5,752 research outputs found

    Derived automorphism groups of K3 surfaces of Picard rank 1

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    We give a complete description of the group of exact autoequivalences of the bounded derived category of coherent sheaves on a K3 surface of Picard rank 1. We do this by proving that a distinguished connected component of the space of stability conditions is preserved by all autoequivalences, and is contractible

    Electronic ground states of Fe2+_2^+ and Co2+_2^+ as determined by x-ray absorption and x-ray magnetic circular dichroism spectroscopy

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    The 6Π^6\Pi electronic ground state of the Co2+_2^+ diatomic molecular cation has been assigned experimentally by x-ray absorption and x-ray magnetic circular dichroism spectroscopy in a cryogenic ion trap. Three candidates, 6Φ^6\Phi, 8Φ^8\Phi, and 8Γ^8\Gamma, for the electronic ground state of Fe2+_2^+ have been identified. These states carry sizable orbital angular momenta that disagree with theoretical predictions from multireference configuration interaction and density functional theory. Our results show that the ground states of neutral and cationic diatomic molecules of 3d3d transition elements cannot generally be assumed to be connected by a one-electron process

    Exciton spin dynamics and photoluminescence polarization of CdSe/CdS dot-in-rod nanocrystals in high magnetic fields

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    The exciton spin dynamics and polarization properties of the related emission are investigated in colloidal CdSe/CdS dot-in-rod (DiR) and spherical core/shell nanocrystal (NC) ensembles by magneto-optical photoluminescence (PL) spectroscopy in magnetic fields up to 15 T. It is shown that the degree of circular polarization (DCP) of the exciton emission induced by the magnetic field is affected by the NC geometry as well as the exciton fine structure and can provide information on nanorod orientation. A theory to describe the circular and linear polarization properties of the NC emission in magnetic field is developed. It takes into account phonon mediated coupling between the exciton fine structure states as well as the dielectric enhancement effect resulting from the anisotropic shell of DiR NCs. This theoretical approach is used to model the experimental results and allows us to explain most of the measured features. The spin dynamics of the dark excitons is investigated in magnetic fields by time-resolved photoluminescence. The results highlight the importance of confined acoustic phonons in the spin relaxation of dark excitons. The bare core surface as well as the core/shell interface give rise to an efficient spin relaxation channel, while the surface of core/shell NCs seems to play only a minor role.Comment: 18 pages, 15 figure

    Spin diffusion in the Mn2+ ion system of II-VI diluted magnetic semiconductor heterostructures

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    The magnetization dynamics in diluted magnetic semiconductor heterostructures based on (Zn,Mn)Se and (Cd,Mn)Te has been studied experimentally by optical methods and simulated numerically. In the samples with nonhomogeneous magnetic ion distribution this dynamics is contributed by spin-lattice relaxation and spin diffusion in the Mn spin system. The spin diffusion coefficient of 7x10^(-8) cm^2/s has been evaluated for Zn(0.99)Mn(0.01)Se from comparison of experimental and numerical results. Calculations of the giant Zeeman splitting of the exciton states and the magnetization dynamics in the ordered alloys and parabolic quantum wells fabricated by the digital growth technique show perfect agreement with the experimental data. In both structure types the spin diffusion has an essential contribution to the magnetization dynamics.Comment: 12 pages, 11 figure

    Nanoscale Weibull Statistics

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    In this paper a modification of the classical Weibull Statistics is developed for nanoscale applications. It is called Nanoscale Weibull Statistics. A comparison between Nanoscale and classical Weibull Statistics applied to experimental results on fracture strength of carbon nanotubes clearly shows the effectiveness of the proposed modification. A Weibull's modulus around 3 is, for the first time, deduced for nanotubes. The approach can treat (also) a small number of structural defects, as required for nearly defect free structures (e.g., nanotubes) as well as a quantized crack propagation (e.g., as a consequence of the discrete nature of matter), allowing to remove the paradoxes caused by the presence of stress-intensifications
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