62 research outputs found
Bimetallic Coordination Insertion Polymerization of Unprotected Polar Monomers: Copolymerization of Amino Olefins and Ethylene by Dinickel Bisphenoxyiminato Catalysts
A giant exoplanet orbiting a very-low-mass star challenges planet formation models
Surveys have shown that super-Earth and Neptune-mass exoplanets are more frequent than gas giants around low-mass stars, as predicted by the core accretion theory of planet formation. We report the discovery of a giant planet around the very-low-mass star GJ 3512, as determined by optical and near-infrared radial-velocity observations. The planet has a minimum mass of 0.46 Jupiter masses, very high for such a small host star, and an eccentric 204-day orbit. Dynamical models show that the high eccentricity is most likely due to planet-planet interactions. We use simulations to demonstrate that the GJ 3512 planetary system challenges generally accepted formation theories, and that it puts constraints on the planet accretion and migration rates. Disk instabilities may be more efficient in forming planets than previously thought
Synthesis of Aqueous Polyethylene Dispersions with Electron-Deficient Neutral Nickel(II) Catalysts with Enolatoimine Ligands
Versuche mit Toxaphen-Staub zur Festsfellung der Bienengefährlichkeit und der Wirkung gegen Kohlschotenrüßler und Rapsglanzkäferler und Rapsglanzkäfer
Hydrocarbon Waxes from a Salt in Water: The C1 Polymerization of Trimethylsulfoxonium Halide
Modeled black carbon radiative forcing and atmospheric lifetime in AeroCom Phase II constrained by aircraft observations
Atmospheric black carbon (BC) absorbs solar radiation, and exacerbates global warming
through exerting positive radiative forcing (RF). However, the contribution of BC to
ongoing changes in global climate is under debate. Anthropogenic BC emissions, and
5 the resulting distribution of BC concentration, are highly uncertain. In particular, long
range transport and processes affecting BC atmospheric lifetime are poorly understood.
Here we discuss whether recent assessments may have overestimated present
day BC radiative forcing in remote regions. We compare vertical profiles of BC concentration
from four recent aircraft measurement campaigns to simulations by 13 aerosol
10 models participating in the AeroCom Phase II intercomparision. An atmospheric lifetime
of BC of less than 5 days is shown to be essential for reproducing observations
in remote ocean regions, in line with other recent studies. Adjusting model results to
measurements in remote regions, and at high altitudes, leads to a 25% reduction in
AeroCom Phase II median direct BC forcing, from fossil fuel and biofuel burning, over
15 the industrial era. The sensitivity of modeled forcing to BC vertical profile and lifetime
highlights an urgent need for further flight campaigns, close to sources and in remote
regions, to provide improved quantification of BC effects for use in climate policy
Kinetic and Mechanistic Aspects of Ethylene and Acrylates Catalytic Copolymerization in Solution and in Emulsion
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