462 research outputs found
Studies on the respiratory pigment of Urechis eggs
Experiments previously reported (1) have shown that the eggs of the Pacific marine worm, Urechis caupo, contain a reversible oxidation-reduction pigment. The pigment, called urechrome, is autoxidizable and changes color from red to yellow on oxidation. It is soluble in water (reduced form insoluble below pH 5) and in acidified methanol, but insoluble in ether, acetone, chloroform, and neutral alcohol. Evidence for participation of the pigment in cellular respiration has been previously given
Correlating microbial community profiles with geochemical data in highly stratified sediments from the Arctic Mid-Ocean Ridge
Microbial communities and their associated metabolic activity in
marine sediments have a profound impact on global biogeochemical
cycles. Their composition and structure are attributed to geochemical
and physical factors, but finding direct correlations has remained a
challenge. Here we show a significant statistical relationship between
variation in geochemical composition and prokaryotic community
structure within deep-sea sediments. We obtained comprehensive
geochemical data from two gravity cores near the hydrothermal
vent field Loki’s Castle at the Arctic Mid-Ocean Ridge, in the Norwegian-
Greenland Sea. Geochemical properties in the rift valley
sediments exhibited strong centimeter-scale stratigraphic variability.
Microbial populations were profiled by pyrosequencing from
15 sediment horizons (59,364 16S rRNA gene tags), quantitatively
assessed by qPCR, and phylogenetically analyzed. Although the
same taxa were generally present in all samples, their relative
abundances varied substantially among horizons and fluctuated
between Bacteria- and Archaea-dominated communities. By independently
summarizing covariance structures of the relative
abundance data and geochemical data, using principal components
analysis, we found a significant correlation between changes in
geochemical composition and changes in community structure.
Differences in organic carbon and mineralogy shaped the relative
abundance of microbial taxa. We used correlations to build hypotheses
about energy metabolisms, particularly of the Deep Sea Archaeal
Group, specific Deltaproteobacteria, and sediment lineages
of potentially anaerobic Marine Group I Archaea. We demonstrate
that total prokaryotic community structure can be directly correlated
to geochemistry within these sediments, thus enhancing our
understanding of biogeochemical cycling and our ability to predict
metabolisms of uncultured microbes in deep-sea sediments
Creation and control of a two-dimensional electron liquid at the bare SrTiO3 surface
Many-body interactions in transition-metal oxides give rise to a wide range
of functional properties, such as high-temperature superconductivity, colossal
magnetoresistance, or multiferroicity. The seminal recent discovery of a
two-dimensional electron gas (2DEG) at the interface of the insulating oxides
LaAlO3 and SrTiO3 represents an important milestone towards exploiting such
properties in all-oxide devices. This conducting interface shows a number of
appealing properties, including a high electron mobility, superconductivity,
and large magnetoresistance and can be patterned on the few-nanometer length
scale. However, the microscopic origin of the interface 2DEG is poorly
understood. Here, we show that a similar 2DEG, with an electron density as
large as 8x10^13 cm^-2, can be formed at the bare SrTiO3 surface. Furthermore,
we find that the 2DEG density can be controlled through exposure of the surface
to intense ultraviolet (UV) light. Subsequent angle-resolved photoemission
spectroscopy (ARPES) measurements reveal an unusual coexistence of a light
quasiparticle mass and signatures of strong many-body interactions.Comment: 14 pages, 4 figures, supplementary information (see other files
On slip pulses at a sheared frictional viscoelastic/ non deformable interface
We study the possibility for a semi-infinite block of linear viscoelastic
material, in homogeneous frictional contact with a non-deformable one, to slide
under shear via a periodic set of ``self-healing pulses'', i.e. a set of
drifting slip regions separated by stick ones. We show that, contrary to
existing experimental indications, such a mode of frictional sliding is
impossible for an interface obeying a simple local Coulomb law of solid
friction. We then discuss possible physical improvements of the friction model
which might open the possibility of such dynamics, among which slip weakening
of the friction coefficient, and stress the interest of developing systematic
experimental investigations of this question.Comment: 23 pages, 3 figures. submitted to PR
Self healing slip pulses along a gel/glass interface
We present an experimental evidence of self-healing shear cracks at a
gel/glass interface. This system exhibits two dynamical regimes depending on
the driving velocity : steady sliding at high velocity (> Vc = 100-125 \mu
m/s), caracterized by a shear-thinning rheology, and periodic stick-slip
dynamics at low velocity. In this last regime, slip occurs by propagation of
pulses that restick via a ``healing instability'' occuring when the local
sliding velocity reaches the macroscopic transition velocity Vc. At driving
velocities close below Vc, the system exhibits complex spatio-temporal
behavior.Comment: 4 pages, 6 figure
Stick-slip motion of solids with dry friction subject to random vibrations and an external field
We investigate a model for the dynamics of a solid object, which moves over a
randomly vibrating solid surface and is subject to a constant external force.
