A study of the need for curriculum adjustments in Weeping Water high school

The purpose of this thesis is to build a curriculum that will meet the needs of the pupils in this locality. The procedure consists in examining past practices, making a scientific survey of prevailing conditions, helping each pupil select the type of work for which he is best fitted, and permitting the results to emerge as the needs of the school demand. The results will be used not only to build a more suitable offering for the high school pupil, but also to serve the instructor as as introduction to the school philosophy and community conditions

Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences

A theoretical description of pulsed reaction yield detected magnetic resonance (RYDMR) is proposed. In RYDMR, magnetic resonance spectra of radical pairs (RPs) are indirectly detected by monitoring their recombination yield. Such a detection method is significantly more sensitive than conventional electron paramagnetic resonance (EPR), but design of appropriate pulse sequences for RYDMR requires additional effort because of a different observable. In this work various schemes for generating spin-echo like signals and detecting them by RYDMR are treated. Specifically, we consider refocusing of zero-quantum coherences (ZQCs) and single-quantum coherences (SQCs) by selective as well as by non-selective pulses and formulate a general analytical approach to pulsed RYDMR, which makes an efficient use of the product operator formalism. We anticipate that these results are of importance for RYDMR studies of elusive paramagnetic particles, notably, in organic semiconductors

Framing fusion and fission

Engineering inter-triplet exchange coupling allows spin mixing between singlet and quintet manifolds in triplet–triplet pair states in metal–organic frameworks, demonstrating increased room-temperature triplet-fusion rates under relatively small applied magnetic fields

The ubiquitin ligation machinery in the defense against bacterial pathogens

The ubiquitin system is an important part of the host cellular defense program during bacterial infection. This is in particular evident for a number of bacteria including Salmonella Typhimurium and Mycobacterium tuberculosis which-inventively as part of their invasion strategy or accidentally upon rupture of seized host endomembranes-become exposed to the host cytosol. Ubiquitylation is involved in the detection and clearance of these bacteria as well as in the activation of innate immune and inflammatory signaling. Remarkably, all these defense responses seem to emanate from a dense layer of ubiquitin which coats the invading pathogens. In this review, we focus on the diverse group of host cell E3 ubiquitin ligases that help to tailor this ubiquitin coat. In particular, we address how the divergent ubiquitin conjugation mechanisms of these ligases contribute to the complexity of the anti-bacterial coating and the recruitment of different ubiquitin-binding effectors. We also discuss the activation and coordination of the different E3 ligases and which strategies bacteria evolved to evade the activities of the host ubiquitin system

Extremely high absolute internal quantum efficiency of photoluminescence in co-doped GaN:Zn,Si

We report on the fabrication of GaN co-doped with silicon and zinc by metalorganic vapor phase epitaxy and a detailed study of photoluminescence in this material. We observe an exceptionally high absolute internal quantum efficiency of blue photoluminescence in GaN:Zn,Si. The value of0.93±0.04 has been obtained from several approaches based on rate equations

Site-selective measurement of coupled spin pairs in an organic semiconductor

From organic electronics to biological systems, understanding the role of intermolecular interactions between spin pairs is a key challenge. Here we show how such pairs can be selectively addressed with combined spin and optical sensitivity. We demonstrate this for bound pairs of spin-triplet excitations formed by singlet fission, with direct applicability across a wide range of synthetic and biological systems. We show that the site sensitivity of exchange coupling allows distinct triplet pairs to be resonantly addressed at different magnetic fields, tuning them between optically bright singlet (S=0) and dark triplet quintet (S=1,2) configurations: This induces narrow holes in a broad optical emission spectrum, uncovering exchange-specific luminescence. Using fields up to 60 T, we identify three distinct triplet-pair sites, with exchange couplings varying over an order of magnitude (0.3–5 meV), each with its own luminescence spectrum, coexisting in a single material. Our results reveal how site selectivity can be achieved for organic spin pairs in a broad range of systems

Determination of the absolute internal quantum efficiency of photoluminescence in GaN co-doped with Si and Zn

The optical properties of high-quality GaN co-doped with silicon and zinc are investigated by using temperature-dependent continuous-wave and time-resolved photoluminescence measurements. The blue luminescence band is related to the ZnGa acceptor in GaN:Si,Zn, which exhibits an exceptionally high absolute internal quantum efficiency (IQE). An IQE above 90% was calculated for several samples having different concentrations of Zn. Accurate and reliable values of the IQE were obtained by using several approaches based on rate equations. The concentrations of the ZnGa acceptors and free electrons were also estimated from the photoluminescence measurements

Physical Vacuum Properties and Internal Space Dimension

The paper addresses matrix spaces, whose properties and dynamics are determined by Dirac matrices in Riemannian spaces of different dimension and signature. Among all Dirac matrix systems there are such ones, which nontrivial scalar, vector or other tensors cannot be made up from. These Dirac matrix systems are associated with the vacuum state of the matrix space. The simplest vacuum system realization can be ensured using the orthonormal basis in the internal matrix space. This vacuum system realization is not however unique. The case of 7-dimensional Riemannian space of signature 7(-) is considered in detail. In this case two basically different vacuum system realizations are possible: (1) with using the orthonormal basis; (2) with using the oblique-angled basis, whose base vectors coincide with the simple roots of algebra E_{8}. Considerations are presented, from which it follows that the least-dimension space bearing on physics is the Riemannian 11-dimensional space of signature 1(-)& 10(+). The considerations consist in the condition of maximum vacuum energy density and vacuum fluctuation energy density.Comment: 19 pages, 1figure. Submitted to General Relativity and Gravitatio