Structural and magnetic properties of amorphous Co-W alloyed nanoparticles

18 páginas, 20 figuras, 4 tablas.-- PACS number(s): 75.75.Fk, 75.50.Kj, 75.30.Gw, 61.46.Df.-- et al.et al.W-capped Co nanoparticles dispersed in an alumina matrix are studied by means of high-resolution transmission electron microscopy, extended x-ray absorption fine structure, SQUID-based magnetic measurements, dc magnetization, ac magnetic susceptibility, and x-ray magnetic circular dichroism. Results show the formation of amorphous Co-W alloy nanoparticles, the magnetic properties of which are modified by the amount of W or Co present in the samples. The average Co magnetic moment depends on the number of W atoms surrounding it. Co-W particles show superparamagnetic behavior and are described as an array of noninteracting particles with random anisotropy axes and an average moment per particle proportional to the particle volume and to the average Co moment for each alloy composition. Values of the magnetic anisotropy constant of the particles are on the order of 106 erg/cm3, higher than that of bulk Co. Evidence of short-range ordering within each amorphous particle is found that provides insight of the origin of their magnetic anisotropy.The financial support of MICINN-FEDER MAT08/1077 and Aragonese IMANA project is acknowledged. A.I.F. acknowledges a CSIC JAE2008-Predoc grant.Peer reviewe

European Economies in the First Epoch of Imperialism and Mercantilism. 1415-1846.

The costs and benefits of European Imperialism from the conquest of Ceuta, 1415, to the Treaty of Lusaka, 1974.Twelfth International Economic History Congress. Madrid, 1998.Patrick K. O'Brien and Leandro Prados de la Escosura (eds.)Editada en la Fundación Empresa PúblicaJorge M. Pedreira. «To Have and To Have not». The Economic Consequences of Empire: Portugal (1415-1822).-- Bartolomé Yun-Casalilla. The American Empire and the Spanish Economy: An Institutional and Regional Perspective.-- Pieter C. Emmer. The Economic Impact of the Dutch Expansion Overseas, 1570-1870.-- Paul Butel and François Crouzet. Empire and Economic Growth: the Case of 18th Century France.-- Stanley L. Engerman. British Imperialism in a Mercantilist Age, 1492-1849: Conceptual Issues and Empirical Problems.Publicad

Achieving a "SIL 1" TCR Monitoring System

SIL 1 (Safety Integrity Level 1) refers to the quantification and measurement of the availability, reliability, maintenance and safety of the monitoring system. In the last few years the computer infrastructure used to acquire and to diffuse data to the TCR has evolved very rapidly. A number of measures in hardware, software and management have been introduced to cope with this situation. These include: the Multipurpose Monitoring Device (MMD), a standard data acquisition platform used in the renovation of old front end monitoring equipment, the Smart Equipment Controller (Dsec), a driver that reduces the layers in the data diffusion pyramid, the multiplatform monitoring software to integrate the different SCADA systems, a software configuration tool (RAZOR) for problem tracking and version control, and a complete development environment reproducing a real installation for thorough testing of any changes. To achieve SIL 1 objectives, while mastering the evolution of our systems will be the challenge for the computer team

Critical fields for vortex expulsion from narrow superconducting strips

We calculate the critical magnetic fields for vortex expulsion for an infinitely long superconducting strip, using the Ginzburg-Landau formalism. Two critical fields can be defined associated with the disappearance of either the energetic stability or metastability of vortices in the center of the strip for decreasing magnetic fields. We compare the theoretical predictions for the critical fields in the London formalism with ours and with recently published experimental results. As expected, for narrow strips our results reproduce better the experimental findings.Comment: 5 pages, 5 figure

Morphology and magnetic properties of W-capped Co nanoparticles

3 páginas, 3 figuras, 2 tablas.-- et al.Co–W nanoparticles formed by sequential sputtering of Co on amorphous alumina substrate and subsequent W capping are studied by high resolution and by scanning transmission electron microscopies, and by superconducting quantum interference device magnetometry. The analysis is focused on W nominal thickness dependence. Results suggest the formation of amorphous Co–W alloy nanoparticles, whose magnetic moment per Co atom is systematically reduced as the nominal thickness of W capping layer increases. The Co–W nanoparticles show superparamagnetic behavior. The activation energy for moment reversal and the effective anisotropy are obtained.The financial support of MAT08/1077 is acknowledged. A. I. Figueroa acknowledges a JAE-Predoc grant.Peer reviewe

Intracluster interactions in butterfly {Fe3 LnO2} molecules with the non-Kramers ions Tb(III) and Ho(III)

The intracluster exchange interactions within the >butterfly> [Fe3Ln(μ3-O)2(CCl3COO)8(H2O)(THF)3] molecules, where Ln(III) represents a lanthanide cation, have been determined by a combination of x-ray magnetic circular dichroism (XMCD) and vibrating sample magnetometry (VSM) along with an interaction model. We have studied the compounds with Ln=Tb and Ho, both non-Kramers lanthanides and with high uniaxial anisotropy, and Ln=Lu(III) and Y(III) as pseudolanthanides, which supply nonmagnetic Ln reference cases. At low temperature, the three Fe atoms can be considered as a self-unit with total spin SFe3=5/2. Using the element selectivity of the XMCD magnetometry, measured at the Ln L2,3 edges, together with the VSM measurements, the local magnetization of the Ln ion and the Fe3 subcluster, as a function of the field and low temperature (T≈2.5K), has been determined separately. These results are described quantitatively in the framework of a theoretical model based on an effective spin Hamiltonian, which considers the competing effects of intracluster interactions and the external applied magnetic field. The Ln-Fe3 exchange interaction within the {Fe3LnO2} cluster has been determined to be antiferromagnetic, in both Tb and Ho compounds, with JFeTb/kB=-0.13(1)K and JFeHo/kB=-0.18(1)K, respectively. In both cases, a field-induced reorientation of the Fe3 and Ln spins from antiparallel to parallel orientation takes place at a threshold field μ0H=1.1 and 2 T, for the {Fe3TbO2} and {Fe3HoO2} compounds, respectively. By comparison with other compounds of the series with uniaxial anisotropy, it is concluded that the polarizability of the Fe3 subcluster magnetic moment decreases in the trend {Fe3YO2}→{Fe3TbO2}→{Fe3HoO2}→{Fe3DyO2}, because of the increasing opposition of the exchange antiferromagnetic field caused by the Ln ion. In the Ln=Tb, Ho, and Dy, the magnetization of the whole molecule is dominated by the anisotropy of the Ln ion. The intracluster Fe3-Ln exchange interactions are very weak compared to the Ln ligand field and Fe-Fe exchange interactions.The projects MINECO (MAT2011/23791, MAT2011/27233-C02-02, and MAT2014/53921-R), DGA IMANA E34, and Alexander Von Humboldt Foundation (D.P.) are acknowledged for financial support.Peer Reviewe