfur and organic polluting matter. These experimental results confirm that the best performance can be obtained at the hydrodynamic conditions of: a temperature of 43 °C; a transmembrane pressure of 2 bar; and a flow velocity of 3 m/s. Seasonal variation changed the quality of effluents, which considerably affects the performances of the microfiltration. Effluent 2, which was obtained from the treatment of sheep skin during the spring season, led to more membrane pore blocking than effluent 1 for the same initial concentration in COD. The interactions of fats and sulfur with the membrane layer appear to play an important role in the formation of a cake layer

    ‘Chemlali Mhassen’: New olive cultivar derived from crossbreeding program in Tunisia with high oil quality and productivity

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    The new olive cultivar ‘Chemlali Mhassen’ was derived from the autopollination of the Tunisian oil cultivar ‘Chemlali Sfax’. The main morphological differences between the two cultivars were observed on the endocarp (symmetry, position of maximum diameter, apex, base and surface). On the agronomic plan, this cultivar is distinguishable from the original cultivar due to its medium earliness of bearing (4 years), medium alternate bearing (0.44), early ripening, moderate sensitivity to verticillium and its high olive production per tree (7.7 kg). Concerning oil quality, ‘Chemlali Mhassen’ had higher performances than the original cultivar for oleic acid content (70 to 77 %) and lower contents for palmitic acid (9.2 to 11.5 %) and linoleic acid (9.3 to 14.7 %). Similar performances were recorded between the new and the original cultivars for rhizogenesis behavior and pollen compatibility

    Kinetics of Heterogeneous Single-Species Annihilation

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    We investigate the kinetics of diffusion-controlled heterogeneous single-species annihilation, where the diffusivity of each particle may be different. The concentration of the species with the smallest diffusion coefficient has the same time dependence as in homogeneous single-species annihilation, A+A-->0. However, the concentrations of more mobile species decay as power laws in time, but with non-universal exponents that depend on the ratios of the corresponding diffusivities to that of the least mobile species. We determine these exponents both in a mean-field approximation, which should be valid for spatial dimension d>2, and in a phenomenological Smoluchowski theory which is applicable in d<2. Our theoretical predictions compare well with both Monte Carlo simulations and with time series expansions.Comment: TeX, 18 page
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