The dry friction between the two solids is modeled phenomenologically as being
proportional to the sign of the object's velocity relative to the surface, and
therefore shows a discontinuity at zero velocity. Using a path integral
approach, we derive analytical expressions for the transition probability of
the object's velocity and the stationary distribution of the work done on the
object due to the external force. From the latter distribution, we also derive
a fluctuation relation for the mechanical work fluctuations, which incorporates
the effect of the dry friction.Comment: v1: 23 pages, 9 figures; v2: Reference list corrected; v3: Published
version, typos corrected, references adde
Friction Laws for Elastic Nano-Scale Contacts
The effect of surface curvature on the law relating frictional forces F with
normal load L is investigated by molecular dynamics simulations as a function
of surface symmetry, adhesion, and contamination. Curved, non-adhering, dry,
commensurate surfaces show a linear dependency, F proportional to L, similar to
dry flat commensurate or amorphous surfaces and macroscopic surfaces. In
contrast, curved, non-adhering, dry, amorphous surfaces show F proportional to
L^(2/3) similar to friction force microscopes. In our model, adhesive effects
are most adequately described by the Hertz plus offset model, as the
simulations are confined to small contact radii. Curved lubricated or
contaminated surfaces show again different behavior; details depend on how much
of the contaminant gets squeezed out of the contact. Also, it is seen that the
friction force in the lubricated case is mainly due to atoms at the entrance of
the tip.Comment: 7 pages, 5 figures, submitted to Europhys. Let
Coupling Of The B1g Phonon To The Anti-Nodal Electronic States of Bi2Sr2Ca0.92Y0.08Cu2O(8+delta)
Angle-resolved photoemission spectroscopy (ARPES) on optimally doped
Bi2Sr2Ca0.92Y0.08Cu2O(8+delta) uncovers a coupling of the electronic bands to a
40 meV mode in an extended k-space region away from the nodal direction,
leading to a new interpretation of the strong renormalization of the electronic
structure seen in Bi2212. Phenomenological agreements with neutron and Raman
experiments suggest that this mode is the B1g oxygen bond-buckling phonon. A
theoretical calculation based on this assignment reproduces the electronic
renormalization seen in the data.Comment: 4 Pages, 4 Figures Updated Figures and Tex
Doping dependence of the coupling of electrons to bosonic modes in the single-layer high-temperature Bi2Sr2CuO6 superconductor
A recent highlight in the study of high-Tc superconductors is the observation
of band renormalization / self-energy effects on the quasiparticles. This is
seen in the form of kinks in the quasiparticle dispersions as measured by
photoemission and interpreted as signatures of collective bosonic modes
coupling to the electrons. Here we compare for the first time the self-energies
in an optimally doped and strongly overdoped, non-superconducting single-layer
Bi-cuprate (Bi2Sr2CuO6). Besides the appearance of a strong overall weakening,
we also find that weight of the self-energy in the overdoped system shifts to
higher energies. We present evidence that this is related to a change in the
coupling to c-axis phonons due to the rapid change of the c-axis screening in
this doping range.Comment: 4 pages, 3 figure
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