Photochromism of dihydroquinolines

Reversible photochromic reactions, in which absorption spectrum of chemical compound may be shifted by application of visible or ultraviolet light, and then returned to original state by heating, are observed for certain members of 1,2-dihydroquinoline family. Structural formulas for colorless and colored states are given

Mechanics of deformations and fracture final report

Thermal analysis of mechanical behavior of material models with temperature dependent propertie

Acoustic source location in a jet-blown flap using a cross-correlation technique

The acoustic source strength distribution in a turbulent flow field was measured for two far field microphones at 45 deg above and below the plane of the flap surface. A processed signal from an inclined hot-film anemometry probe was cross correlated with the signal from the appropriate far field microphone. The contribution made by the sources associated with the fluctuating pressure on the flap surface to the sound received at far field microphone was estimated by cross correlating the processed signals of microphones which were embedded in the flap surface with the far field microphone signals. In addition, detailed fluid dynamic measurements were made in the flow field of the jet flap using dual sensor hot-film anemometry probes

A Reformulation of the Economic Theory of Fertility

When parents are altruistic toward children, the choices of fertility and consumption come from the maximization of a dynastic utility function. The maximization conditions imply first, an arbitrage condition for consumption across generations, and second, the equation of the benefit from an extra child to the net cost of rearing that child. These conditions imply that fertility in open economies depends positively on the world interest rate, on the degree of altruism, and on the growth of child-survival probabilities; and negatively on the rate of technical progress and the growth rate of social security. The growth of consumption across generations depends on changes in the net cost of rearing children, but not on interest rates or tirne preference. Even when we include life-cycle elements, we conclude that the growth of aggregate consumption per capita depends in the long run on the growth of consumption across generations. Thereby we show that real interest rates and growth rates of consumption per capita would be unrelated in the long run.

Helium atom diffraction measurements of the surface structure and vibrational dynamics of CH_3-Si(111) and CD_3-Si(111) surfaces

The surface structure and vibrational dynamics of CH_3–Si(111) and CD_3–Si(111) surfaces were measured using helium atom scattering. The elastic diffraction patterns exhibited a lattice constant of 3.82 Å, in accordance with the spacing of the silicon underlayer. The excellent quality of the observed diffraction patterns, along with minimal diffuse background, indicated a high degree of long-range ordering and a low defect density for this interface. The vibrational dynamics were investigated by measurement of the Debye–Waller attenuation of the elastic diffraction peaks as the surface temperature was increased. The angular dependence of the specular (θ_i=θ_f) decay revealed perpendicular mean-square displacements of 1.0 x 10^(−5) Å^2 K^(−1) for the CH_3–Si(111) surface and 1.2 x 10^(−5) Å^2 K^(−1) for the CD_3–Si(111) surface, and a He-surface attractive well depth of ~7 meV. The effective surface Debye temperatures were calculated to be 983 K for the CH_3–Si(111) surface and 824 K for the CD_3–Si(111) surface. These relatively large Debye temperatures suggest that collisional energy accommodation at the surface occurs primarily through the Si–C local molecular modes. The parallel mean-square displacements were 7.1 x 10^(−4) and 7.2 x 10^(−4) Å^2 K^(−1) for the CH_3–Si(111) and CD_3–Si(111) surfaces, respectively. The observed increase in thermal motion is consistent with the interaction between the helium atoms and Si–CH_3 bending modes. These experiments have thus yielded detailed information on the dynamical properties of these robust and technologically interesting semiconductor interfaces

Theoretical analysis of STM-derived lifetimes of excitations in the Shockley surface state band of Ag(111)

We present a quantitative many-body analysis using the GW approximation of the decay rate $\Gamma$ due to electron-electron scattering of excitations in the Shockley surface state band of Ag(111), as measured using the scanning tunnelling microscope (STM). The calculations include the perturbing influence of the STM, which causes a Stark-shift of the surface state energy $E$ and concomitant increase in $\Gamma$. We find $\Gamma$ varies more rapidly with $E$ than recently found for image potential states, where the STM has been shown to significantly affect measured lifetimes. For the Shockley states, the Stark-shifts that occur under normal tunnelling conditions are relatively small and previous STM-derived lifetimes need not be corrected.Comment: 4 pages, 3 figure

Pristine CNO abundances from Magellanic Cloud B stars II. Fast rotators in the LMC cluster NGC 2004

We present spectroscopic abundance analyses of three main-sequence B stars in the young Large Magellanic Cloud cluster NGC 2004. All three targets have projected rotational velocities around 130 km/s. Techniques are presented that allow the derivation of stellar parameters and chemical abundances in spite of these high v sin i values. Together with previous analyses of stars in this cluster, we find no evidence among the main-sequence stars for effects due to rotational mixing up to v sin i around 130 km/s. Unless the equatorial rotational velocities are significantly larger than the v sin i values, this finding is probably in line with theoretical expectations. NGC 2004/B30, a star of uncertain evolutionary status located in the Blue Hertzsprung Gap, clearly shows signs of mixing in its atmosphere. To verify the effects due to rotational mixing will therefore require homogeneous analysis of statistically significant samples of low-metallicity main-sequence B stars over a wide range of rotational velocities.Comment: 12 pages, 5 figures, 2 tables; accepted for publication in ApJ (vol. 633, p. 899